Citation: Zhenghua ZHAO, Qin ZHANG, Yufeng LIU, Zifa SHI, Jinzhong GU. Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342 shu

Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid

Zhenghua ZHAO ¹ ,
Qin ZHANG ¹ ,
Yufeng LIU ¹ ,
Zifa SHI ^2,, ,
Jinzhong GU ^2,,

1.
Petrochina Lanzhou Lube Oil R&D Institute, Lanzhou 730000, China
2.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Zifa SHI, shizf@lzu.edu.cn Jinzhong GU, gujzh@lzu.edu.cn
Received Date: 12 September 2023
Revised Date: 27 November 2023

Figures(10)

Two nickel(Ⅱ) and zinc(Ⅱ) coordination polymers, namely {[Ni(μ₃-cpna)(μ-dpea)_0.5]·H₂O}_n (1) and {[Zn(μ₃-cpna)(μ-dpey)_0.5]·H₂O}_n (2) have been constructed hydrothermally using 5-(2-carboxyphenyl)nicotinic acid (H₂cpna), 1, 2-di(4-pyridyl)ethane (dpea), 1, 2-di(4-pyridyl)ethylene (dpey), and nickel and zinc chlorides at 160℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that two compounds crystallize in the monoclinic or orthorhombic systems, space groups, P2₁/c or Pbca. Both compounds show 3D metal-organic frameworks. Compound 2 exhibited an effective catalytic activity in the Knoevenagel condensation reaction at room temperature. Meanwhile, compound 2 showed an effective anti-wear performance in poly-α-olefine synthetic lubricant.
- coordination polymer,
- dicarboxylic acid,
- catalytic property,
- Knoevenagel condensation reaction,
- anti-wear performance
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沈阳化工大学材料科学与工程学院沈阳 110142