Citation: Yao ZHANG, Chun-Mei WANG, Xin-Yao SUN, Yuan-Yuan GAO, Yan-Fang GAO. Dual-metal ions adjustable nickel and cobalt oxide nanosheets for asymmetric supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2415-2424. doi: 10.11862/CJIC.2023.201 shu

Dual-metal ions adjustable nickel and cobalt oxide nanosheets for asymmetric supercapacitors

Yao ZHANG ^{1, 2,,} ,
Chun-Mei WANG ^{1, 2} ,
Xin-Yao SUN ^{1, 2} ,
Yuan-Yuan GAO ¹ ,
Yan-Fang GAO ^{1, 2}

1.
College of Chemical Technology, Inner Mongolia University of Technology, Hohhot 010050, China
2.
Engineering Research Center of Large Energy Storage Technology, Ministry of Education, Inner Mongolia University of Technology, Hohhot 010050, China

Corresponding author: Yao ZHANG, zhangyao@imut.edu.cn
Received Date: 25 May 2023
Revised Date: 23 October 2023

Figures(7)

A series of nickel and cobalt oxide (NCO) nanosheets were synthesized through a two-step hydrothermal- calcined method. Transition metal ions in NCO nanosheets were adjusted by changing the molar ratios of nickel and cobalt ions in precursor solutions. The crystalline phases, morphologies, and structures of the NCO nanosheets were characterized using X-ray diffraction, scanning electron microscope, and X-ray photoelectron spectroscopy. Furthermore, the electrochemical performances of the NCO nanosheets electrodes were tested. The result indicated that the NCO-2 (Ni_1.95Co₁O_x) nanosheets exhibited high specific capacitance of 1 096.88 F·g^-1 under 0.5 A·g^-1, which concurrently possessed a cycling ability of 78.26% after 5 000 cycles. Importantly, the asymmetric supercapacitor, which was constructed from the NCO-2 positive electrode and active carbon negative electrode, presented an energy density of 57.70 Wh·kg^-1 at a power density of 576 W·kg^-1.
- dual-metal ions,
- nickel and cobalt oxide,
- nanosheet,
- pseudocapacitive performance,
- asymmetric superca
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