Citation: Wenjing SHANG, Xin DENG, Binghao WANG, Yiqin TIAN, Xiang LI, Yongbing LOU, Jinxi CHEN. Preparation and electrocatalytic performance of MoSe2/Co-MOF/NF for oxygen evolution reaction[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 79-87. doi: 10.11862/CJIC.20230284 shu

Preparation and electrocatalytic performance of MoSe2/Co-MOF/NF for oxygen evolution reaction

  • Corresponding author: Jinxi CHEN, chenjinxi@seu.edu.cn
  • Received Date: 31 July 2023
    Revised Date: 4 December 2023

Figures(10)

  • Designing efficient oxygen evolution reaction (OER) catalysts is crucial for water splitting to produce hydrogen. Based on the catalytic activity of transition metal selenides (TMSe) and the structural characteristics of metal-organic frameworks (MOFs), the work proposed a strategy to compound MOFs and TMSe. The composite material grew on conductive base nickel foam (NF) inherited the advantages of the two materials, and the defects of poor conductivity of MOFs and easy aggregation of TMSe were effectively improved. The MoSe2/Co -MOF/NF showed excellent electrochemical performance in alkaline solution, and its overpotential was only 242 mV at 10 mA·cm-2, the Tafel slope was 50.64 mV·dec-1. In addition, it exhibited good stability in an alkaline solution after 1 000 cyclic voltammetry (CV) cycles and 30 h constant voltage electrolysis test.
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    1. [1]

      Wang Z H, Zhou T, Chen Z, Gu R Z, Tao J W, Fan Z W, Guo L Y, Liu Y S. Three-dimensional strawlike MoSe2-Ni (Fe) Se electrocatalysts for overall water splitting[J]. Inorg Chem., 2023,62:2894-2904. doi: 10.1021/acs.inorgchem.2c04354

    2. [2]

      Chang Y, Zhai P L, Hou J G, Zhao J J, Gao J F. Excellent HER and OER catalyzing performance of Se-vacancies in defects-engineered PtSe 2:From simulation to experiment[J]. Adv. Energy Mater., 2021,122102359.

    3. [3]

      Kim E J, Shin J, Bak J, Lee S J, Kim K H, Song D H, Roh J H, Lee Y J, Kim H W, Lee K S, Cho E A. Stabilizing role of Mo in TiO2-MoOx supported Ir catalyst toward oxygen evolution reaction[J]. Appl. Catal. B-Environ., 2021,280119433. doi: 10.1016/j.apcatb.2020.119433

    4. [4]

      Xu X Y, Zhao W F, Wang L, Gao S, Li Z, Hu J C, Jiang Q Q. Anion substitution induced vacancy regulating of cobalt sulfoselenide toward electrocatalytic overall water splitting[J]. J. Colloid Interface Sci., 2023,630:580-590. doi: 10.1016/j.jcis.2022.09.073

    5. [5]

      Zhang X H, Wu A P, Wang D X, Jiao Y Q, Yan H J, Jin C X, Xie Y, Tian C G. Fine-tune the electronic structure in Co-Mo based catalysts to give easily coupled HER and OER catalysts for effective water splitting[J]. Appl. Catal. B-Environ., 2023,328122474. doi: 10.1016/j.apcatb.2023.122474

    6. [6]

      Shang W J, Li Q L, Li X, Zhang K, Wang B H, Lou Y B, Chen J X. 2D iron/cobalt metal-organic frameworks with an extended ligand for efficient oxygen evolution reaction[J]. Dalton Trans., 2023,52:8613-8619. doi: 10.1039/D3DT01175E

    7. [7]

      Jamesh M I, Sun X M. Recent progress on earth abundant electrocatalysts for oxygen evolution reaction (OER) in alkaline medium to achieve efficient water splitting-A review[J]. J. Power Sources, 2018,400:31-68. doi: 10.1016/j.jpowsour.2018.07.125

    8. [8]

      Wang Y N, Du Z Y, Xu J, Meng Z S, Zhang C X, Cui Y N, Li Y X, Jiang C, Zeng Y, Yu S S, Tian H W. Improved catalytic activity and stability of Co9S8 by Se incorporation for efficient oxygen evolution reaction[J]. Inorg. Chem., 2022,61:21139-21147. doi: 10.1021/acs.inorgchem.2c03805

    9. [9]

      Wei L T, Du M Y, Zhao R, Lv F, Li L B, Zhang L, Zhou D, Su J Z. High-valence Mo doping for highly promoted water oxidation of NiFe (oxy) hydroxide[J]. J. Mater. Chem. A, 2022,10:23790-23798. doi: 10.1039/D2TA05600C

    10. [10]

      Wygant B R, Poterek A H, Burrow J N, Mullins C B. Effect of selenium content on nickel sulfoselenide-derived nickel (oxy) hydroxide electrocatalysts for water oxidation[J]. ACS Appl. Mater. Interfaces, 2020,12:20366-20375. doi: 10.1021/acsami.0c00425

    11. [11]

      Shaikh N, Mukhopadhyay I, Ray A. Heterointerfaces of nickel sulphides and selenides on Ni-foam as efficient bifunctional electrocatalysts in acidic environments[J]. J. Mater. Chem. A, 2022,10:12733-12746. doi: 10.1039/D2TA01630C

    12. [12]

      Li X Y, Luo D, Jiang F, Zhang K J, Wang S X, Li S F, Zha Q Q, Huang Y C, Ni Y H. Electronic modulation of metal-organic frameworks caused by atomically dispersed Ru for efficient hydrogen evolution[J]. Small, 2023,192301850. doi: 10.1002/smll.202301850

    13. [13]

      Zhang H T, Guo H R, Ren J K, Jin X T, Li X P, Song R. Synergistic engineering of morphology and electronic structure in constructing metal-organic framework-derived Ru doped cobalt-nickel oxide heterostructure towards efficient alkaline hydrogen evolution reaction[J]. Chem. Eng. J., 2021,426131300. doi: 10.1016/j.cej.2021.131300

    14. [14]

      Wang S M, Zhang Y, Deng X Y, Ma Z Z, Cheng R T, Wan Z H, Li J P, Wang X G. Rational construction of loosely packed nickel nanoparticulates with residual HCOO ligands derived from a Ni-MOF for high-efficiency electrocatalytic overall water splitting[J]. J. Mater. Chem. A, 2023,11:5222-5232. doi: 10.1039/D2TA09369C

    15. [15]

      Wu F, Guo X X, Wang Q H, Lu S W, Wang J L, Hu Y B, Hao G Z, Li Q L, Yang M Q, Jiang W. A hybrid of MIL-53(Fe) and conductive sulfide as a synergistic electrocatalyst for the oxygen evolution reaction[J]. J. Mater. Chem. A, 2020,8:14574-14582. doi: 10.1039/D0TA01912G

    16. [16]

      Jin M T, Zhang X, Niu S Z, Wang Q, Huang R Q, Ling R H, Huang J Q, Shi R, Amini A, Cheng C. Strategies for designing high-performance hydrogen evolution reaction electrocatalysts at large current densities above 1000 mA·cm-2[J]. ACS Nano, 2022,16:11577-11597. doi: 10.1021/acsnano.2c02820

    17. [17]

      Xuan C J, Xia K D, Lei W, Xia W W, Xiao W P, Chen L X, Xin H L L, Wang D L. Composition-dependent electrocatalytic activities of NiFe-based selenides for the oxygen evolution reaction[J]. Electrochim. Acta, 2018,291:64-72. doi: 10.1016/j.electacta.2018.08.106

    18. [18]

      Peng X, Yan Y J, Xiong S J, Miao Y P, Wen J, Liu Z T, Gao B, Hu L S, Chu P K. Se-NiSe2 hybrid nanosheet arrays with self-regulated elemental Se for efficient alkaline water splitting[J]. J. Mater. Sci. Tech-nol., 2022,118:136-143. doi: 10.1016/j.jmst.2021.12.022

    19. [19]

      Duan S, Chen S Q, Wang T Y, Li S Z, Liu J Y, Liang J S, Xie H Q, Han J T, Jiao S H, Cao R G, Wang H L, Li Q. Elemental selenium enables enhanced water oxidation electrocatalysis of NiFe layered double hydroxides[J]. Nanoscale, 2019,11:17376-17383. doi: 10.1039/C9NR06169J

    20. [20]

      Chen S, Yu C, Cao Z F, Huang X P, Wang S, Zhong H. Trimetallic NiFeCr-LDH/MoS2 composites as novel electrocatalyst for OER[J]. Int. J. Hydrog. Energy, 2021,46:7037-7046. doi: 10.1016/j.ijhydene.2020.11.249

    21. [21]

      Sahu N, Das J K, Behera J N. NiSe2 nanoparticles encapsulated in N-doped carbon matrix derived from a one-dimensional Ni-MOF: An efficient and sustained electrocatalyst for hydrogen evolution reaction[J]. Inorg. Chem., 2022,61:2835-2845. doi: 10.1021/acs.inorgchem.1c03323

    22. [22]

      Deng S J, Yang F, Zhang Q H, Zhong Y, Zeng Y X, Lin S W, Wang X L, Lu X H, Wang C Z, Gu L, Xia X H, Tu J P. Phase modulation of (1T-2H)-MoSe2/TiC-C shell/core arrays via nitrogen doping for highly efficient hydrogen evolution reaction[J]. Adv. Mater., 2018,301802223. doi: 10.1002/adma.201802223

    23. [23]

      Li Q Q, Wang X Q, Yang N N, He F, Yang Y F, Wu B H, Chu J, Zh ou, A N, Xiong S X. Hydrangea-like NiCo-based bimetal-organic frameworks, and their pros and cons as supercapacitor electrode materials in aqueous electrolytes[J]. Z. Anorg. Allg. Chem., 2019,645:1022-1030. doi: 10.1002/zaac.201900035

    24. [24]

      Zhang T T, Cai Y F, Lou Y B, Chen J X. 1T-2H MoSe2 modified MAPbI 3 for effective photocatalytic hydrogen evolution[J]. J. Alloy. Compd., 2022,893162329. doi: 10.1016/j.jallcom.2021.162329

    25. [25]

      Li W X, Fang W, Wu C, Dinh K N, Ren H, Zhao L, Liu C T, Yan Q Y. Bimetal-MOF nanosheets as efficient bifunctional electrocatalysts for oxygen evolution and nitrogen reduction reaction[J]. J. Mater. Chem. A, 2020,8:3658-3666. doi: 10.1039/C9TA13473E

    26. [26]

      Cheng C C, Cheng P Y, Huang C L, Raja D S, Wu Y J, Lu S Y. Gold nanocrystal decorated trimetallic metal organic frameworks as high performance electrocatalysts for oxygen evolution reaction[J]. Appl. Catal. B-Environ., 2021,286119916. doi: 10.1016/j.apcatb.2021.119916

    27. [27]

      Upadhyay S, Pandey O P. Effect of Se content on the oxygen evolution reaction activity and capacitive performance of MoSe2 nano-flakes[J]. Electrochim. Acta, 2022,412140109. doi: 10.1016/j.electacta.2022.140109

    28. [28]

      Wu J, Yu Z J, Zhang Y Y, Niu S Q, Zhao J Y, Li S W, Xu P. Under-standing the effect of second metal on CoM (M=Ni, Cu, Zn) metalorganic frameworks for electrocatalytic oxygen evolution reaction[J]. Small, 2021,172105150. doi: 10.1002/smll.202105150

    29. [29]

      Chen J S, Li H, Chen S M, Fei J Y, Liu C, Yu Z X, Shin K, Liu Z W, Song L, Henkelman G, Wei L, Chen Y. Co-Fe-Cr (oxy) hydroxides as efficient oxygen evolution reaction catalysts[J]. Adv. Energy Mater, 2021,112003412. doi: 10.1002/aenm.202003412

    30. [30]

      Xin Y, Shen K, Guo T T, Chen L Y, Li Y W. Coupling hydrazine oxidation with seawater electrolysis for energy-saving hydrogen production over bifunctional CoNC nanoarray electrocatalysts[J]. Small, 2023,192300019. doi: 10.1002/smll.202300019

    31. [31]

      Shi F, Wang Z S, Zhu K Y, Zhu X F, Yang W S. Enhancing activity and stability of Co-MOF-74 for oxygen evolution reaction by wrapping polydopamine[J]. Electrochim. Acta, 2022,416140293. doi: 10.1016/j.electacta.2022.140293

    32. [32]

      Hu L, Hu Y W, Liu R, Mao Y C, Balogun M S, Tong Y X. Co-based MOF-derived Co/CoN/Co2P ternary composite embedded in N-and P-doped carbon as bifunctional nanocatalysts for efficient overall water splitting[J]. Int. J. Hydrog. Energy, 2019,44:11402-11410. doi: 10.1016/j.ijhydene.2019.03.157

    33. [33]

      Lv D M, Su S B, Zhang S F, Cai D D. Heterostructured ultrafine metal oxides nanoparticles anchored on Co-MOF nanosheets obtained by partial pyrolysis for promoted oxygen evolution reaction[J]. J. Alloy. Compd., 2022,912165143. doi: 10.1016/j.jallcom.2022.165143

    34. [34]

      Zhang W J, Li F, Fu Z N, Dai S, Pan F H K, Li J X, Zhou L H. Co-MOF Nanosheets etched by FeCl2 solution for enhanced electrocatalytic oxygen evolution[J]. Energy Fuels, 2022,36:4524-4531. doi: 10.1021/acs.energyfuels.2c00417

    35. [35]

      Li T M, Hu B Q, Han J H, Lu W T, Yu F, Li B. Highly effective OER electrocatalysts generated from a two-dimensional metal-organic framework including a sulfur-containing linker without doping[J]. Inorg Chem., 2022,61:7051-7059. doi: 10.1021/acs.inorgchem.2c00493

    36. [36]

      Wang H, Zhang X D, Yin F X, Chu W Y, Chen B H. Coordinately unsaturated metal-organic framework as an unpyrolyzed bifunctional electrocatalyst for oxygen reduction and evolution reactions[J]. J. Mater. Chem. A, 2020,8:22111-22123. doi: 10.1039/D0TA04331A

    37. [37]

      Wang Y R, Wang A N, Xue Z Z, Wang L, Li X Y, Wang G M. Ultrathin metal-organic framework nanosheet arrays and derived self-supported electrodes for overall water splitting[J]. J. Mater. Chem. A, 2021,9:22597-22602. doi: 10.1039/D1TA06360J

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