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Citation: Zhanggui DUAN, Yi PEI, Shanshan ZHENG, Zhaoyang WANG, Yongguang WANG, Junjie WANG, Yang HU, Chunxin LÜ, Wei ZHONG. Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317 shu

Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation

  • College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China

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  • In this study, a composite of Cu-Cu2O/UiO-66-NH2 based on a metal-organic framework (MOF) was successfully prepared by solvothermal method, and it was comprehensively characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The effects of solvent, temperature, and catalyst loading on the oxidation of benzyl alcohol to benzaldehyde were investigated using air as an oxidant. The composite catalyst showed excellent catalytic performance, and benzyl alcohol could be quantitatively converted to benzaldehyde at 60 ℃ for 5 h. Additionally, other alcohol substrates such as benzylic alcohols, allylic alcohols, and heteroaryl alcohols, were selectively transformed into the corresponding aldehydes in excellent yields. Notably, the activity of the catalyst was almost unchanged after three cycles of recycling, demonstrating good stability and reusability.
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