Citation: Silu WANG, Fengfeng ZHANG, Cheng ZHANG, Xiao WANG, Long TANG, Erlin YUE, Jijiang WANG, Xiangyang HOU. Design and synthesis of Eu³⁺/Tb³⁺-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr⁴⁺, Fe³⁺, Cr₂O₇^2-, HPO₄^2- and identifying fingerprints[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 441-450. doi: 10.11862/CJIC.20230145 shu

Design and synthesis of Eu³⁺/Tb³⁺-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr⁴⁺, Fe³⁺, Cr₂O₇^2-, HPO₄^2- and identifying fingerprints

Department of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: Xiangyang HOU, houxiangyang7@126.com
Received Date: 17 April 2023
Revised Date: 1 November 2023

Figures(5)

The isomorphic terbium and europium coordination polymers (CPs) {[Eu(PLIA)_1.5(H₂O)₂] ·H₂O}_n (1) and {[Tb(PLIA)_1.5(H₂O)₂]·H₂O}_n (2), where H₂PLIA=5-((pyridin-4-yl-methyl)oxy)benzene-1,3-dicarboxylic acid, were synthesized by using aromatic π-conjugated and nitrogen-containing organic linkers. The structure determination, characterization, and fluorescence trace identification of the CPs were studied. The two isomorphic complexes have an ideal 3D frame structure and their chemical stability is enhanced by weak interactions such as π…π packing and hydrogen bonds. The characterization shows that CPs 1 and 2 have good fluorescence deletion properties, crystallinity, thermodynamic stability, and structural integrity, and can be used as fluorescence sensing materials. 1 and 2 have fluorescence recognition ability for Zr⁴⁺, Cr₂O₇^2- and Fe³⁺, HPO₄^2- in aqueous solution, respectively, with good selectivity and high sensitivity. The detection limits of these four ions by 1 and 2 were 0.139 μmol·L^-1 (1, Zr⁴⁺), 0.626 μmol·L^-1 (1, Cr₂O₇^2-), 0.430 μmol·L^-1 (2, Fe³⁺), 1.36 μmol·L^-1 (2, HPO₄^2-), respectively. The fluorescence quenching mechanism of 1 and 2 as probes was investigated in detail. More interestingly, the two complexes have potential fingerprint recognition properties. Their fluorescent fingerprint patterns were clear and coherent, and the details were obvious and could be clearly observed.
- Eu³⁺/Tb³⁺-coordination polymers,
- synthesis,
- characterization,
- fluorescent probe,
- fingerprint recognition
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Design and synthesis of Eu3+/Tb3+-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr4+, Fe3+, Cr2O72-, HPO42- and identifying fingerprints

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通讯作者: 陈斌, bchen63@163.com

Design and synthesis of Eu³⁺/Tb³⁺-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr⁴⁺, Fe³⁺, Cr₂O₇^2-, HPO₄^2- and identifying fingerprints