Citation: Liangqing LI, Jiajia LI, Qiting YE, Kaikai WANG, Liangsong LI. Preparation of mordenite zeolite membrane by intermittent hydrothermal synthesis and its application in isopropanol dehydration[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 316-324. doi: 10.11862/CJIC.20230327 shu

Preparation of mordenite zeolite membrane by intermittent hydrothermal synthesis and its application in isopropanol dehydration

Liangqing LI ^{1, 2,,} ,
Jiajia LI ³ ,
Qiting YE ¹ ,
Kaikai WANG ¹ ,
Liangsong LI ^{4, 5}

1.
Key Laboratory of Functional Membranes and Energy Materials, School of Chemistry and Chemical Engineering, Huangshan University, Huangshan, Anhui 245041, China
2.
School of Chemistry and Materials, University of Science and Technology of China, Hefei 230026, China
3.
Department of Chemical and Biological Engineering, Korea University, Seoul 02841, Republic of Korea
4.
Shanghai Safety and Environmental Protection Branch, CNOOC Energy Technology & Services Limited, Shanghai 200335, China
5.
Shanghai Branch, CNOOC Safety & Technology Services Limited, Shanghai 200335, China

Corresponding author: Liangqing LI, liliangqing@hsu.edu.cn
Received Date: 30 August 2023
Revised Date: 12 December 2023

Figures(8)

A novel intermittent hydrothermal method was applied to synthesize mordenite zeolite membrane. The membrane was synthesized in a template-free synthetic solution using commercially available, economical, macroporous α-Al₂O₃ tube as the substrate. The out surface of the substrate was coated with a mordenite seed layer via a hotdip coating procedure. The influences of the traditional continuous heating method and the novel intermittent heating method on the morphology, microstructure and pervaporation performance for isopropanol dehydration of the mordenite membranes were compared. The impacts of molar ratios of Na₂O/SiO₂, SiO₂/Al₂O₃, and NaF/SiO₂ in the synthetic solution on the preparation of mordenite zeolite membranes under intermittent hydrothermal synthesis were investigated. The as-synthesized mordenite zeolite membrane showed maximum pervaporation performance for isopropanol dehydration under optimized synthetic solution composition with the molar ratios of Na₂O/SiO₂, SiO₂/Al₂O₃, and NaF/SiO₂ were 0.24, 16.7 and 0.25, respectively. The maximum water permeation flux was 5.60 kg·m^-2·h^-1 and the separation factor was greater than 10 000, respectively, in the dehydration of isopropanol/water mixture (9∶1, w/w) at 75 ℃.
- mordenite membrane,
- intermittent hydrothermal synthesis,
- pervaporation,
- isopropanol dehydration
1. [1]
  Lei Z G, Li C Y, Chen B H. Extractive distillation: A review[J]. Sep. Purif. Rev., 2003,32(2):121-213. doi: 10.1081/SPM-120026627
2. [2]
  Nhien L C, Agarwal N, Lee M. Dehydration of isopropanol: A comparative review of distillation processes, heat integration, and intensification techniques[J]. Energies, 2023,16(16)5934. doi: 10.3390/en16165934
3. [3]
  Hoof V V, Abeele L V, Buekenhoudt A, Dotremont C. Economic comparison between azeotropic distillation and different hybrid systems combining distillation with pervaporation for the dehydration of isopropanol[J]. Sep. Purif. Technol., 2004,37(1):33-49. doi: 10.1016/j.seppur.2003.08.003
4. [4]
  Zhang C, Peng L, Jiang J, Gu X H. Mass transfer model, preparation and applications of zeolite membranes for pervaporation dehydration: A review[J]. Chin. J. Chem. Eng., 2017,25(11):1627-1638. doi: 10.1016/j.cjche.2017.09.014
5. [5]
  Wee S L, Tye C T, Bhatia S. Membrane separation process—Pervaporation through zeolite membrane[J]. Sep. Purif. Technol., 2008,63(3):500-516. doi: 10.1016/j.seppur.2008.07.010
6. [6]
  Jyothi M S, Reddy K R, Soontarapa K, Naveen S, Raghu A V, Kulkarni R V, Suhas D P, Shetti N P, Nadagouda M N, Aminabhavi T M. Membranes for dehydration of alcohols via pervaporation[J]. J. Environ. Manage., 2019,242:415-429. doi: 10.1016/j.jenvman.2019.04.043
7. [7]
  Vane L M. Membrane materials for the removal of water from industrial solvents by pervaporation and vapor permeation[J]. J. Chem. Technol. Biotechnol., 2019,94(2):343-365. doi: 10.1002/jctb.5839
8. [8]
  Liu G P, Jin W Q. Pervaporation membrane materials: Recent trends and perspectives[J]. J. Membr. Sci., 2021,636119557. doi: 10.1016/j.memsci.2021.119557
9. [9]
  Algieri C, Drioli E. Zeolite membranes: Synthesis and applications[J]. Sep. Purif. Technol., 2021,278119295. doi: 10.1016/j.seppur.2021.119295
10. [10]
  Yue B, Liu S S, Chai Y C, Wu G J, Guan N J, Li L D. Zeolites for separation: fundamental and application[J]. J. Energy Chem., 2022,71:288-303. doi: 10.1016/j.jechem.2022.03.035
11. [11]
  Luo Y W, Raza W, Yang J H, Li L Q, Lu Y. Recent advances in acid-resistant zeolite T membranes for dehydration of organics[J]. Chin. J. Chem. Eng., 2019,27(6):1449-1457. doi: 10.1016/j.cjche.2019.05.004
12. [12]
  Li L Q, Li J J, Cheng L J, Wang J X, Yang J H. Microwave synthesis of high-quality mordenite membrane by a two-stage varying heating-rate procedure[J]. J. Membr. Sci., 2020,612118479. doi: 10.1016/j.memsci.2020.118479
13. [13]
  Raza W, Wang J X, Yang J H, Tsuru T. Progress in pervaporation membranes for dehydration of acetic acid[J]. Sep. Purif. Technol., 2021,262118338. doi: 10.1016/j.seppur.2021.118338
14. [14]
  Li L Q, Li J J, Wang X Y, Liu C C, Li L S. Preparation of high-performance zeolite membrane on a macroporous support by novel intermittent hydrothermal synthesis[J]. Microporous Mesoporous Mat., 2023,360112734. doi: 10.1016/j.micromeso.2023.112734
15. [15]
  Li J J, Li L Q, Yang J H, Lu J M, Wang J Q. Organotemplate-free synthesis of ZSM-5 membrane for pervaporation dehydration of isopropanol[J]. Membr. Water Treat., 2019,10:353-360.
16. [16]
  Yang J H, Li L Q, Li W Z, Wang J Q, Chen Z, Yin D H, Lu J M, Zhang Y, Guo H C. Tuning aluminum spatial distribution in ZSM-5 membranes: a new strategy to fabricate high performance and stable zeolite membranes for dehydration of acetic acid[J]. ChemComm, 2014,50(93):14654-14657.
17. [17]
  Lu X F, Wang H S, Yang Y W, Wang Z B. Microstructural manipulation of MFI-type zeolite films/membranes: Current status and perspectives[J]. J. Membr. Sci., 2022,662120931. doi: 10.1016/j.memsci.2022.120931
18. [18]
  Wang J X, Wang L, Li L Q, Li J J, Raza W, Lu J M, Yang J H. A green synthesis of MOR zeolite membranes by wet gel conversion for dehydration of water-acetic acid mixtures[J]. Sep. Purif. Technol., 2022,286120311. doi: 10.1016/j.seppur.2021.120311
19. [19]
  Chen C, Cheng Y L, Peng L, Zhang C, Wu Z Q, Gu X H, Wang X Y, Murad S. Fabrication and stability exploration of hollow fiber mordenite zeolite membranes for isopropanol/water mixture separation[J]. Microporous Mesoporous Mat., 2019,274:347-355. doi: 10.1016/j.micromeso.2018.09.010
20. [20]
  Lin X, Kikuchi E, Matsukata M. Preparation of mordenite membranes on α-alumina tubular supports for pervaporation of water-isopropyl alcohol mixtures[J]. ChemComm, 2000(11):957-958.
21. [21]
  Navajas A, Mallada R, Téllez C, Coronas J, Menéndez M, Santamaría J. Study on the reproducibility of mordenite tubular membranes used in the dehydration of ethanol[J]. J. Membr. Sci., 2007,299(1/2):166-173.
22. [22]
  Barrer R M. Zeolites and their synthesis[J]. Zeolites, 1981,1(3):130-140. doi: 10.1016/S0144-2449(81)80001-2
23. [23]
  Occelli M L, Robson H E. Zeolite Synthesis. Washington: ACS Symposium Series, 1989: 11-27
24. [24]
  Karthika S, Radhakrishnan T, Kalaichelvi P. A review of classical and nonclassical nucleation theories[J]. Cryst. Growth Des., 2016,16(11):6663-6681. doi: 10.1021/acs.cgd.6b00794
25. [25]
  Cundy C S, Cox P A. The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism[J]. Microporous Mesoporous Mat., 2005,82(1/2):1-78.
26. [26]
  Wong W C, Au L T, Ariso C T, Yeung K L. Effects of synthesis parameters on the zeolite membrane growth[J]. J. Membr. Sci., 2001,191(1/2):143-163.
27. [27]
  Aguado S, Gascón J, Jansen J C, Kapteijn F. Continuous synthesis of NaA zeolite membranes[J]. Microporous Mesoporous Mat., 2009,120(1/2):170-176.
28. [28]
  Li L Q, Yang J H, Li J J, Wang J Q, Lu J M, Yin D H, Zhang Y. High performance ZSM-5 membranes on coarse macroporous α-Al₂O₃ supports for dehydration of alcohols[J]. AIChE J, 2016,62(8):2813-2824. doi: 10.1002/aic.15234
29. [29]
  Li L Q, Yang J H, Li J J, Han P, Wang J X, Zhao Y, Wang J Q, Lu J M, Yin D H, Zhang Y. Synthesis of high performance mordenite membranes from fluoride-containing dilute solution under microwave-assisted heating[J]. J. Membr. Sci., 2016,512:83-92. doi: 10.1016/j.memsci.2016.03.056
30. [30]
  Zhu J, Liu Z D, Endo A, Yanaba Yutaka, Yoshikawa T, Wakihara T, Okubo T. Ultrafast, OSDA-free synthesis of mordenite zeolite[J]. CrystEngComm, 2017,19(4):632-640. doi: 10.1039/C6CE02237E
31. [31]
  Bronić J, Palčić A, Subotić B, Itani L, Valtchev V. Influence of alkalinity of the starting system on size and morphology of the zeolite A crystals[J]. Mater. Chem. Phys., 2012,132(2/3):973-976.
32. [32]
  Xie Z K, Chen Q L, Chen B, Zhang C F. Influence of alkalinity on particle size distribution and crystalline structure in synthesis of zeolite beta[J]. Cryst. Eng., 2001,4(4):359-372. doi: 10.1016/S1463-0184(01)00027-2
33. [33]
  Ren N, Bronić J, Subotić B, Lv X C, Yang Z J, Tang Y. Controllable and SDA-free synthesis of sub-micrometer sized zeolite ZSM-5. Part 1: Influence of alkalinity on the structural, particulate and chemical properties of the products[J]. Microporous Mesoporous Mat., 2011,139(1/2/3):197-206.
34. [34]
  Torres J C, Cardoso D. The influence of gel alkalinity in the synthesis and physicochemical properties of the zeolite[Ti, Al]-Beta[J]. Microporous Mesoporous Mat., 2008,113(1/2/3):204-211.
35. [35]
  Suzuki Y, Wakihara T, Itabashi K, Ogura M, Okubo T. Cooperative effect of sodium and potassium cations on synthesis of ferrierite[J]. Top Catal., 2009,52:67-74. doi: 10.1007/s11244-008-9136-6
36. [36]
  Zhu M H, Hua X M, Liu Y S, Hu H L, Li Y Q, Hu N, Kumakiri I, Chen X S, Kita H. Influences of synthesis parameters on preparation of acid-stable and reproducible mordenite membrane[J]. Ind. Eng. Chem. Res., 2016,55(47):12268-12275. doi: 10.1021/acs.iecr.6b02125
37. [37]
  Chen X X, Wang J Q, Yin D H, Yang J H, Lu J M, Zhang Y, Chen Z. High-performance zeolite T membrane for dehydration of organics by a new varying temperature hot-dip coating method[J]. AIChE J., 2013,59(3):936-947. doi: 10.1002/aic.13851
38. [38]
  Li Y Q, Zhu M H, Hu N, Zhang F, Wu T, Chen X S, Kita H. Scale-up of high performance mordenite membranes for dehydration of water-acetic acid mixtures[J]. J. Membr. Sci., 2018,564:174-183. doi: 10.1016/j.memsci.2018.07.024
39. [39]
  Li G, Kikuchi E, Matsukata M. Separation of water-acetic acid mixtures by pervaporation using a thin mordenite membrane[J]. Sep. Purif. Technol., 2003,32(1/2/3):199-206.
40. [40]
  Zhu M H, Xia S L, Hua X M, Feng Z J, Hu N, Zhang F, Kumakiri I, Lu Z H, Chen X S, Kita H. Rapid preparation of acid-stable and high dehydration performance mordenite membranes[J]. Ind. Eng. Chem. Res., 2014,53(49):19168-19174. doi: 10.1021/ie501248y
41. [41]
  Zhou R F, Hu Z L, Hu N, Duan L Q, Chen X S, Kita H. Preparation and microstructural analysis of high-performance mordenite membranes in fluoride media[J]. Microporous Mesoporous Mat., 2012,156:166-170. doi: 10.1016/j.micromeso.2012.02.023
42. [42]
  Zhang F, Xu L N, Hu N, Bu N, Zhou R F, Chen X S. Preparation of NaY zeolite membranes in fluoride media and their application in dehydration of bio-alcohols[J]. Sep. Purif. Technol., 2014,129:9-17. doi: 10.1016/j.seppur.2014.03.018
43. [43]
  Shafiei K, Pakdehi S G, Moghaddam M K, Mohammadi T. Improvement of zeolite T membrane via clear solution gel in dehydration of methanol, ethanol, and 2-propanol[J]. Sep. Sci. Technol., 2014,49(6):797-802. doi: 10.1080/01496395.2013.870576
44. [44]
  Kondo M, Kita H. Permeation mechanism through zeolite NaA and T-type membranes for practical dehydration of organic solvents[J]. J. Membr. Sci., 2010,361(1/2):223-231.
45. [45]
  Wang S, Li L Q, Li J J, Wang J X, Pan E Z, Lu J M, Zhang Y, Yang J H. Sustainable synthesis of highly water-selective ZSM-5 membrane by wet gel conversion[J]. J. Membr. Sci., 2021,635119431. doi: 10.1016/j.memsci.2021.119431
1. [1]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
2. [2]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
3. [3]
  Yinuo Wu , Jiantao Ye , Xie Zhou , Yu Qian , Lei Guo . Teaching Design of Basic Chemistry Based on PBL Methodology for Medical Undergraduates: A Case Study on “Osmotic Pressure of Solution”. University Chemistry, 2024, 39(3): 149-157. doi: 10.3866/PKU.DXHX202309077
4. [4]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
5. [5]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
6. [6]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
7. [7]
  Weihua Jiang , Yongsheng Zhou , Qiaoqiao Teng . Progressive Teaching Model in the Practice and Exploration of Ideological and Political Education in Laboratory Courses: Taking the Organic Chemistry Experiment “Synthesis of Aspirin” as an Example. University Chemistry, 2024, 39(2): 99-104. doi: 10.3866/PKU.DXHX202306028
8. [8]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
9. [9]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
10. [10]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
13. [13]
  Jiantao Zai , Hongjin Chen , Xiao Wei , Li Zhang , Li Ma , Xuefeng Qian . The Learning-Centered Problem-Oriented Experimental Teaching. University Chemistry, 2024, 39(4): 40-47. doi: 10.3866/PKU.DXHX202309023
14. [14]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
15. [15]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
16. [16]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
17. [17]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
18. [18]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
19. [19]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
20. [20]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(378)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142