Citation: Wen-Ze ZHAO, Qi-Long ZHANG. Syntheses, crystal structures of two silver coordination polymers based on β-diketone ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2295-2300. doi: 10.11862/CJIC.2023.198 shu

Syntheses, crystal structures of two silver coordination polymers based on β-diketone ligand

Wen-Ze ZHAO ¹ ,
Qi-Long ZHANG ^2,,

1.
Shandong Vocational College of Industry, Zibo, Shandong 256414, China
2.
School of Basic Medical Sciences, Guizhou Medical University, Guiyang 550025, China

Corresponding author: Qi-Long ZHANG, gzuqlzhang@126.com
Received Date: 23 July 2023
Revised Date: 1 November 2023

Figures(8)

We performed a coordination reaction between ligand 3-(5-(3-pyridyl)-2-(1, 3, 4-oxadiazoles))thio)-2, 4-glutaric ketone (L₁) and AgSbF₆ to obtain a coordination polymer {[Ag(L₁)₂]SbF₆}_n (1). The ligand 3-((5-(4-pyridyl)-2-(1, 3, 4-oxadiazole))thio-2, 4-pentanedione (L₂) was used to react with AgCF₃SO₃ to obtain a coordination polymer [Ag(L₂)(CF₃SO₃)]_n (2). The structures of the two complexes were characterized by powder X-ray diffraction, infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. In the solid state, coordination polymers 1 and 2 form 1D chain structures, and the coordination configuration of Ag(Ⅰ) ions is a twisted tetrahedron. The carbonyl oxygen atoms of the β-diketone units in the two complexes do not coordinate with Ag(Ⅰ) ions, providing the possibility for constructing heteronuclear complexes.
- β-diketone,
- Ag(Ⅰ) coordination polymers,
- crystal structure
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