Citation: Yuhao SUN, Qingzhe DONG, Lei ZHAO, Xiaodan JIANG, Hailing GUO, Xianglong MENG, Yongmei GUO. Synthesis and antibacterial properties of silver-loaded sod-based zeolite[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169 shu

Synthesis and antibacterial properties of silver-loaded sod-based zeolite

Yuhao SUN ^{1, 2, #} ,
Qingzhe DONG ^{3, #} ,
Lei ZHAO ² ,
Xiaodan JIANG ^1,, ,
Hailing GUO ^2,, ,
Xianglong MENG ² ,
Yongmei GUO ⁴

1.
Department of Otolaryngology, Affiliated Hospital of Qingdao University, Qingdao, Shandong 266555, China
2.
China State Key Laboratory of Heavy Oil, College of Chemical Engineering, China University of Petroleum, Qingdao, Shandong 266580, China
3.
China Medical Research Center, Affiliated Hospital of Qingdao University, Qingdao, Shandong 266555, China
4.
Key Laboratory of New Functional Textile Fibers and Materials, Minjiang University, Fuzhou 350108, China

Corresponding author: Xiaodan JIANG, jiangxiaodan@qdu.edu.cn Hailing GUO, guohl@upc.edu.cn
Received Date: 6 May 2023
Revised Date: 1 March 2024

Figures(12)

A series of sod-based zeolites (EMT, FAU, SOD) were synthesized by two-step method, and Ag⁺ was introduced by ion exchange method to obtain silver-loaded zeolite. X-ray diffraction (XRD) and scanning electron microscope (SEM) showed that the structure and grain size of the zeolite did not change significantly before and after ion exchange. It was proved by infrared (IR) and thermogravimetry (TG) that the silver bearing zeolite had good stability. The Ag⁺ release experiment and antibacterial activity test were carried out on the prepared silver-loaded zeolite, and the effects of zeolite type and grain size on antibacterial performance were investigated. The results showed that the cage structure of FAU and EMT zeolite had better antibacterial properties because they could store more Ag⁺, and the super cage structure of FAU zeolite had the best antibacterial properties. By comparing the antibacterial data of FAU zeolite with different grain sizes, it was found that the FAU zeolite with grain size of 100 nm had the best antibacterial performance and antibacterial life because of the abundant antibacterial active sites on the outer surface and the Ag⁺ could be stored and released continuously inside. The silver-loaded FAU zeolite with grain size of 10 nm had the fastest Ag⁺ release rate and the highest antibacterial efficiency due to its small grain size, large external specific surface area and short diffusion path. The factors affecting the antibacterial properties of silver-loaded zeolite were summarized.
- nanosized zeolite,
- antibacterial property,
- silver ion,
- grain size
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