Citation: Shuwen SUN, Gaofeng WANG. Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368 shu

Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties

Shuwen SUN ,
Gaofeng WANG ^,

Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Gaofeng WANG, wgf1979@126.com
Received Date: 8 October 2023
Revised Date: 18 December 2023

Figures(4)

Based on Ⅴ-shaped auxiliary ligands, two novel coordination polymers, {[Cd(bipmo)(NDC)]·1.75H₂O}_n (1), {[Cd(bppmo)(NDC)(H₂O)]·H₂O}_n (2), where H₂NDC=2,6-naphthalenedicarboxylic acid, bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, bppmo=bis(4-(pyridin-4-yl)phenyl)methanone, have been synthesized under solvothermal conditions. They have been characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, and elemental analyses. Complex 1 shows 2-fold interpenetrating sheets of {6³} topology, which interpenetrate in a 2D → 2D parallel manner. Complex 2 reveals a 3-fold interpenetrating {6³} network. The results indicate that the Ⅴ-shaped ligands have a great effect on the formation of the final structures. In addition, the luminescent properties of complexes 1 and 2 were investigated in detail.
- bond valence sum,
- coordination polymer,
- Ⅴ-shaped ligand,
- topology,
- fluorescence
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