Citation: Xin LU, Jianlei QIAN, Fayuan GE, Haotian LI, Hegen ZHENG, Chuanlei ZHANG. Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO₂ reduction reaction[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 209-220. doi: 10.11862/CJIC.20230377 shu

Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO₂ reduction reaction

Xin LU ^{1, #} ,
Jianlei QIAN ^{1, #} ,
Fayuan GE ² ,
Haotian LI ¹ ,
Hegen ZHENG ^2,, ,
Chuanlei ZHANG ^1,,

1.
Anhui Key Laboratory of Photoelectric-Magnetic Functional Materials, School of Chemistry and Engineering, Anqing Normal University, Anqing, Anhui 246133, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Hegen ZHENG, zhenghg@nju.edu.cn Chuanlei ZHANG, clzhang@nju.edu.cn
Received Date: 11 October 2023
Revised Date: 1 December 2023

Figures(8)

A 2D Cd-based metal-organic framework with moderate coordination bond strength and adequate framework flexibility was obtained by self-assembly, namely {[Cd(HL)(BPY)_0.5(H₂O)]·2H₂O}_n (1), where H₃L=4,4′,4″-(nitrilotris(methylene))tribenzoic acid, BPY=4,4′-bipyridine. Due to the unique structural features, under the stimulation of metal ions (Zn²⁺/Ni²⁺/Co²⁺), 1 gradually transforms into the MOF structures dominated by the corresponding metal ions (2, 3, and 4). During this process, with the exchanges of Cd²⁺→Zn²⁺, Cd²⁺→Ni²⁺, and Cd²⁺→Co²⁺, the free Cd²⁺ and L^3- in the channel of 1 fuse with the backbone, leading to the channel space expansion and secondary building unit (SBU) transformation to form a tunable backbone. The photocatalytic CO₂ reduction results show that the new structures obtained by ion exchange do not have a great improvement in catalytic efficiency, but have a great increase in product selectivity (3 demonstrated 100% CO selectivity).
- metal-organic framework,
- ionic stimulation,
- structural transformation,
- photocatalysis,
- carbon dioxide reduction
1. [1]
  Liang J X, Yu H, Shi J J, Li B, Wu L X, Wang M. Dislocated bilayer MOF enables high-selectivity photocatalytic reduction of CO₂ to CO, morphologies, and composites[J]. Adv. Mater., 2023,35(10)2209814. doi: 10.1002/adma.202209814
2. [2]
  Han C, Zhang X D, Huang S S, Hu Y, Yang Z, Li T T, Li Q P, Qian J J. MOF-on-MOF-derived hollow Co₃O₄/In₂O₃ nanostructure for efficient photocatalytic CO₂ reduction[J]. Adv. Sci., 2023,10(19)2300797. doi: 10.1002/advs.202300797
3. [3]
  Luo T, Gilmanova L, Kaskel S. Advances of MOFs and COFs for photocatalytic CO₂ reduction, H₂ evolution and organic redox transformations[J]. Coord. Chem. Rev., 2023,490215210. doi: 10.1016/j.ccr.2023.215210
4. [4]
  Stock N, Biswas S. Synthesis of metal-organic frameworks (MOFs): Routes to various MOF topologies, morphologies, and composites[J]. Chem. Rev., 2012,112(2):933-969. doi: 10.1021/cr200304e
5. [5]
  ZHAO Y X, HU H, ZHOU X, YANG S J, YANG Y. Preparation and photocatalytic degradation performance of MOF-808/BiOCl composites[J]. Chinese J. Inorg. Chem., 2023,39(8):1553-1563.
6. [6]
  Zhao X L, Sun W Y. The organic ligands with mixed N-/O-donors used in construction of functional metal-organic framework[J]. CrystEngComm, 2014,16:3247-3258. doi: 10.1039/c3ce41791c
7. [7]
  Qian Z P, Zhang R, Xiao Y, Huang H W, Sun Y, Chen Y, Ma T Y, Sun X D. Trace to the source: Self-tuning of MOF photocatalysts[J]. Adv. Energy Mater., 2023(13)2300086.
8. [8]
  Hu Y C, Zhang X, Khoo R S H, Fiankor C, Zhang X, Zhang J. Stepwise assembly of quinary multivariate metal-organic frameworks via diversified linker exchange and installation[J]. J. Am. Chem. Soc., 2023,145(25):13929-1393. doi: 10.1021/jacs.3c03421
9. [9]
  Mukherjee G, Biradha K. Post-synthetic modification of isomorphic coordination layers: Exchange dynamics of metal ions in a single crystal to single crystal fashion[J]. Chem. Comm., 2012,48(36):4293-4295. doi: 10.1039/c2cc30983a
10. [10]
  Brozek C K, Dincǎ M. Lattice-imposed geometry in metal-organic frameworks: Lacunary Zn₄O clusters in MOF-5 serve as tripodal chelating ligands for Ni²⁺[J]. Chem. Sci., 2012,3(6):2110-2113. doi: 10.1039/c2sc20306e
11. [11]
  Das S, Kim H, Kim K. Metathesis in single crystal: Complete and reversible exchange of metal ions constituting the frameworks of metal-organic frameworks[J]. J. Am. Chem. Soc., 2009,131(11):3814-3815. doi: 10.1021/ja808995d
12. [12]
  Wei J X, Mu X J, Hu Y, Liu L L, Wu X X, Liu Q Y, Zhang T, Peng Y, Cao J, Yan C H, Tang Y. A general preparation of solid solution-oxide heterojunction photocatalysts through metal-organic framework transformation induced pre-nucleation[J]. Angew. Chem. Int. Ed., 2023(26)e202302986.
13. [13]
  Kwon N H, Han S H, Kim J, Cho E S. Super proton conductivity through control of hydrogen-bonding networks in flexible metal-organic frameworks[J]. Small, 2023,19(32)2201122.
14. [14]
  Li C, Wang K B, Li J Z, Zhang Q C. Recent progress in stimulus-responsive two-dimensional metal-organic frameworks[J]. ACS Materials Lett., 2020,2(7):779-797. doi: 10.1021/acsmaterialslett.0c00148
15. [15]
  Kitagawa S, Kitaura R, Noro S I. Functional porous coordination polymers[J]. Angew. Chem. Int. Ed., 2004,43(18):2334-2375. doi: 10.1002/anie.200300610
16. [16]
  Brozek C K, Dincă M. Cation exchange at the secondary building units of metalorganic frameworks[J]. Chem. Soc. Rev., 2014,43(16):5456-5467. doi: 10.1039/C4CS00002A
17. [17]
  Prasad T K, Hong D H, Suh M P. High gas sorption and metal-ion exchange of microporous metal-organic frameworks with incorporated imide groups[J]. Chem.-Eur. J., 2010,16(47):14043-14050. doi: 10.1002/chem.201002135
18. [18]
  Aslani A, Morsali A. Crystal-to-crystal transformation from a chain polymer to a two-dimensional network by thermal desolvation[J]. Chem. Commun., 2008(29):3402-3404. doi: 10.1039/b800126j
1. [1]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
2. [2]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
3. [3]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
4. [4]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
5. [5]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
6. [6]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
7. [7]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
8. [8]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
9. [9]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
10. [10]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
11. [11]
  Jian Yang , Guang Yang , Zhijie Chen . Capturing carbon dioxide from air by using amine-functionalized metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(5): 100267-100267. doi: 10.1016/j.cjsc.2024.100267
12. [12]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
13. [13]
  Jia-Cheng Hou , Wei Cai , Hong-Tao Ji , Li-Juan Ou , Wei-Min He . Recent advances in semi-heterogenous photocatalysis in organic synthesis. Chinese Chemical Letters, 2025, 36(2): 110469-. doi: 10.1016/j.cclet.2024.110469
14. [14]
  Qiaojia GUO , Junkai CAI , Chunying DUAN . Effects of anions on the structural regulation of Zn-salen-modified metal-organic cage. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2203-2211. doi: 10.11862/CJIC.20240209
15. [15]
  Yin-Hang Chai , Li-Long Dang . New structural breakthrough and topological transformation of homogeneous metalla[4]catenane compounds. Chinese Journal of Structural Chemistry, 2024, 43(10): 100322-100322. doi: 10.1016/j.cjsc.2024.100322
16. [16]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
17. [17]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
18. [18]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
19. [19]
  Yuan Dong , Mutian Ma , Zhenyang Jiao , Sheng Han , Likun Xiong , Zhao Deng , Yang Peng . Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction. Chinese Chemical Letters, 2024, 35(7): 109049-. doi: 10.1016/j.cclet.2023.109049
20. [20]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(459)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO2 reduction reaction

Metrics

通讯作者: 陈斌, bchen63@163.com

Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO₂ reduction reaction