Citation: Xiang GAO, Qiushui MU, Yuejian LIN, Guoxin JIN. A synthetic strategy of organometallic supramolecular bridged compounds and spirocyclic compounds featuring half-sandwich Cp*Rh units[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 164-172. doi: 10.11862/CJIC.20230356 shu

A synthetic strategy of organometallic supramolecular bridged compounds and spirocyclic compounds featuring half-sandwich Cp*Rh units

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200438, China

Corresponding author: Guoxin JIN, gxjin@fudan.edu.cn
Received Date: 26 September 2023
Revised Date: 27 November 2023

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Bridged and spirocyclic compounds are common concepts in the pure organic field. Herein, we extend these concepts to supramolecular chemistry and a synthetic strategy is exhibited. Three supramolecular bridged compounds [(Cp*Rh)₆(μ-η²-η²-C₂O₄)₂(μ-C₂O₄)(L^A)₂](OTf)₆ (1), [(Cp*Rh)₆(dhbq)₂(pyrazine)(L^A)₂](OTf)₈ (2), and [(Cp*Rh)₆ (tpphz)₂(bpea)(L^A)₂](OTf)₁₂ (3), and a spirocyclic compound (Cp*Rh)₁₂(bibzim)₃Ru(L^A)₃(L^B)₃](OTf)₁₀(PF₆)₄ (4), where L^A =3,3′-di(pyridin-4-yl)-2,2′-bipyridine, OTf^-=CF₃SO³^-, dhbq=2,5-dihydroxy-1,4-benzoquinone, tpphz=tetrapyrido[3,2-a∶2′,3′-c∶3″, 2″-h∶2''',3'''-j]phenazine, bpea=1,2-di(pyridin-4-yl)ethane, bibzim=2,2′-bisbenzimidazole, L^B=4,4′-di(pyridin-4-yl)-1,1′-biphenyl, were obtained by introducing of additional chelating sites in rigid linear ligand through coordination-driven stepwise chemical self-assembly method and were characterized by single crystal X-ray diffraction method.
- self-assembly,
- macrocycles,
- coordination-driven,
- bridged compounds,
- spirocyclic compounds
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