Citation: Jie ZHANG, Xin LIU, Zhixin LI, Yuting PEI, Yuqi YANG, Huimin LI, Zhiqiang LIU. Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310 shu

Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection

Jie ZHANG ^{1, 2} ,
Xin LIU ¹ ,
Zhixin LI ¹ ,
Yuting PEI ¹ ,
Yuqi YANG ¹ ,
Huimin LI ¹ ,
Zhiqiang LIU ^3,,

1.
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China
2.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
3.
Anhui Key Laboratory of Photoelectric-Magnetic Functional Materials, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, Anhui 246133, China

Corresponding author: Zhiqiang LIU, liuzhiqiang711@126.com; liuzhiqiang@aqnu.edu.cn
Received Date: 15 August 2023
Revised Date: 4 January 2024

Figures(9)

A unique 3D luminescent metal-organic framework, namely [Cd(L)(H₂O)_0.5]·DMF·2.5H₂O (1), where H₂L=3-(tetrazol-5-yl)triazole, has been successfully prepared and characterized. The framework has demonstrated excellent luminescence properties and structural stability in the water system. Notably, the luminescence intensity of 1 was significantly quenched by Cr(Ⅵ) (1 mL of Cr₂O₇^2- or 150 μL of CrO₄^2-, 1 mmol·L^-1), leading to the formation of an "on-off" luminescence silencing system (Cr₂O₇^2-@1), which was capable of accurately detecting Cr(Ⅵ) in the water system. The primary mechanism responsible for luminescence quenching was the Forster resonance energy transfer (FRET) process. Additionally, by removing the involvement of the FRET process, the luminescence intensity of the Cr₂O₇^2-@1 system could be restored, allowing for the highly selective and sensitive detection of ascorbic acid (AA) in water systems. Moreover, it has been demonstrated that 1 can successfully detect AA in vitamin C tablets, yielding recovery rates ranging from 98.20% to 103.33% and relative standard deviations (RSDs) ranging from 1.78% to 3.42%. Based on the findings of this experiment, a luminescent "IMPLICATION" molecular logic gate has been constructed utilizing AA and Cr(Ⅵ) as the chemical inputs, respectively.
- luminescence silencing,
- metal-organic framework,
- Cr(Ⅵ),
- ascorbic acid
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