Citation: Chao FENG, Ling-Mei ZHANG, Yu-Meng YANG, Hong ZHAO. A cobalt co-crystal complex based on 5-(3-pyridyl)-1H-pyrazole-3-carboxylic acid: Synthesis, crystal structure and electrochemical property[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2377-2384. doi: 10.11862/CJIC.2023.207 shu

A cobalt co-crystal complex based on 5-(3-pyridyl)-1H-pyrazole-3-carboxylic acid: Synthesis, crystal structure and electrochemical property

Chao FENG ^{1, 2, #,,} ,
Ling-Mei ZHANG ^{2, #} ,
Yu-Meng YANG ² ,
Hong ZHAO ^2,,

1.
School of Materials and Chemical Engineering, Bengbu University, Bengbu, Anhui 233030, China
2.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: Chao FENG, fchg042@163.com Hong ZHAO, zhaohong@seu.edu.cn
Received Date: 29 July 2023
Revised Date: 15 November 2023

Figures(9)

A new cobalt(Ⅱ)-based complex, namely {[Co(Hppc)₂][Co₂(4, 4′-bipy)(H₂O)₄](SO₄)₂•2H₂O}_n (1) where H₂ppc=5-(3-pyridyl)-1H-pyrazole-3-carboxylic acid and 4, 4′-bipy=4, 4′-bipyridine, was synthesized by solvothermal method. The ligand H₂ppc is constituted by a pyridine ring, pyrazole ring, and carboxyl group, which possesses rigidity and flexibility. Complex 1 was structurally determined by single-crystal X-ray diffraction and displays that the complex crystallizes in the C2/c pace group, monoclinic system. Complex 1 includes two crystallographic independent parts which are 2D layered [Co(Hppc)₂] and 1D chain like [Co₂(4, 4′-bipy)(H₂O)₄]^2- forming a co-crystal structure with a {4⁴•6²}{4}₂ topological network. Furthermore, complex 1 exhibits good electrochemiluminescence (ECL) performance and supercapacitive performance.
- complex,
- co-crystal,
- topology,
- electrochemiluminescence,
- supercapacitor
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