Citation: Ruolin CHENG, Haoran WANG, Jing REN, Yingying MA, Huagen LIANG. Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349 shu

Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst

Ruolin CHENG ^1,, ,
Haoran WANG ² ,
Jing REN ² ,
Yingying MA ³ ,
Huagen LIANG ^{1, 4,,}

1.
Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization, Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou, Jiangsu 221008, China
2.
School of Information and Control Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
3.
Training Center, Jiangsu Provincial Xuzhou Pharmaceutical Vocational College, Xuzhou, Jiangsu 221116, China
4.
School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221008, China

Corresponding author: Ruolin CHENG, ruolin.cheng@cumt.edu.cn Huagen LIANG, lianghg@cumt.edu.cn
Received Date: 18 September 2023
Revised Date: 22 December 2023

Figures(10)

Zr-based metal-organic framework (MOF) NH₂-UiO-66 was first synthesized by a solvothermal method using 2-amino terephthalic acid (H₂ATA) as the ligand. The efficient W₁₈O₄₉/NH₂-UiO-66 photocatalysts with a typical type Ⅱ heterojunction were then constructed by in-situ growth of the oxygen vacancy-rich defective tungsten oxide (W₁₈O₄₉) on NH₂-UiO-66, using tungsten chloride as the precursor. The composition and structure of the catalysts were characterized by a series of measurements, including powder X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis diffuse reflectance spectroscopy. At room temperature and atmospheric pressure, the photoactivity of all the catalysts was examined under simulated sunlight with styrene oxide as the model substrate. W₁₈O₄₉/NH₂-UiO-66 exhibited the highest yield of styrene carbonate (58 mmol·g^-1·h^-1). The introduction of NH₂-UiO-66 expanded the specific surface area, CO₂ adsorption capacity, light harvesting ability, and photogenerated charge carriers transfer of W₁₈O₄₉.
- CO₂ cycloaddition,
- photocatalysis,
- W₁₈O₄₉,
- metal-organic framework
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Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst