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Citation: Yuanchao LI, Weifeng HUANG, Pengchao LIANG, Zifang ZHAO, Baoyan XING, Dongliang YAN, Li YANG, Songlin WANG. Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252 shu

Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites

  • 1.

    School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China

  • 2.

    Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

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  • LiMn0.8Fe0.2PO4/C composite was synthesized using sucrose and graphite as heterogeneous carbon sources through a solid-state method assisted by aqueous rheological phase. The effect of different addition methods of graphite on electrochemical performances was studied. The LiMn0.8Fe0.2PO4/C composite was characterized by the X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results showed that different graphite coating processes had obvious effects on the structure and electrochemical properties of the materials. The sample, which the graphite was added after the precursor was calcined, showed a high purity and uniform elliptic morphology. And its specific discharge capacity was 149 mAh·g-1 (87% of the theoretical specific capacity) at 0.1C. The specific discharge capacity was 133 mAh·g-1 at 5C. After 300 cycles at 2C, its capacity was maintained at 127 mAh·g-1, whose decay rate was 1.9%, showing excellent electrochemical performances.
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    1. [1]

      Shi J J, Wang Z G, Fu Y Q. Density functional theory study of lithium diffusion at the interface between olivine-type LiFePO4 and LiMnPO4[J]. J. Phys. D-Appl. Phys., 2016,49(50):505601-505606. doi: 10.1088/0022-3727/49/50/505601

    2. [2]

      Gnewuch S, Rodriguez E E. Distinguishing the intrinsic antiferromagnetism in polycrystalline LiCoPO4 and LiMnPO4 olivines[J]. Inorg. Chem., 2020,59(9):5883-5895. doi: 10.1021/acs.inorgchem.9b03545

    3. [3]

      SHANG W L, KONG L Y, CHEN L Z, HUANG S Z, TANG Y, REN C. Preparation and electrochemical performance of LiMn0.6Fe0.4PO4/C with high energy density[J]. Chinese J. Inorg. Chem., 2019,35(3):485-492.  

    4. [4]

      WU X Y, RUAN D S, MAO L L, FENG M H, LI B. Mn doped LiFePO4 cathode material: Solvothermal preparation and electrochemical performance[J]. Chinese J. Inorg. Chem., 2021,37(8):1399-1406.  

    5. [5]

      Budumuru A K, Viji M, Jena A, Nanda B R K, Sudakar C. Mn substitution controlled Li-diffusion in single crystalline nanotubular LiFePO4 high rate-capability cathodes: Experimental and theoretical studies[J]. J. Power Sources, 2018,406:50-62. doi: 10.1016/j.jpowsour.2018.10.020

    6. [6]

      Wang C, Li S H, Han Y Y, Lu Z D. Assembly of LiMnPO4 nanoplates into microclusters as a high-performance cathode in lithium-ion batteries[J]. ACS Appl. Mater. Interfaces, 2017,9(33):27618-27624. doi: 10.1021/acsami.7b05868

    7. [7]

      Lei Z H, Wang J L, Yang J, Nuli Y N, Ma Z F. Nano-/microhierarchical-structured LiMn0.85Fe0.15PO4 cathode material for advanced lithium ion battery[J]. ACS Appl. Mater. Interfaces, 2018,10(50):43552-43560. doi: 10.1021/acsami.7b04193

    8. [8]

      Xie Y, Yu H T, Yi T F, Zhu Y R. Understanding the thermal and mechanical stabilities of olivine-type LiMPO4 (M=Fe, Mn) as cathode materials for rechargeable lithium batteries from first principles[J]. ACS Appl. Mater. Interfaces, 2014,6(6):4033-4042. doi: 10.1021/am4054833

    9. [9]

      Kellerman D, Medvedeva N, Mukhina N, Semenova A, Baklanova I, Perelyaeva L, Gorshkov V. Vanadium doping of LiMnPO4: Vibrational spectroscopy and first-principle studies[J]. Chem. Phys. Lett., 2014,591:21-24. doi: 10.1016/j.cplett.2013.10.087

    10. [10]

      Li Z F, Ren X, Zheng Y, Tian W C, An L W, Sun J C, Ding R Q, Wen L Z, Liang G C. Effect of Ti doping on LiFePO4/C cathode material with enhanced low-temperature electrochemical performance[J]. Ionics, 2020,26(4):1599-1609. doi: 10.1007/s11581-019-03408-4

    11. [11]

      Jung Y H, Park W B, Pyo M, Sohn K S, Ahn D. A multi-element doping design for a high-performance LiMnPO4 cathode via metaheuristic computation[J]. J. Mater. Chem. A, 2017,5(19):8939-8945. doi: 10.1039/C6TA10228J

    12. [12]

      Wu K P, Yin S, Wang S, Zhu J L, Yao W T. Construction of submicron-sized LiFe0.4Mn0.6PO4/C enwrapped into graphene framework for advanced Li-storage[J]. Carbon, 2020,169:55-64. doi: 10.1016/j.carbon.2020.07.030

    13. [13]

      Zhang J, Luo S H, Ren Q X, Zhang D J, Qin Y. Tailoring the sodium doped LiMnPO4/C orthophosphate to nanoscale as a high-performance cathode for lithium ion battery[J]. Appl. Surf. Sci., 2020,530146628. doi: 10.1016/j.apsusc.2020.146628

    14. [14]

      Xu G, Yang Y R, Li L L, Li F, Wang J W, Bao L, Li X, Shen G, Han G R. Ethylene glycol (EG) solvothermal synthesis of flower-like LiMnPO4 nanostructures self-assembled with (010) nanobelts for Li-ion battery positive cathodes[J]. CrystEngComm, 2016,18(18):3282-3288. doi: 10.1039/C6CE00336B

    15. [15]

      Xu H, Zong J, Ding F, Lu Z W, Li W, Liu X J. Effects of Fe2+ ion doping on LiMnPO4 nanomaterial for lithium ion batteries[J]. RSC Adv., 2016,6(32):27164-27169. doi: 10.1039/C6RA02977A

    16. [16]

      Deng Y F, Yang C X, Zou K X, Qin X S, Zhao Z X, Chen G H. Recent advances of Mn-rich LiFe1-yMnyPO4 (0.5=y<1.0) cathode materials for high energy density lithium ion batteries. Adv[J]. Energy Mater., 2017,7(13)1601958. doi: 10.1002/aenm.201601958

    17. [17]

      Kim T H, Park H S, Lee M H, Lee S Y, Song H K. Restricted growth of LiMnPO4 nanoparticles evolved from a precursor seed[J]. J. Power Sources, 2012,210:1-6. doi: 10.1016/j.jpowsour.2012.02.078

    18. [18]

      Guo H, Wu C Y, Xie J, Zhang S C, Cao G S, Zhao X B. Controllable synthesis of high-performance LiMnPO4 nanocrystals by a facile one-spot solvothermal process[J]. J. Mater. Chem. A, 2014,2(27):10581-10588. doi: 10.1039/C4TA01365D

    19. [19]

      Wang Y, Wu C Y, Yang H, Duh J G. Rational design of a synthetic strategy, carburizing approach and pore-forming pattern to unlock the cycle reversibility and rate capability of micro-agglomerated LiMn0.8Fe0.2PO4 cathode materials[J]. J. Mater. Chem. A, 2018,6(22):10395-10403. doi: 10.1039/C8TA03418D

    20. [20]

      Yang L T, Xia Y G, Fan X, Qin L F, Qiu B, Liu Z P. Constructing durable carbon layer on LiMn08Fe0.2PO4 with superior long-term cycling performance for lithium-ion battery[J]. Electrochim. Acta, 2016,191:200-206. doi: 10.1016/j.electacta.2016.01.069

    21. [21]

      LUO D D, TIAN J H, ZHU X, WANG Z D, SHAN Z Q. Effect of carbon and graphene on performance of LiMnPO4 material[J]. Chinese J. Inorg. Chem., 2017,33(6):1000-1006.  

    22. [22]

      QIU G C, XIA B B, SUN H D, FANG G Q, LIU W W, LI D C, WEI J. Improvement of electrochemical properties of LiMn2O4 cathode material by LiMnPO4 coating via hydrothermal method[J]. Chinese J. Inorg. Chem., 2013,29(3):437-443.  

    23. [23]

      Li L G, Tu H F, Wang J, Wang M C, Li W F, Li X, Ye F M, Guan Q H, Zhu F Y, Zhang Y P, Hu Y Z, Yan C, Lin H Z, Liu M N. Electrocatalytic MOF-carbon bridged network accelerates Li+-solvents desolvation for high Li+ diffusion toward rapid sulfur redox kinetics[J]. Adv. Funct. Mater., 2023,332212499. doi: 10.1002/adfm.202212499

    24. [24]

      Li Y C, Xing B Y, Wang Z G, Zhang H S, Liu Y Y, Jiang J C, Yang S T, Li B J. Constructing a hierarchical LiMn0.8Fe0.2PO4/C cathode via Co-modification of Li3PO4 and graphite for high-performance lithium-ion batteries[J]. ACS Appl. Energy Mater., 2022,5:10983-10993. doi: 10.1021/acsaem.2c01634

    25. [25]

      Liu C L, Li Q L, Sun H Z, Wang Z, Gong W B, Cong S, Yao Y G, Zhao Z G. MOF-derived vertically stacked Mn2O3@C flakes for fiber-shaped zinc-ion batteries[J]. J. Mater. Chem. A, 2020,8(45):24031-24039. doi: 10.1039/D0TA09212F

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