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Citation: Cong-Yu ZUO, Qin-Qin LI, Ming-Zhu DAI, Chen-Yang FAN, Ye XU, Guang-Ze LIU, Si-Yu WANG. A Cadmium-based metal-organic framework for fluorescence detection of acetone and Fe3+[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2301-2310. doi: 10.11862/CJIC.2023.203 shu

A Cadmium-based metal-organic framework for fluorescence detection of acetone and Fe3+

  • School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China

  • Corresponding author: Cong-Yu ZUO, cyzuo@aust.edu.cn
  • Received Date: 5 July 2023
    Revised Date: 2 November 2023

Figures(9)

  • A Cd-based metal-organic framework with the formula (Me2NH2)[Cd(BTB)(DMF)]·DMF·H2O (Cd-MOF) has been synthesized via the solvothermal method using 1, 3, 5-tris(4-carboxyphenyl)benzene (H3BTB) as a ligand, and its structure was characterized by single crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, and thermogravimetric analysis. It could selectively detect acetone and Fe3+ ions by fluorescence quenching with the detection limits (volume fraction and concentration) of 0.6% and 0.89 μmol·L-1, respectively. The linear detection ranges of 2.0%-2.5% for acetone and 0-0.05 mmol·L-1 for Fe3+ ions were observed. Time response and recyclability experiments confirmed that Cd-MOF is a reliable and efficient fluorescence sensor for the long-term detection of acetone molecules and Fe3+ ions.
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