Citation: Xiaoling LUO, Pintian ZOU, Xiaoyan WANG, Zheng LIU, Xiangfei KONG, Qun TANG, Sheng WANG. Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271 shu

Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand

1.
College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guilin, Guangxi 541004, China
2.
Guangxi Guilin RID Testing & Certification Group, Guilin, Guangxi 541100, China

Corresponding author: Zheng LIU, lisa4.6@163.com Qun TANG, tangq@glut.edu.cn
Received Date: 18 July 2023
Revised Date: 12 April 2024

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The present report deals with the synthesis of the two MOFs of respective formula {[Nd₂(L)₃(DMF)₂(H₂O)₂]·2DMF}_n (1) and {[Gd₂(L)₃(DMF)₂(H₂O)₂]·2DMF}_n (2) were synthesized by solvothermal method using 2, 5-dibromo-terephthalic acid (H₂L) as a ligand and reacting with neodymium nitrate hexahydrate and gadolinium nitrate hexahydrate, respectively. The structures of both of them were elucidated by single-crystal X-ray diffraction and powder X-ray diffraction to demonstrate that complexes 1 and 2 crystallize in a similar space group P1 as a triclinic system with high crystal purity. Meanwhile, the complexes were characterized by elemental analysis, IR spectroscopy, UV-Vis absorption spectroscopy, fluorescence, and thermal analysis. Single-crystal X-ray diffraction analysis demonstrates the complexes are connected to the ligand with rare earth ions as metal nodes, forming an infinitely extended 3D network structure.
- lanthanide series,
- 2, 5-dibromoterephthalic acid,
- metal-organic framework,
- crystal structure
1. [1]
  LIU Y, DUAN X D, REN S S, GE F Y, ZHENG H G. Application of metal-organic frameworks and their derivatives for water splitting and zinc-air batteries[J]. Chinese J. Inorg. Chem., 2024,40(1):15-32.
2. [2]
  Li H L, Eddaoudi E M, O′Keeffe M, Yaghi O M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J]. Nature, 1999,402:276-279. doi: 10.1038/46248
3. [3]
  Ali S M, Emran K M, Alrashedee F M M. Removal of organic pollutants by lanthanide-doped MIL-53(Fe) metal-organic frameworks: Effect of dopant type in magnetite precursor[J]. J. Rare Earths, 2023,41:140-148. doi: 10.1016/j.jre.2022.01.012
4. [4]
  ZHAO T, ZHU H X, DONG M, ZHAO Y. Framework isomerism in chromium-benzenedicarboxylate MOF: MIL-88B(Cr) and MIL-101(Cr)[J]. Chinese J. Inorg. Chem., 2021,37(1):103-109.
5. [5]
  Li R X, Kong X X, Dong J P, Li K Y, Wan T T, Wu H L. Two new Ag-MOFs: Synthesis, structure, electrocatalytic hydrogen evolution and H₂O₂ electrochemical sensing[J]. Inorg. Chim. Acta, 2023,544121208. doi: 10.1016/j.ica.2022.121208
6. [6]
  Qiu L G, Li Z Q, Wu Y, Wang W, Xu T, Jiang X. Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines[J]. Chem. Commun., 2008,31:3642-3644.
7. [7]
  Yang X, Zhang X, Yang N, Yang L, Wang W L, Fang X, He Q. NiCo-MOF nanospheres created by the ultra-fast microwave method for use in high-performance supercapacitors[J]. Molecules, 2023,28(14)5613. doi: 10.3390/molecules28145613
8. [8]
  YANG Y T, TU C Z, WANG F, ZHANG Y, WANG J L, YIN H J, CHENG F X. Flexible bis(imidazole)-based ligands oriented Co(Ⅱ)-glutarate metal-organic frameworks: Syntheses, structures and properties[J]. Chinese J. Inorg. Chem., 2021,37(4):735-743.
9. [9]
  HE X, ZHANG S L, XIAO T Y, ZHU D R. Two metal-organic frameworks built from 2, 2′-dimethyl-4, 4′-biphenyldicarboxylic acid[J]. Chinese J. Inorg. Chem., 2021,37(5):945-952.
10. [10]
  Shi R, Yu L, Tian Y R, Wang X M, Sun Z Y, Qi B, Luo F. pH response luminescence reversible lanthanide-2, 6-pyridinedicarboxylic acid complex with tunable multi-color and white light emission for fluorescent anti-counterfeiting labels and LED[J]. Mater. Chem. Phys., 2022,280125806. doi: 10.1016/j.matchemphys.2022.125806
11. [11]
  Liu X, Sun Y, Lu M H, Pan X M, Wang Z B. Electrochemical and surface analytical studies of transition metal bipyridine dicarboxylic acid complexes as corrosion inhibitors for a mild steel in HCl solution[J]. J. Adhes. Sci. Technol., 2022,36(6):567-583. doi: 10.1080/01694243.2021.1929017
12. [12]
  Tugsuz T, Yuksel D, Gokoglu E, Ates S. A study on the luminescent terbium􀃮 and pyridine 2, 6 dicarboxylate complexes by experimental and TD-DFT approaches[J]. J. Fluoresc., 2022,33(3):1057-1065.
13. [13]
  Albrecht M, Nieger M, Schmidt A. A metal-organic framework constructed of 1, 2-di(pyridin-4-yl)ethyne, terephthalic acid, and zinc(Ⅱ) nitrate[J]. Z. Naturforsch. B, 2014,67(2):103-106.
14. [14]
  Zhou L, Wang S J, Chen Y L, Serre C. Direct synthesis of robust hcp UiO-66(Zr) MOF using poly(ethylene terephthalate) waste as ligand source[J]. Microporous Mesoporous Mat., 2019,290109674. doi: 10.1016/j.micromeso.2019.109674
15. [15]
  Noa F M A, Cheung O, Ahlen M, Ahlberg E, Nehla P, Salazar-Alvarez G, Ershadrad S, Sanyal B, Ohrstrom L. A hexagon based Mn(Ⅱ) rod metal-organic framework-structure, SF₆ gas sorption, magnetism and electrochemistry[J]. Chem. Commun., 2023,59(15):2106-2109. doi: 10.1039/D2CC06916D
16. [16]
  Michida W, Nagai A, Sakuragi M, Okobira T, Kusakabe K. Fluorescence emission behaviors of the L-Cysteine/Au􀃬 complex in a cyclodextrin-based metal-organic framework[J]. Processes, 2020,8(12)1555. doi: 10.3390/pr8121555
17. [17]
  CUI P P, SUN Y, ZHA Y, LIU S N, ZHANG M X, CAO J Y, WANG Q, WANG X Q. Synthesis, structural characterization, and fluorescence property of three coordination polymers with dicarboxylate ligands[J]. Chinese J. Inorg. Chem., 2023,39(12):2358-2366.
18. [18]
  Raduca M, Ene C D, Ionescu S, Florea M, Madalan A M. Coordination polymers and a dinuclear complex constructed from zinc(Ⅱ) ions and fluorescein: Iodine adsorption and optical properties[J]. J. Coord. Chem., 2019,72(8):1222-1237. doi: 10.1080/00958972.2019.1605442
19. [19]
  Kuriyama S, Zhao W H, Nishibayashi Y. Synthesis and characterization of rhodium complex bearing anionic CNC-type pincer ligand with pyrrolide and imidazo[1, 5-a]pyridin-3-ylidene moieties[J]. Z. Anorg. Allg. Chem., 2021,647:1408-1414. doi: 10.1002/zaac.202100065
20. [20]
  Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds. New York: Wiley, 1997: 5603-5604
21. [21]
  Ramya A R, Reddy M L P, Cowley A H, Vasudevan K V. Synthesis, crystal structure, and photoluminescence of homodinuclear lanthanide 4-(dibenzylamino)benzoate complexes[J]. Inorg. Chem., 2010,49(5):2407-2415. doi: 10.1021/ic902257u
22. [22]
  WANG Y, NIE G H, DAN Y M, YANG Y X. Synthesis, characterization and properties of rare earth complex Nd(C₅H₈NO₃)₂(C₃H₅N₂)₂Cl₃·4H₂O[J]. Journal of Xinyang Normal University (Natural Science Edition), 2009,22(2):261-264. doi: 10.3969/j.issn.1003-0972.2009.02.026
23. [23]
  Ilichev V A, Rozhkov V A, Rumyantcev R V, Fukin G K, Grishin I D, Dmitriev A V, Lypenko D A, Maltsev E I, Yablonskiy A N, Andreev B A, Bochkarev M N. LMCT facilitated room temperature phosphorescence and energy transfer in substituted thiophenolates of Gd and Yb[J]. Dalton Trans., 2017,46(9):3041-3050. doi: 10.1039/C6DT04519G
24. [24]
  Demesh M P, Yasukevich A S, Shekhovtsov A N, Kosmyna M B, Paszkowicz W, Kuleshov V. Compositional dependence of spectroscopic properties of Nd³⁺ ions in binary calcium orthovanadates[J]. J. Lumin., 2020,224117270. doi: 10.1016/j.jlumin.2020.117270
25. [25]
  SONG H H, YANG F, WANG J Y, SHI S K. Synthesis and fluorescence properties of terbium phthalate doped (Yttrium, Gadolinium) complexes[J]. Spectrosc. Spect. Anal., 2007,27(10):2093-2097.
26. [26]
  Irfan M F, Arami-Niya A. Temperature effect on the synthesis of iron-cobalt nano-particles using catalytic chemical vapor deposition of CO₂ in thermo-gravimetric analyzer: Analytical and thermodynamic studies[J]. Nano-Structures & Nano-Objects, 2019,18100261.
27. [27]
  HU W H. Preparation and properties of benzoxazine-based hydrophilic and hydrophobic reversible coatings. Taiyuan: North University of China, 2020: 19-20
28. [28]
  Jiang Y, Wang J, Liu B, Jiang W, Zhou T Y, Ma Y C, Che G B, Liu G B. Superhydrophilic N, S, O-doped Co/CoO/Co₉S₈@carbon derived from metal-organic framework for activating peroxymonosulfate to degrade sulfamethoxazole: Performance, mechanism insight and large-scale application[J]. Chem. Eng. J., 2022,446137361. doi: 10.1016/j.cej.2022.137361
29. [29]
  Liu G C, Li Y, Chi J, Xu N, Wang X L, Lin H Y, Chen Y Q. Multi-functional fluorescent responses of cobalt complexes derived from functionalized amide-bridged ligand[J]. Dyes Pigment., 2020,174108064. doi: 10.1016/j.dyepig.2019.108064
30. [30]
  Li Y L, Wang H L, Zhu Z H, Liang F P, Zou H H. Recent advances in the structural design and regulation of lanthanide clusters: Formation and self-assembly mechanisms[J]. Coord. Chem. Rev., 2023,493215322. doi: 10.1016/j.ccr.2023.215322
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