Citation: Huan ZHANG, Jijiang WANG, Guang FAN, Long TANG, Erlin YUE, Chao BAI, Xiao WANG, Yuqi ZHANG. A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291 shu

A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol

Huan ZHANG ¹ ,
Jijiang WANG ^1,, ,
Guang FAN ^2,, ,
Long TANG ¹ ,
Erlin YUE ¹ ,
Chao BAI ¹ ,
Xiao WANG ¹ ,
Yuqi ZHANG ¹

1.
Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
2.
Department of Chemistry and Chemical Engineering, Xianyang Normal University, Xiangyang, Shaanxi 712000, China

Corresponding author: Jijiang WANG, yadxwjj@126.com Guang FAN, fanguang2004@163.com
Received Date: 3 August 2023
Revised Date: 17 December 2023

Figures(6)

A new metal-organic framework (MOF) {[Cd(L)_0.5(4, 4'-bpy)_0.5]·H₂O}_n (1), where H₄L=(1, 1': 4', 1″-terphenyl)-2, 2″, 4, 4″-tetracarboxylic acid, 4, 4'-bpy=4, 4'-bipyridine, was synthesized by hydro-solvothermal method. The structure of complex 1 was characterized by single-crystal X-ray diffraction, elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and infrared spectrum analysis. The analysis of single crystal structure shows that 1 is a 3D structure, belonging to the monoclinic crystal system, C2/c space group. Cd(Ⅱ) connects L^4- and 4, 4'-bpy to form a 2D plane structure, and the layers are connected by L^4- to form a 3D network structure. The MOF shows good stability and can be used for the detection of tetracycline (TET) and p-nitrophenol (4-NP) by fluorescence quenching. The detection limits of TET and 4-NP were 0.15 and 0.062 μmol·L^-1, respectively. In addition, the fluorescence quenching mechanism of 1 was also studied. 1 can be successfully applied to the determination of TET and 4-NP content in Yanhe water samples.
- metal-organic framework,
- crystal structure,
- tetracycline,
- p-nitrophenol
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