Citation: Endong YANG, Haoze TIAN, Ke ZHANG, Yongbing LOU. Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369 shu

Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays

Endong YANG ^{1, 2} ,
Haoze TIAN ³ ,
Ke ZHANG ³ ,
Yongbing LOU ^3,,

1.
Shanghai Yijin Electronic Technology Co., Ltd., Shanghai 200120, China
2.
Nantong Jianghai Energy Storage Technology Co., Ltd., Nantong, Jiangsu 226399, China
3.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: Yongbing LOU, lou@seu.edu.cn
Received Date: 8 October 2023
Revised Date: 22 January 2024

Figures(7)

Using an interface engineering strategy, we successfully synthesized a core-shell nano-flower array of CuCo₂O₄/NiFe-layered bimetallic hydroxide (LDH) on nickel foam (NF) (CuCo₂O₄/NiFe-LDH@NF). The research indicates that electrons undergo transfer across the coupled interface of CuCo₂O₄ and NiFe-LDH, resulting in the enrichment of the CuCo₂O₄ core in electron density and thereby enhancing reaction kinetics. The amorphous NiFe-LDH shell not only provides additional channels for electron/material transport and increases active sites but also effectively shields the core CuCo₂O₄ from strong alkali corrosion during the oxygen evolution reaction (OER) in electrocatalysis. Therefore, when employed as an OER catalyst in a 1.0 mol·L^-1 KOH solution, CuCo₂O₄/NiFe-LDH@NF required only a low overpotential of 191 mV to achieve a current density of 10 mA·cm^-2 and a low Tafel slope of 31 mV·dec^-1. Furthermore, CuCo₂O₄/NiFe-LDH@NF demonstrated stability in catalytic performance, crystal structure, morphological structure, and composition during prolonged operation.
- interfacial engineering,
- transition metal oxide,
- nickel-iron hydroxide,
- oxygen evolution reaction,
- core-shell structure
1. [1]
  Han J Y, Guan J Q. Multicomponent transition metal oxides and (oxy) hydroxides for oxygen evolution[J]. Nano Res., 2022,16:1913-1966.
2. [2]
  Zhang Q, Lian K, Liu Q, Qi G C, Zhang S S, Luo J, Liu X J. High entropy alloy nanoparticles as efficient catalysts for alkaline overall seawater splitting and Zn-air batteries[J]. J. Colloid Interface Sci., 2023,646:844-854. doi: 10.1016/j.jcis.2023.05.074
3. [3]
  Zhang K, Jia J, Tan L, Qi S P, Li B L, Chen J X, Li J, Lou Y B, Guo Y Z. Morphological and electronic modification of NiS₂ for efficient supercapacitors and hydrogen evolution reaction[J]. J. Power Sources, 2023,577233239. doi: 10.1016/j.jpowsour.2023.233239
4. [4]
  Liang Q N, Chen J M, Wang F L, Li Y W. Transition metal-based metal-organic frameworks for oxygen evolution reaction[J]. Coord. Chem. Rev., 2020,424213488. doi: 10.1016/j.ccr.2020.213488
5. [5]
  He R Z, Huang X Y, Feng L G. Recent progress in transition-metal sulfide catalyst regulation for improved oxygen evolution reaction[J]. Energy Fuels, 2022,36(13):6675-6694. doi: 10.1021/acs.energyfuels.2c01429
6. [6]
  Zhang Q, Lian K, Qi G C, Zhang S, Liu Q, Luo Y, Luo J, Liu X. High-entropy alloys in water electrolysis: Recent advances, fundamentals, and challenges[J]. Sci. China Mater., 2023,66(5):1681-1701. doi: 10.1007/s40843-022-2379-8
7. [7]
  Zhang K, Jia J, Yang E D, Qi S P, Tian H, Chen J X, Li J, Lou Y B, Guo Y Z. Work-function-induced electron rearrangement of in-plane FeP@CoP heterojunction enhances all pH range and alkaline seawater hydrogen evolution reaction[J]. Nano Energy, 2023,114108601. doi: 10.1016/j.nanoen.2023.108601
8. [8]
  Zhang K, Yang E D, Zheng Y P, Yu D H, Chen J X, Lou Y B. Robust and hydrophilic Mo-NiS@NiTe core-shell heterostructure nanorod arrays for efficient hydrogen evolution reaction in alkaline freshwater and seawater[J]. Appl. Surf. Sci., 2023,637157977. doi: 10.1016/j.apsusc.2023.157977
9. [9]
  Wang H P, Zhu S, Deng J W, Zhang W C, Feng Y Z, Ma J M. Transition metal carbides in electrocatalytic oxygen evolution reaction[J]. Chin. Chem. Lett., 2021,32(1):291-298. doi: 10.1016/j.cclet.2020.02.018
10. [10]
  Wang H X, Zhang K H L, Hofmann J P, De La Pena O'shea V A, Oropeza F E. The electronic structure of transition metal oxides for oxygen evolution reaction[J]. J. Mater. Chem. A, 2021,9(35):19465-19488. doi: 10.1039/D1TA03732C
11. [11]
  Yan D F, Xia C F, Zhang W J, Hu Q, He C X, Xia B Y, Wang S Y. Cation defect engineering of transition metal electrocatalysts for oxygen evolution reaction[J]. Adv. Energy Mater., 2022,12(45)2202317. doi: 10.1002/aenm.202202317
12. [12]
  Zhang H, Luo Y, Chu P K, Liu Q, Liu X, Zhang S S, Luo J, Wang X Z, Hu G Z. Recent advances in non-noble metal-based bifunctional electrocatalysts for overall seawater splitting[J]. J. Alloy. Compd., 2022,922166113. doi: 10.1016/j.jallcom.2022.166113
13. [13]
  Vazhayil A, Vazhayal L, Thomas J, Ashok S C, Thomas N. A comprehensive review on the recent developments in transition metal-based electrocatalysts for oxygen evolution reaction[J]. Appl. Surf. Sci. Adv., 2021,6100184. doi: 10.1016/j.apsadv.2021.100184
14. [14]
  Hao Z M, Liu D P, Ge H Y, Zuo X T, Feng X L, Shao M Z, Yu H H, Yuan G B, Zhang Y. Preparation of quaternary FeCoMoCu metal oxides for oxygen evolution reaction[J]. Chem. Res. Chin. Univ., 2022,38(3):823-828. doi: 10.1007/s40242-022-2040-y
15. [15]
  Bera K, Karmakar A, Kumaravel S, Sankar S S, Madhu R, Dhandapani H N, Nagappan S, Kundu S. Vanadium-doped nickel cobalt layered double hydroxide: A high-performance oxygen evolution reaction electrocatalyst in alkaline medium[J]. Inorg. Chem., 2022,61(10):4502-4512. doi: 10.1021/acs.inorgchem.2c00093
16. [16]
  Zeng F, Mebrahtu C, Liao L F, Beine A K, Palkovits R. Stability and deactivation of OER electrocatalysts: A review[J]. J. Energy Chem., 2022,69:301-29. doi: 10.1016/j.jechem.2022.01.025
17. [17]
  Wang H Y, Chen L Y, Tan L, Liu X, Wen Y H, Hou W G, Zhan T R. Electrodeposition of NiFe-layered double hydroxide layer on sulfur-modified nickel molybdate nanorods for highly efficient seawater splitting[J]. J. Colloid Interface Sci., 2022,613:349-57. doi: 10.1016/j.jcis.2022.01.044
18. [18]
  Gao X H, Zhang H X, Li Q G, Yu X G, Hong Z L, Zhang X W, Liang C D, Lin Z. Hierarchical NiCo₂O₄ hollow microcuboids as bifunctional electrocatalysts for overall water-splitting[J]. Angew. Chem. Int. Ed., 2016,55(21):6290-6294. doi: 10.1002/anie.201600525
19. [19]
  Zhang L J, Yuan H C, Li X, Wang Y. Hydrothermal synthesis of NiCo₂O₄@NiCo₂O₄ core-shell nanostructures anchored on Ni foam for efficient oxygen evolution reactions catalysts[J]. Coatings, 2022,12(9)1240. doi: 10.3390/coatings12091240
20. [20]
  Long X, Wang Z L, Xiao S, An Y M, Yang S H. Transition metal based layered double hydroxides tailored for energy conversion and storage[J]. Mater. Today, 2016,19(4):213-226. doi: 10.1016/j.mattod.2015.10.006
21. [21]
  Wang Y Y, Yan D F, El Hankari S, Zou Y Q, Wang S Y. Recent progress on layered double hydroxides and their derivatives for electrocatalytic water splitting[J]. Adv. Sci., 2018,5(8)1800064. doi: 10.1002/advs.201800064
22. [22]
  Liu Y P, Liang X, Gu L, Zhang Y, Li G D, Zou X X, Chen J S. Corrosion engineering towards efficient oxygen evolution electrodes with stable catalytic activity for over 6 000 hours[J]. Nat. Commun., 2018,92609. doi: 10.1038/s41467-018-05019-5
23. [23]
  Lu X Y, Zhao C. Electrodeposition of hierarchically structured three-dimensional nickel-iron electrodes for efficient oxygen evolution at high current densities[J]. Nat. Commun., 2015,66616. doi: 10.1038/ncomms7616
24. [24]
  Wang S Y, Wang H P, Chen S M, Cheung K K K, Wong H F, Leung C W, Zapien J A. Hydrochloric acid etching induced flower-like NiFe-layered double hydroxide as efficient electrocatalyst for oxygen evolution reaction[J]. Int. J. Hydrog. Energy, 2023,48:17045-1705. doi: 10.1016/j.ijhydene.2023.01.119
25. [25]
  Song S, Fu Y, Yin F, Zhang Y, Ma J, Liu Y, Ren J, Ye W, Ma R. NiFe-based tungstate@layered double hydroxide heterostructure supported on graphene as efficient oxygen evolution reaction catalyst[J]. Mater. Today Chem., 2023,28101369. doi: 10.1016/j.mtchem.2022.101369
26. [26]
  Fauzi A, Geng S, Tian F Y, Liu Y Q, Li H B, Yu Y S, Li J M, Yang W W. NiFe-LDH@Ni₃S₂ supported on nickel foam as highly active electrocatalysts for oxygen evolution reaction[J]. Int. J. Hydrog. Energy, 2023,48(4):1370-1379. doi: 10.1016/j.ijhydene.2022.09.305
27. [27]
  Zhang K, Yang E D, Zheng Y Y, Wang S Y, Xie Y H, Chen J X, Lou Y B, Song L L. Work-function-induced interfacial built-in electric field optimized electronic structure of V-CoS_x@NiTe as high capacity and robust electrode for supercapacitors[J]. Chem. Eng. J., 2024,480148030. doi: 10.1016/j.cej.2023.148030
28. [28]
  Chen W Y, Zhang X M, Mo L E, Zhang Y S, Chen S G, Zhang X X, Hu L H. NiCo₂S₄ quantum dots with high redox reactivity for hybrid supercapacitors[J]. Chem. Eng. J., 2020,388124109. doi: 10.1016/j.cej.2020.124109
29. [29]
  Song Y B, Guo Y M, Qi S P, Zhang K, Yang J F, Li B N, Chen J X, Zhao Y X, Lou Y B. Cu₇S₄/MnIn₂S₄ heterojunction for efficient photo-catalytic hydrogen generation[J]. J. Alloy. Compd., 2021,884161035. doi: 10.1016/j.jallcom.2021.161035
30. [30]
  Guo X X, Hu B, Wang K, Wang H H, Li B L, Guo M, Tian Y, Zhang R X, Shi S S, Han Y F. Cu embedded Co oxides and its Fenton-like activity for metronidazole degradation over a wide pH range: Active sites of Cu doped Co₃O₄ with {112} exposed facet[J]. Chem. Eng. J., 2022,435132910. doi: 10.1016/j.cej.2021.132910
31. [31]
  Tian H Z, Zhang K, Feng X A, Chen J X, Lou Y B. Self-supported CoMoO₄/NiFe-LDH core-shell nanorods grown on nickel foam for enhanced electrocatalysis of oxygen evolution[J]. Dalton Trans., 2022,51(36):13762-13770. doi: 10.1039/D2DT02167F
32. [32]
  Dastafkan K, Wang S H, Rong C L, Meyer Q, Li Y B, Zhang Q, Zhao C A. Cosynergistic molybdate oxo-anionic modification of feni-based electrocatalysts for efficient oxygen evolution reaction[J]. Adv. Funct. Mater., 2022,32(5)2107342. doi: 10.1002/adfm.202107342
33. [33]
  Sun S G, Sun Y M, Zhou Y, Shen J J, Mandler D, Neumann R, Xu Z J. Switch of the rate-determining step of water oxidation by spin-selected electron transfer in spinel oxides[J]. Chem. Mater., 2019,31(19):8106-8111. doi: 10.1021/acs.chemmater.9b02737
34. [34]
  Ren X, Wu T Z, Sun Y M, Li Y, Xian G Y, Liu X H, Shen C M, Gracia J, Gao H J, Yang H T, Xu Z J. Spin-polarized oxygen evolution reaction under magnetic field[J]. Nat. Commun., 2021,12(1)2608. doi: 10.1038/s41467-021-22865-y
35. [35]
  Lv J J, Wang L M, Li R S, Zhang K Y, Zhao D F, Li Y Q, Li X J, Huang X B, Wang G. Constructing a hetero-interface composed of oxygen vacancy-enriched Co₃O₄ and crystalline-amorphous NiFe-LDH for oxygen evolution reaction[J]. ACS Catal., 2021,11(23):14338-14351. doi: 10.1021/acscatal.1c03960
36. [36]
  Wang Z Q, Zeng S, Liu W H, Wang X W, Li Q W, Zhao Z G, Geng F X. Coupling molecularly ultrathin sheets of nife-layered double hydroxide on NiCo₂O₄ nanowire arrays for highly efficient overall water-splitting activity[J]. ACS Appl. Mater. Interfaces, 2017,9(2):1488-1495. doi: 10.1021/acsami.6b13075
37. [37]
  Wang S G, Li J H, Fang H, Li B Y, Wang G M, Gao Y. 3D core-shell structured NiFe layered double hydroxide with NiCo₂O₄ as an efficient electrocatalysts for oxygen evolution reaction[J]. J. Phys. Chem. Solids, 2022,166110730. doi: 10.1016/j.jpcs.2022.110730
38. [38]
  Dong Q B, Shuai C, Mo Z L, Liu N J, Liu G G, Wang J, Pei H B, Jia Q Q, Liu W T, Guo X D. CeO₂ nanoparticles@ NiFe-LDH nanosheet heterostructure as electrocatalysts for oxygen evolution reaction[J]. J. Solid State Chem., 2021,296121967. doi: 10.1016/j.jssc.2021.121967
39. [39]
  Sirisomboonchai S, Li S, Yoshida A, Li X M, Samart C, Abudula A, Guan G. Fabrication of NiO microflake@NiFe-LDH nanosheet heterostructure electrocatalysts for oxygen evolution reaction[J]. ACS Sustain. Chem. Eng., 2019,7(2):2327-2334. doi: 10.1021/acssuschemeng.8b05088
40. [40]
  Arshad F, Munir A, Tahir A, Hussain S Z, Jilani A, Hussain A, Ullah N, Sher F, Hussain I. Microwave-assisted growth of spherical core-shell NiFe LDH@Cu_xO nanostructures for electrocatalytic water oxidation reaction[J]. Int. J. Hydrog. Energy, 2023,48(12):4719-4727. doi: 10.1016/j.ijhydene.2022.10.252
41. [41]
  Xiao C L, Li Y B, Lu X Y, Zhao C. Bifunctional porous NiFe/NiCo₂O₄/Ni foam electrodes with triple hierarchy and double synergies for efficient whole cell water splitting[J]. Adv. Funct. Mater., 2016,26(20):3515-3523. doi: 10.1002/adfm.201505302
42. [42]
  Chen H, Gao Y, Sun L C. Highly active three-dimensional NiFe/Cu₂O nanowires/Cu foam electrode for water oxidation[J]. ChemSusChem, 2017,10(7):1475-1481. doi: 10.1002/cssc.201601884
43. [43]
  Li X, Fan M L, Wei D N, Wang X L, Wang Y L. Core-shell NiO/C@NiFe-LDH nanocomposite as an efficient electrocatalyst for oxygen evolution reaction[J]. J. Electrochem. Soc., 2020,167(2)024501. doi: 10.1149/1945-7111/ab61eb
44. [44]
  Que R H, Liu S, Yang Y, Pan Y Y. High catalytic performance of core-shell structure ZnCo₂O₄@NiFe LDH for oxygen evolution reaction[J]. Mater. Lett., 2021,298129982. doi: 10.1016/j.matlet.2021.129982
45. [45]
  Wang S P, Wu J, Yin J W, Hu Q, Geng D S, Liu L M. Improved electrocatalytic performance in overall water splitting with rational design of hierarchical Co₃O₄@NiFe layered double hydroxide core-shell nanostructure[J]. ChemElectroChem, 2018,5(10):1357-1363. doi: 10.1002/celc.201800194
46. [46]
  Yang H Y, Driess M, Menezes P W. Self-supported electrocatalysts for practical water electrolysis[J]. Adv. Energy Mater., 2021,11(39)2170153. doi: 10.1002/aenm.202170153
47. [47]
  Sun J L, Xu C J, Chen H Y. A review on the synthesis of CuCo₂O₄-based electrode materials and their applications in supercapacitors[J]. J. Materiomics, 2021,7(1):98-126. doi: 10.1016/j.jmat.2020.07.013
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Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays

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Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays