Citation: Huan ZHANG, Jijiang WANG, Guang FAN, Long TANG, Erlin YUE, Chao BAI, Xiao WANG, Yuqi ZHANG. A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291 shu

A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol

Huan ZHANG ¹ ,
Jijiang WANG ^1,, ,
Guang FAN ^2,, ,
Long TANG ¹ ,
Erlin YUE ¹ ,
Chao BAI ¹ ,
Xiao WANG ¹ ,
Yuqi ZHANG ¹

1.
Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
2.
Department of Chemistry and Chemical Engineering, Xianyang Normal University, Xiangyang, Shaanxi 712000, China

Corresponding author: Jijiang WANG, yadxwjj@126.com Guang FAN, fanguang2004@163.com
Received Date: 3 August 2023
Revised Date: 17 December 2023

Figures(6)

A new metal-organic framework (MOF) {[Cd(L)_0.5(4, 4'-bpy)_0.5]·H₂O}_n (1), where H₄L=(1, 1': 4', 1″-terphenyl)-2, 2″, 4, 4″-tetracarboxylic acid, 4, 4'-bpy=4, 4'-bipyridine, was synthesized by hydro-solvothermal method. The structure of complex 1 was characterized by single-crystal X-ray diffraction, elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and infrared spectrum analysis. The analysis of single crystal structure shows that 1 is a 3D structure, belonging to the monoclinic crystal system, C2/c space group. Cd(Ⅱ) connects L^4- and 4, 4'-bpy to form a 2D plane structure, and the layers are connected by L^4- to form a 3D network structure. The MOF shows good stability and can be used for the detection of tetracycline (TET) and p-nitrophenol (4-NP) by fluorescence quenching. The detection limits of TET and 4-NP were 0.15 and 0.062 μmol·L^-1, respectively. In addition, the fluorescence quenching mechanism of 1 was also studied. 1 can be successfully applied to the determination of TET and 4-NP content in Yanhe water samples.
- metal-organic framework,
- crystal structure,
- tetracycline,
- p-nitrophenol
1. [1]
  Meng L, Lan C W, Liu Z H, Xu N, Wu Y Q. A novel ratiometric fluorescence probe for highly sensitive and specific detection of chlorotetracycline among tetracycline antibiotics[J]. Anal. Chim. Acta, 2019,1089:144-151. doi: 10.1016/j.aca.2019.08.065
2. [2]
  Li C H, Zhu L, Yang W X, He X, Zhao S L, Zhang X S, Tang W Z, Wang J L, Yue T L, Li Z H. Amino-functionalized Al-MOF for fluorescent detection of tetracyclines in milk[J]. J. Agric. Food Chem., 2019,67(4):1277-1283. doi: 10.1021/acs.jafc.8b06253
3. [3]
  Thangavelu D, Chen Y F, Annamalai P, Ramadoss M, Narayanan V. Rationally designed Ag@polymer@2-D LDH nanoflakes for bifunctional efficient electrochemical sensing of 4-nitrophenol and water oxidation reaction[J]. ACS Appl. Mater. Interfaces, 2022,14(5):6518-6527. doi: 10.1021/acsami.1c19077
4. [4]
  Hu L L, Peng F, Xia D H, He H J W, He C, Fang Z K, Yang J L, Tian S H, Sharma V K, Shu D. Carbohydrates-derived nitrogen-doped hierarchical porous carbon for ultrasensitive detection of 4-nitrophenol[J]. ACS Sustainable Chem. Eng., 2018,6(12):17391-17401. doi: 10.1021/acssuschemeng.8b05169
5. [5]
  Wang Z J, Qin L, Chen J X, Zheng H G. H-bonding interactions induced two isostructural Cd(Ⅱ) metal-organic frameworks showing different selective detection of nitroaromatic explosives[J]. Inorg. Chem., 2016,55(21):10999-11005. doi: 10.1021/acs.inorgchem.6b01521
6. [6]
  Pan M Q, Yang R Q, Muhammad Y, Cai K T, Han F, Zhang H C, Niu Y Q, Wang H. Crystal structure, Fe³⁺ luminescence sensing and color tuning of 2D lanthanide-metal-organic frameworks constructed from tricarboxylic acid ligand[J]. Chin. J. Struct. Chem., 2022,41(2)2202023.
7. [7]
  Sun H P, Li Z X, Gu Y, Guo C X. A review on the progress of metal-organic frameworks in electrochemiluminescence sensors[J]. Chin. J. Struct. Chem., 2022,41(11)2211018.
8. [8]
  Liang N N, Hu X T, Zhang X A, Li W T, Guo Z, Huang X W, Li Z H, Zhang R J, Shen T T, Zou X B, Shi J Y. Ratiometric sensing for ultratrace tetracycline using electrochemically active metal-organic frameworks as response signals[J]. J. Agric. Food Chem., 2023,71(19):7584-7592. doi: 10.1021/acs.jafc.3c00846
9. [9]
  Zhao Y F, Zeng H, Zhu X W, Lu W G, Li D. Metal-organic frameworks as photoluminescent biosensing platforms: Mechanisms and applications[J]. Chem. Soc. Rev., 2021,50(7):4484-4513. doi: 10.1039/D0CS00955E
10. [10]
  Liang Q N, Chen J M, Wang F L, Li Y W. Transition metal-based metal-organic frameworks for oxygen evolution reaction[J]. Coord. Chem. Rev., 2020,424:213488-213511. doi: 10.1016/j.ccr.2020.213488
11. [11]
  Sakamoto N, Nishimura Y F, Nonaka T, Ohashi M, Ishida N, Kitazumi K, Kato Y, Sekizawa K, Morikawa T, Arai T. Self-assembled cuprous coordination polymer as a catalyst for CO₂ electrochemical reduction into C₂ products[J]. ACS Catal., 2020,10(18):10412-10419. doi: 10.1021/acscatal.0c01593
12. [12]
  Yousefi R, Asgari S, Banitalebi Dehkordi A, Mohammadi Ziarani G, Badiei A, Mohajer F, Varma R S, Iravani S. MOF-based composites as photoluminescence sensing platforms for pesticides: Applications and mechanisms[J]. Environ. Res., 2023,226115664. doi: 10.1016/j.envres.2023.115664
13. [13]
  Zhang R Y, Zhu L L, Yue B B. Luminescent properties and recent progress in applications of lanthanide metal-organic frameworks[J]. Chin. Chem. Lett., 2023,34(2)108009. doi: 10.1016/j.cclet.2022.108009
14. [14]
  Yeston J. Americium in a MOF[J]. Science, 2019,366:69-70. doi: 10.1126/science.2019.366.6461.twil
15. [15]
  Liang Y, Xu X D, Ni J L, Li J F, Wang F M. Synthesis, structure and fluorescence property of new Cd-MOFs based on a tetraphenylethylene (TPE) ligand[J]. Chin. J. Struct. Chem., 2021,40(2):193-198.
16. [16]
  Li R W, Yan J T, Feng B, Sun M, Ding C F, Shen H, Zhu J H, Yu S N. Ultrasensitive detection of multidrug-resistant bacteria based on boric acid-functionalized fluorescent MOF@COF[J]. ACS Appl. Mater. Interfaces, 2023,15(15):18663-18671. doi: 10.1021/acsami.3c00632
17. [17]
  Hu Y L, Dai L M, Liu D H, Du W, Wang Y J. Progress & prospect of metal-organic frameworks (MOFs) for enzyme immobilization (enzyme/MOFs)[J]. Renew. Sust. Energ. Rev., 2018,91:793-801. doi: 10.1016/j.rser.2018.04.103
18. [18]
  Khalil I E, Fonseca J, Reithofer M R, Eder T, Chin J M. Tackling orientation of metal-organic frameworks (MOFs): The quest to enhance MOF performance[J]. Coord. Chem. Rev., 2023,481215043. doi: 10.1016/j.ccr.2023.215043
19. [19]
  Bhattacharya S, Bhattacharyya A J, Natarajan S. High proton mobility, solvent induced single crystal to single crystal structural transformation, and related studies on a family of compounds formed from Mn₃ oxo-clusters[J]. Inorg. Chem., 2015,54(4):1254-1271. doi: 10.1021/ic5018517
20. [20]
  Yang X G, Zhang J R, Tian X K, Qin J H, Zhang X Y, Ma L F. Enhanced activity of enzyme immobilized on hydrophobic ZIF-8 modified by Ni²⁺ ions[J]. Angew. Chem. Int. Ed., 2023,62(7)e202216699. doi: 10.1002/anie.202216699
21. [21]
  Zhao X, Wang Y X, Li D S, Bu X H, Feng P Y. Metal-organic frameworks for separation[J]. Adv. Mater., 2018,30(37)e1705189. doi: 10.1002/adma.201705189
22. [22]
  Wang W, Wang Y X, Yang H B. Supramolecular transformations within discrete coordination-driven supramolecular architectures[J]. Chem. Soc. Rev., 2016,45(9):2656-2693. doi: 10.1039/C5CS00301F
23. [23]
  Kole G K, Vittal J J. Solid-state reactivity and structural transformations involving coordination polymers[J]. Chem. Soc. Rev., 2013,42(4):1755-1775. doi: 10.1039/C2CS35234F
24. [24]
  Chandrasekhar P, Mukhopadhyay A, Savitha G, Savitha G, Moorthy J N. Remarkably selective and enantiodifferentiating sensing of histidine by a fluorescent homochiral Zn-MOF based on pyrene-tetralactic acid[J]. Chem. Sci., 2016,7(5):3085-3091. doi: 10.1039/C5SC03839A
25. [25]
  Wang S Q, Wang L, Zhu Y M, Song Y H. Fluorescent detection of S^2- based on ZnMOF-74 and CuMOF-74[J]. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2020,236118327. doi: 10.1016/j.saa.2020.118327
26. [26]
  Farahani Y D, Safarifard V. Highly selective detection of Fe³⁺, Cd²⁺ and CH₂Cl₂ based on a fluorescent Zn-MOF with azine-decorated pores[J]. J. Solid State Chem., 2019,275:131-140. doi: 10.1016/j.jssc.2019.04.018
27. [27]
  CHEN X L, LIU L, SHANG L, CAI M, CUI H L, YANG H, WANG J J. A highly sensitive and multi-responsive Zn-MOF fluorescent sensor for detection of Fe³⁺, 2, 4, 6-trinitrophenol, and ornidazole[J]. Chinese J. Inorg. Chem., 2022,38(4):735-744.
28. [28]
  Ma Y S, Zhang X M, Bai J L, Huang K, Ren L L. Facile, controllable tune of blue shift or red shift of the fluorescence emission of solid-state carbon dots[J]. Chem. Eng. J., 2019,374:787-792. doi: 10.1016/j.cej.2019.06.016
29. [29]
  Liu L, Chen Q, Lv J, Li Y P, Wang K C, Li J R. Stable metal-organic frameworks for fluorescent detection of tetracycline antibiotics[J]. Inorg. Chem., 2022,61(20):8015-8021. doi: 10.1021/acs.inorgchem.2c00754
30. [30]
  Singh H, Thakur B, Bhardwaj S K, Khatri M, Kim K H, Bhardwaj N. Nanomaterial-based fluorescent biosensors for the detection of antibiotics in foodstuffs: A review[J]. Food Chem., 2023,426(15)136657.
31. [31]
  Lee J Y, Root H D, Ali R, An W, Lynch V M, Bähring S, Kim I S, Sessler J L, Park J S. Ratiometric turn-on fluorophore displacement ensembles for nitroaromatic explosives detection[J]. J. Am. Chem. Soc., 2020,142(46):19579-19587. doi: 10.1021/jacs.0c08106
32. [32]
  Ma Y X, Li H, Peng S, Wang L Y. Highly selective and sensitive fluorescent paper sensor for nitroaromatic explosive detection[J]. Anal. Chem., 2012,84(19):8415-8421. doi: 10.1021/ac302138c
33. [33]
  Dang S, Ma E, Sun Z M, Zhang H J. A layer-structured Eu-MOF as a highly selective fluorescent probe for Fe³⁺ detection through a cation-exchange approach[J]. J. Mater. Chem. C, 2012,22:16920-16926. doi: 10.1039/c2jm32661b
34. [34]
  Chen Z, Sun Y W, Zhang L L, Sun D, Liu F L, Meng Q G, Wang R M, Sun D F. A tubular europium-organic framework exhibiting selective sensing of Fe³⁺ and Al³⁺ over mixed metal ions[J]. Chem. Commun., 2013,49:11557-11559. doi: 10.1039/c3cc46613b
35. [35]
  Jung H S, Verwilst P, Kim W Y, Kim J S. Fluorescent and colorimetric sensors for the detection of humidity or water content[J]. Chem. Soc. Rev., 2016,45(5):1242-1256. doi: 10.1039/C5CS00494B
36. [36]
  Sun X C, Wang Y, Yu L. Fluorescence based explosive detection: From mechanisms to sensory materials[J]. Chem. Soc. Rev., 2015,44(22):8019-8061. doi: 10.1039/C5CS00496A
37. [37]
  Zhang Y Z, Xiang X, Mei P, Dai J, Zhang L L, Liu L. Spectroscopic studies on the interaction of Congo Red with bovine serum albumin[J]. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2009,72(4):907-914. doi: 10.1016/j.saa.2008.12.007
38. [38]
  Xu H, Gao J K, Qian X F, Wang J P, He H J, Cui Y J, Yang Y, Wang Z Y, Qian G D. Metal-organic framework nanosheets for fast-response and highly sensitive luminescent sensing of Fe³⁺[J]. J. Mater. Chem. A, 2016,4(28):10900-10905. doi: 10.1039/C6TA03065C
39. [39]
  XU X Y, CUI H L, LIU W, CHEN X L, YANG H, LIU L, WANG J J. Synthesis and fluorescence sensing for Fe³⁺ and p-nitrophenol of a copper coordination polymer[J]. Chinese J. Inorg. Chem., 2022,38(12):2539-2549.
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