Citation: Sheng HUANG, Husheng SHAN, Yulong ZHAO, Tongshun DING, Yifan REN, Xiuquan GU. Preparation of humidity sensors based on CsPbBr₃ quantum dots for applications in microcrack detection[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 383-393. doi: 10.11862/CJIC.20230189 shu

Preparation of humidity sensors based on CsPbBr₃ quantum dots for applications in microcrack detection

Sheng HUANG ¹ ,
Husheng SHAN ¹ ,
Yulong ZHAO ¹ ,
Tongshun DING ¹ ,
Yifan REN ¹ ,
Xiuquan GU ^{1, 2,,}

1.
School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
State Key Laboratory of Silicon, Zhejiang University, Hangzhou 310027, China

Corresponding author: Xiuquan GU, xqgu@cumt.edu.cn
Received Date: 18 May 2023
Revised Date: 7 December 2023

Figures(10)

Perovskite CsPbBr₃-Fe quantum dots (QDs) with good dispersion and uniform size were prepared using a simple solution route combined with an acetylacetone iron (AAI) modification technology. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. Then, a resistive humidity sensor was fabricated with the perovskite CsPbBr₃-Fe QDs by a spin-coating method. The humidity sensitivity measurement results showed that the device had good linear and rapid response characteristics with a detection range of 10% to 100% relative humidity (RH). At 70% RH, the humid sensor displayed a sensitivity of 1.1, a response time of 38 s, and a recovery time of 38 s, respectively. In addition, we used the finite element method (FEM) to simulate the leakage behavior of pipeline microcracks, and verified the feasibility of using humidity sensors to detect the leakage locations by simulating the distribution of flow velocity and pressure fields under different flow velocities and pressures.
- quantum dot,
- organometallic ligand,
- humidity sensor,
- pipeline leakage,
- mine detection
1. [1]
  Sadeghi M E, Shahrabi F T, Neshati J. Failure analysis of stress corrosion cracking occurred in a gas transmission steel pipeline[J]. Eng. Fail. Anal., 2011,18(3):963-970. doi: 10.1016/j.engfailanal.2010.11.014
2. [2]
  LIU L G, HU H, LIU P, LU W, ZHAO K, ZENG D Z. Failure analysis of N80 oil pipe corrosion perforation in a shale gas well in southern Sichuan[J]. Materials Protection, 2023,56(11):193-198.
3. [3]
  LI X, FENG D W, YANG Z N, YANG Y, XU Z D. Analysis of corrosion and perforation failure of oil tubing in a production well offshore[J]. Chemical Equipment Technology, 2023,44(5):35-39.
4. [4]
  Tang Z H, Wang Z R, Lu Y W, Sun P P. Cause analysis and preventive measures of pipeline corrosion and leakage accident in alkylation unit[J]. Eng. Fail Anal., 2021,128105623. doi: 10.1016/j.engfailanal.2021.105623
5. [5]
  Luo B, Sun Y J, Xu Z M, Chen G, Zhang L, Lu W N, Zhao X M, Yuan H Q. Damage characteristics and mechanism of the 2017 groundwater inrush accident that occurred at Dongyu coalmine in Taiyuan, Shanxi, China[J]. Water, 2021,13(3)368. doi: 10.3390/w13030368
6. [6]
  YAN J, QI K, SONG W, ZHANG S N, WANG K. Detection and analysis of the height of the development of water conducting fracture zones in the Mudu Chaideng coal mine[J]. China Energy and Environmental Protection, 2023,45(9):272-278.
7. [7]
  Zhang H, Li H X, Zhou J T, Tong K, Xia R C. A multi-dimensional evaluation of wire breakage in bridge cable based on self-magnetic flux leakage signals[J]. J. Magn. Magn. Mater., 2023,566170321. doi: 10.1016/j.jmmm.2022.170321
8. [8]
  LI F M, LIU S Q, XU L, ZHANG H D, ZENG X M, CHEN Z H. Longitudinal bending mode conversion slotted circular tube piezoelectric ultrasonic transducer[J]. Sci. Sin.-Phys. Mech. Astron., 2023,11:198-209.
9. [9]
  Conti F, Madeo F, Boiano A, Tarabini M. Electrical and mechanical data fusion for hydraulic valve leakage diagnosis[J]. Meas. Sci. Technol., 2023,34(4)044011. doi: 10.1088/1361-6501/acb376
10. [10]
  Han L, Chen J F, Li H B, Liu G S, Leng B, Ahmed A, Zhang Z T. Multispectral water leakage detection based on a one-stage anchor-free modality fusion network for metro tunnels[J]. Autom. Constr., 2022,140104345. doi: 10.1016/j.autcon.2022.104345
11. [11]
  Ahn B, Kim J, Choi B. Artificial intelligence-based machine learning considering flow and temperature of the pipeline for leak early detection using acoustic emission[J]. Eng. Fract. Mech., 2019,210:381-392. doi: 10.1016/j.engfracmech.2018.03.010
12. [12]
  Marković L, Ivanišević A, Matijević J, Chan R S M, Tsoi J K H, Šnjarić D, Gjorgievska E. Micro-CT analysis and leakage of bioceramic retrofillings after ultrasonic and Er: YAG laser cavity preparations: An in vitro study[J]. Lasers Med. Sci., 2023,38(1)145. doi: 10.1007/s10103-023-03809-y
13. [13]
  YU S G, ZHANG H Y, ZHANG J. Preparation of Cd/ZnO and study on its humidity sensitivity performance[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 2020,37(2):137-141.
14. [14]
  Li R X, Yu J H, Wang S, Shi Y Q, Wang Z J, Wang K, Ni Z H, Yang X Y, Wei Z P, Chen R. Surface modification of all-inorganic halide perovskite nanorods by a microscale hydrophobic zeolite for stable and sensitive laser humidity sensing[J]. Nanoscale, 2020,12(25):13360-13367. doi: 10.1039/D0NR01889A
15. [15]
  CHEN G D, ZHOU N, MAO H Y, CHEN D P. Research progress in organic polymer MEMS humidity sensors[J]. Micro/nano Electronics and Intelligent Manufacturing, 2021,3(4):47-58.
16. [16]
  WANG W D, LI J, FAN Y Y, CAO J M, ZHANG Y, HU J. Preparation of CeO₂/CuO gas sensor and its gas sensing performance of n- butanol[J]. Micronanoelectronic Technology, 2023,60(10):1626-1631.
17. [17]
  Ghanizadeh S, Naghshara H, Meshginqalam B. A theoretical analysis of performance enhancement of SPR sensor based on ZnO and BaTiO₃ for NH₃ detection[J]. Phys. Scr., 2023,98(11)115412. doi: 10.1088/1402-4896/acfad1
18. [18]
  Zhang M, Wei S H, Ren W, Wu R. Development of high sensitivity humidity sensor based on gray TiO₂/SrTiO₃ composite[J]. Sensors, 2017,17(6)1310. doi: 10.3390/s17061310
19. [19]
  Wang P, Wu Y H, Cai B, Ma Q S, Zheng X J, Zhang W H. Solution‐processable perovskite solar cells toward commercialization: Progress and challenges[J]. Adv. Funct. Mater., 2019,29(47)1807661. doi: 10.1002/adfm.201807661
20. [20]
  Steirer K X, Schulz P, Teeter G, Stevanovic V, Yang M, Zhu K, Berry J J. Defect tolerance in methylammonium lead triiodide perovskite[J]. ACS Energy Lett., 2016,1(2):360-366. doi: 10.1021/acsenergylett.6b00196
21. [21]
  Liu Y, Zheng X P, Fang Y J, Zhou Y, Ni Z Y, Xiao X, Chen S S, Huang J S. Ligand assisted growth of perovskite single crystals with low defect density[J]. Nat. Commun., 2021,12(1)1686. doi: 10.1038/s41467-021-21934-6
22. [22]
  Zhumekenov A A, Saidaminov M I, Haque M A, Alarousu E, Sarmah S P, Murali B, Dursun I, Miao X, Abdelhady A L, Wu T. Formamidinium lead halide perovskite crystals with unprecedented long carrier dynamics and diffusion length[J]. ACS Energy Lett., 2016,1(1):32-37. doi: 10.1021/acsenergylett.6b00002
23. [23]
  De Quilettes D W, Vorpahl S M, Stranks S D, Nagaoka H, Eperon G E, Ziffer M E, Snaith H J, Ginger D S. Impact of microstructure on local carrier lifetime in perovskite solar cells[J]. Science, 2015,348(6235):683-686. doi: 10.1126/science.aaa5333
24. [24]
  Randall C A, Bhalla A S, Shrout T R, Cross L E. Classification and consequences of complex lead perovskite ferroelectrics with regard to b-site cation order[J]. J. Mater. Res., 1990,5(4):829-834. doi: 10.1557/JMR.1990.0829
25. [25]
  Kim Y H, Kim S, Jo S H, Lee T W. Metal halide perovskites: From crystal formations to light‑emitting‑diode applications[J]. Small Methods, 2018,2(11)1800093. doi: 10.1002/smtd.201800093
26. [26]
  WU Y J, WU Z L, WANG L, NIAN W Q, HE Y, GUO Y C. Respiratory rate monitoring system based on inorganic halide perovskite humidity sensor[J]. Opto-Electronic Engineering, 2021,48(3):37-44.
27. [27]
  Haussonne J M, Desgardin G, Bajolet P H, Raveau B. Barium titanate perovskite sintered with lithium fluoride[J]. J. Am. Ceram. Soc., 1983,66(11):801-807.
28. [28]
  Hirotsu S, Harada J, Iizumi M, Gesi K. Structural phase transitions in CsPbBr₃[J]. J. Phys. Soc. Jap., 1974,37(5):1393-1398.
29. [29]
  Park Y S, Bae W K, Padilha L A, Pietryga J M, Klimov V I. Effect of the core/shell interface on auger recombination evaluated by single-quantum-dot spectroscopy[J]. Nano Lett., 2014,14(2):396-402.
30. [30]
  Ren A B, Lai H G, Hao X, Tang Z G, Xu H, Jeco B M F Y, Watanabe K, Wu L L, Zhang J Q, Sugiyama M, Wu J, Zhao D W. Efficient perovskite solar modules with minimized nonradiative recombination and local carrier transport losses[J]. Joule, 2020,4(6):1263-1277.
31. [31]
  Wang H R, Zhang X Y, Wu Q Q, Cao F, Yang D W, Shang Y Q, Ning Z J, Zhang W, Zheng W T, Yan Y Y, Kershaw S V, Zhang L J, Rogach A L, Yang X Y. Trifluoroacetate induced small-grained CsPbBr₃ perovskite films result in efficient and stable light-emitting devices[J]. Nat. Commun., 2019,10(1)665.
32. [32]
  Arramel , Pan H, Xie A Z, Hou S Y, Yin X M, Tang C S, Hoa N T, Birowosuto M D, Wang H, Dang C, Rusydi A, Wee A T S, Wu J S. Surface molecular doping of all-inorganic perovskite using zethrenes molecules[J]. Nano Res., 2019,12:77-84.
33. [33]
  Lee D H, Condrate Sr R A, Lacourse W C. FTIR spectral characterization of thin film coatings of oleic acid on glasses: Coatings on glasses from ethyl alcohol[J]. J. Mater. Sci., 1999,34(1):139-146.
34. [34]
  Nakamato K. Infrared and Raman spectra of inorganic and coordination compound. 3rd ed. Translated by HUANG D R, WANG R Q. Beijing: Chemical Industry Press, 1986.
35. [35]
  Wang C X, Yin L W, Zhang L Y, Xiang D, Gao R. Metal oxide gas sensors: Sensitivity and influencing factors[J]. Sensors, 2010,10(3):2088-2106.
36. [36]
  Kumar M, Kumar A, Abhyankar A C. SnO₂ based sensors with improved sensitivity and response-recovery time[J]. Ceram. Int., 2014,40(6):8411-8418.
37. [37]
  Mainali P, Wagle P, Khatri N, McPherson C, Kalkan K, McIlroy D N. Humidity induced resistive switching and negative differential resistance in α-Fe₂O₃ porous thin films[J]. Sensor. Actuat. A-Phys., 2023,362114631.
38. [38]
  Anderson Jr J H, Parks G A. Electrical conductivity of silica gel in the presence of adsorbed water[J]. J. Phys. Chem., 1968,72(10):3662-3668.
39. [39]
  Agmon N. The grotthuss mechanism[J]. Chem. Phys. Lett., 1995,244(5):456-462.
40. [40]
  Zhang D Z, Sun Y E, Li P, Zhang Y. Facile fabrication of MoS₂-modified SnO₂ hybrid nanocomposite for ultrasensitive humidity sensing[J]. ACS Appl. Mater. Interfaces, 2016,8(22):14142-14149.
41. [41]
  Thürmer S, Seidel R, Eberhardt W, Bradforth S E, Winter B. Ultrafast hybridization screening in Fe³⁺ aqueous solution[J]. J. Am. Chem. Soc., 2011,133(32):12528-12535.
42. [42]
  Bentaher H, Ibrahmi A, Hamza E, Hbaieb M, Kantchev G, Maalej A, Arnold W. Finite element simulation of moldboard-soil interaction[J]. Soil Tillage Res., 2013,134:11-16.
1. [1]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
2. [2]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
3. [3]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
4. [4]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
5. [5]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
6. [6]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
7. [7]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
8. [8]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
9. [9]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
10. [10]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
11. [11]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
12. [12]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
13. [13]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
14. [14]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
15. [15]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
16. [16]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
17. [17]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
18. [18]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082
19. [19]
  Xinyu Zhu , Meili Pang . Application of Functional Group Addition Strategy in Organic Synthesis. University Chemistry, 2024, 39(3): 218-230. doi: 10.3866/PKU.DXHX202308106
20. [20]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(399)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of humidity sensors based on CsPbBr3 quantum dots for applications in microcrack detection

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of humidity sensors based on CsPbBr₃ quantum dots for applications in microcrack detection