Citation: Yuanchao LI, Weifeng HUANG, Pengchao LIANG, Zifang ZHAO, Baoyan XING, Dongliang YAN, Li YANG, Songlin WANG. Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252 shu

Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites

1.
School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China
2.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: Yuanchao LI, liyuanchaozzu@126.com Zifang ZHAO, zzf@hist.edu.cn
Received Date: 2 July 2023
Revised Date: 23 January 2024

Figures(10)

LiMn_0.8Fe_0.2PO₄/C composite was synthesized using sucrose and graphite as heterogeneous carbon sources through a solid-state method assisted by aqueous rheological phase. The effect of different addition methods of graphite on electrochemical performances was studied. The LiMn_0.8Fe_0.2PO₄/C composite was characterized by the X-ray diffraction (XRD), N₂ adsorption-desorption, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results showed that different graphite coating processes had obvious effects on the structure and electrochemical properties of the materials. The sample, which the graphite was added after the precursor was calcined, showed a high purity and uniform elliptic morphology. And its specific discharge capacity was 149 mAh·g^-1 (87% of the theoretical specific capacity) at 0.1C. The specific discharge capacity was 133 mAh·g^-1 at 5C. After 300 cycles at 2C, its capacity was maintained at 127 mAh·g^-1, whose decay rate was 1.9%, showing excellent electrochemical performances.
- LiMn_0.8Fe_0.2PO₄/C,
- secondary coating,
- aqueous rheological phase,
- cathode material,
- Li-ion battery
1. [1]
  Shi J J, Wang Z G, Fu Y Q. Density functional theory study of lithium diffusion at the interface between olivine-type LiFePO₄ and LiMnPO₄[J]. J. Phys. D-Appl. Phys., 2016,49(50):505601-505606. doi: 10.1088/0022-3727/49/50/505601
2. [2]
  Gnewuch S, Rodriguez E E. Distinguishing the intrinsic antiferromagnetism in polycrystalline LiCoPO₄ and LiMnPO₄ olivines[J]. Inorg. Chem., 2020,59(9):5883-5895. doi: 10.1021/acs.inorgchem.9b03545
3. [3]
  SHANG W L, KONG L Y, CHEN L Z, HUANG S Z, TANG Y, REN C. Preparation and electrochemical performance of LiMn_0.6Fe_0.4PO₄/C with high energy density[J]. Chinese J. Inorg. Chem., 2019,35(3):485-492.
4. [4]
  WU X Y, RUAN D S, MAO L L, FENG M H, LI B. Mn doped LiFePO₄ cathode material: Solvothermal preparation and electrochemical performance[J]. Chinese J. Inorg. Chem., 2021,37(8):1399-1406.
5. [5]
  Budumuru A K, Viji M, Jena A, Nanda B R K, Sudakar C. Mn substitution controlled Li-diffusion in single crystalline nanotubular LiFePO₄ high rate-capability cathodes: Experimental and theoretical studies[J]. J. Power Sources, 2018,406:50-62. doi: 10.1016/j.jpowsour.2018.10.020
6. [6]
  Wang C, Li S H, Han Y Y, Lu Z D. Assembly of LiMnPO₄ nanoplates into microclusters as a high-performance cathode in lithium-ion batteries[J]. ACS Appl. Mater. Interfaces, 2017,9(33):27618-27624. doi: 10.1021/acsami.7b05868
7. [7]
  Lei Z H, Wang J L, Yang J, Nuli Y N, Ma Z F. Nano-/microhierarchical-structured LiMn_0.85Fe_0.15PO₄ cathode material for advanced lithium ion battery[J]. ACS Appl. Mater. Interfaces, 2018,10(50):43552-43560. doi: 10.1021/acsami.7b04193
8. [8]
  Xie Y, Yu H T, Yi T F, Zhu Y R. Understanding the thermal and mechanical stabilities of olivine-type LiMPO₄ (M=Fe, Mn) as cathode materials for rechargeable lithium batteries from first principles[J]. ACS Appl. Mater. Interfaces, 2014,6(6):4033-4042. doi: 10.1021/am4054833
9. [9]
  Kellerman D, Medvedeva N, Mukhina N, Semenova A, Baklanova I, Perelyaeva L, Gorshkov V. Vanadium doping of LiMnPO₄: Vibrational spectroscopy and first-principle studies[J]. Chem. Phys. Lett., 2014,591:21-24. doi: 10.1016/j.cplett.2013.10.087
10. [10]
  Li Z F, Ren X, Zheng Y, Tian W C, An L W, Sun J C, Ding R Q, Wen L Z, Liang G C. Effect of Ti doping on LiFePO₄/C cathode material with enhanced low-temperature electrochemical performance[J]. Ionics, 2020,26(4):1599-1609. doi: 10.1007/s11581-019-03408-4
11. [11]
  Jung Y H, Park W B, Pyo M, Sohn K S, Ahn D. A multi-element doping design for a high-performance LiMnPO₄ cathode via metaheuristic computation[J]. J. Mater. Chem. A, 2017,5(19):8939-8945. doi: 10.1039/C6TA10228J
12. [12]
  Wu K P, Yin S, Wang S, Zhu J L, Yao W T. Construction of submicron-sized LiFe_0.4Mn_0.6PO₄/C enwrapped into graphene framework for advanced Li-storage[J]. Carbon, 2020,169:55-64. doi: 10.1016/j.carbon.2020.07.030
13. [13]
  Zhang J, Luo S H, Ren Q X, Zhang D J, Qin Y. Tailoring the sodium doped LiMnPO₄/C orthophosphate to nanoscale as a high-performance cathode for lithium ion battery[J]. Appl. Surf. Sci., 2020,530146628. doi: 10.1016/j.apsusc.2020.146628
14. [14]
  Xu G, Yang Y R, Li L L, Li F, Wang J W, Bao L, Li X, Shen G, Han G R. Ethylene glycol (EG) solvothermal synthesis of flower-like LiMnPO₄ nanostructures self-assembled with (010) nanobelts for Li-ion battery positive cathodes[J]. CrystEngComm, 2016,18(18):3282-3288. doi: 10.1039/C6CE00336B
15. [15]
  Xu H, Zong J, Ding F, Lu Z W, Li W, Liu X J. Effects of Fe²⁺ ion doping on LiMnPO₄ nanomaterial for lithium ion batteries[J]. RSC Adv., 2016,6(32):27164-27169. doi: 10.1039/C6RA02977A
16. [16]
  Deng Y F, Yang C X, Zou K X, Qin X S, Zhao Z X, Chen G H. Recent advances of Mn-rich LiFe_1-yMnyPO₄ (0.5=y<1.0) cathode materials for high energy density lithium ion batteries. Adv[J]. Energy Mater., 2017,7(13)1601958. doi: 10.1002/aenm.201601958
17. [17]
  Kim T H, Park H S, Lee M H, Lee S Y, Song H K. Restricted growth of LiMnPO₄ nanoparticles evolved from a precursor seed[J]. J. Power Sources, 2012,210:1-6. doi: 10.1016/j.jpowsour.2012.02.078
18. [18]
  Guo H, Wu C Y, Xie J, Zhang S C, Cao G S, Zhao X B. Controllable synthesis of high-performance LiMnPO₄ nanocrystals by a facile one-spot solvothermal process[J]. J. Mater. Chem. A, 2014,2(27):10581-10588. doi: 10.1039/C4TA01365D
19. [19]
  Wang Y, Wu C Y, Yang H, Duh J G. Rational design of a synthetic strategy, carburizing approach and pore-forming pattern to unlock the cycle reversibility and rate capability of micro-agglomerated LiMn_0.8Fe_0.2PO₄ cathode materials[J]. J. Mater. Chem. A, 2018,6(22):10395-10403. doi: 10.1039/C8TA03418D
20. [20]
  Yang L T, Xia Y G, Fan X, Qin L F, Qiu B, Liu Z P. Constructing durable carbon layer on LiMn₀₈Fe_0.2PO₄ with superior long-term cycling performance for lithium-ion battery[J]. Electrochim. Acta, 2016,191:200-206. doi: 10.1016/j.electacta.2016.01.069
21. [21]
  LUO D D, TIAN J H, ZHU X, WANG Z D, SHAN Z Q. Effect of carbon and graphene on performance of LiMnPO₄ material[J]. Chinese J. Inorg. Chem., 2017,33(6):1000-1006.
22. [22]
  QIU G C, XIA B B, SUN H D, FANG G Q, LIU W W, LI D C, WEI J. Improvement of electrochemical properties of LiMn₂O₄ cathode material by LiMnPO₄ coating via hydrothermal method[J]. Chinese J. Inorg. Chem., 2013,29(3):437-443.
23. [23]
  Li L G, Tu H F, Wang J, Wang M C, Li W F, Li X, Ye F M, Guan Q H, Zhu F Y, Zhang Y P, Hu Y Z, Yan C, Lin H Z, Liu M N. Electrocatalytic MOF-carbon bridged network accelerates Li⁺-solvents desolvation for high Li⁺ diffusion toward rapid sulfur redox kinetics[J]. Adv. Funct. Mater., 2023,332212499. doi: 10.1002/adfm.202212499
24. [24]
  Li Y C, Xing B Y, Wang Z G, Zhang H S, Liu Y Y, Jiang J C, Yang S T, Li B J. Constructing a hierarchical LiMn_0.8Fe_0.2PO₄/C cathode via Co-modification of Li₃PO₄ and graphite for high-performance lithium-ion batteries[J]. ACS Appl. Energy Mater., 2022,5:10983-10993. doi: 10.1021/acsaem.2c01634
25. [25]
  Liu C L, Li Q L, Sun H Z, Wang Z, Gong W B, Cong S, Yao Y G, Zhao Z G. MOF-derived vertically stacked Mn₂O₃@C flakes for fiber-shaped zinc-ion batteries[J]. J. Mater. Chem. A, 2020,8(45):24031-24039. doi: 10.1039/D0TA09212F
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
3. [3]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
6. [6]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
9. [9]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
10. [10]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
11. [11]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
12. [12]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
13. [13]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
14. [14]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
15. [15]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
18. [18]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
19. [19]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
20. [20]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(384)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites