Citation: Wenda WANG, Jinku MA, Yuzhu WEI, Shuaishuai MA. Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353 shu

Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater

  • Corresponding author: Shuaishuai MA, machem@jsut.edu.cn
  • Received Date: 25 September 2023
    Revised Date: 24 January 2024

Figures(12)

  • A metal - free photocatalyst was developed and synthesized through a single - step thermal treatment process involving banana peel (BP) and urea. The close interfacial connection between biomass-derived carbon (BC) and porous graphite carbon nitride (pg - C3N4) resulted in an increased specific surface area, expanded photo-response range, effective migration of photo-induced electrons, and enhanced stability. The reaction rate constant of pg-C3N4/BC for degradation oxytetracycline (OTC) in artificial seawater was 9.4 times higher than that of pristine pg-C3N4 after 70 min of visible-light illumination, and pg-C3N4/BC also performed better photocatalytic degradation on OTC in the continuous flow reaction process owing to facilitated photogenerated charge separation and transfer. Additionally, a potential photocatalytic mechanism was proposed to explain the enhanced performance of pg-C3N4/BC composites.
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