Citation: Wen-Ze ZHAO, Qi-Long ZHANG. Syntheses, crystal structures of two silver coordination polymers based on β-diketone ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2295-2300. doi: 10.11862/CJIC.2023.198 shu

Syntheses, crystal structures of two silver coordination polymers based on β-diketone ligand

Wen-Ze ZHAO ¹ ,
Qi-Long ZHANG ^2,,

1.
Shandong Vocational College of Industry, Zibo, Shandong 256414, China
2.
School of Basic Medical Sciences, Guizhou Medical University, Guiyang 550025, China

Corresponding author: Qi-Long ZHANG, gzuqlzhang@126.com
Received Date: 23 July 2023
Revised Date: 1 November 2023

Figures(8)

We performed a coordination reaction between ligand 3-(5-(3-pyridyl)-2-(1, 3, 4-oxadiazoles))thio)-2, 4-glutaric ketone (L₁) and AgSbF₆ to obtain a coordination polymer {[Ag(L₁)₂]SbF₆}_n (1). The ligand 3-((5-(4-pyridyl)-2-(1, 3, 4-oxadiazole))thio-2, 4-pentanedione (L₂) was used to react with AgCF₃SO₃ to obtain a coordination polymer [Ag(L₂)(CF₃SO₃)]_n (2). The structures of the two complexes were characterized by powder X-ray diffraction, infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. In the solid state, coordination polymers 1 and 2 form 1D chain structures, and the coordination configuration of Ag(Ⅰ) ions is a twisted tetrahedron. The carbonyl oxygen atoms of the β-diketone units in the two complexes do not coordinate with Ag(Ⅰ) ions, providing the possibility for constructing heteronuclear complexes.
- β-diketone,
- Ag(Ⅰ) coordination polymers,
- crystal structure
1. [1]
  Kimura S, Matsuoka R, Kimura S, Nishihara H, Kusamoto T. Radical-based coordination polymers as a platform for magnetoluminescence[J]. J. Am. Chem. Soc., 2021,143:5610-5615. doi: 10.1021/jacs.1c00661
2. [2]
  Tsurui M, Kitagawa Y, Shoji S, Fushimi K, Hasegawa Y. Enhanced circularly polarized luminescence of chiral Eu(Ⅲ) coordination polymers with structural strain[J]. Dalton Trans., 2023,52:796-805. doi: 10.1039/D2DT03422K
3. [3]
  Zhao D S, Li W Q, Wen R M, Lei N N, Li W C, Liu X, Zhang X T, Fan L M. Eu(Ⅲ)-functionalized MOF-based dual-emission ratiometric sensor integrated with logic gate operation for efficient detection of hippuric acid in urine and serum[J]. Inorg. Chem., 2023,62:2715-2725. doi: 10.1021/acs.inorgchem.2c03828
4. [4]
  Li W Q, Zhao D S, Li W C, Wen R M, Liu X, Liu L Y, Li T, Fan L M. Chemorobust dye-encapsulated framework as dual-emission self-calibrating ratiometric sensor for intelligent detection of toluene exposure biomarker in urine[J]. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2023,296122637. doi: 10.1016/j.saa.2023.122637
5. [5]
  Wang F, Zhao D S, Li W Q, Zhang H H, Li B, Hu T P, Fan L M. Rod-shaped units based cobalt(Ⅱ) organic framework as an efficient electrochemical sensor for uric acid detection in serum[J]. Microchem. J., 2023,185108154. doi: 10.1016/j.microc.2022.108154
6. [6]
  LING G L, WANG M M, TANG X X, ZHANG R, NI Z H. Synthesis, crystal structure, and magnetic properties of a cyanide-bridged Fe₄^ⅢNi₂^Ⅱ hexa-nuclear complex based on tricyanideferrate(Ⅲ)[J]. Chinese J. Inorg. Chem., 2023,39(8):1564-1570.
7. [7]
  HUANG C, WANG K T, CHEN D M, ZHU B X, LU J H. Synthesis, crystal structures, luminescence, and vapor adsorption properties of 1D mercury(Ⅱ) coordination polymers based on two dipyridylamide ligands[J]. Chinese J. Inorg. Chem., 2022,38(11):2291-2298. doi: 10.11862/CJIC.2022.236
8. [8]
  ZHANG Q L, XU H, FENG G W, HUANG Y L. Syntheses, structures and luminescent properties of two silver coordination complexes based on bis(β-diketone) Schiff bases[J]. Chinese J. Inorg. Chem., 2016,32(8):1421-1426.
9. [9]
  Zuffa C, Cappuccino C, Marchini M, Contini L, Farinella F, Maini L. AgX-based hybrid coordination polymers: Mechanochemical synthesis, structure and luminescence property characterization[J]. Faraday Discuss., 2023,241:448-465. doi: 10.1039/D2FD00093H
10. [10]
  Ok M, Kim K Y, Choi H, Kim S, Lee S S, Cho J, Jung S H, Jung J H. Helicity-driven chiral self-sorting supramolecular polymerization with Ag⁺: Right- and left-helical aggregates[J]. Chem. Sci., 2022,13:3109-3117. doi: 10.1039/D1SC06413D
11. [11]
  Zhao C, Kong X Y, Shuang S M, Wang Y, Dong C. An anthraquinone-imidazole-based colorimetric and fluorescent sensor for the sequential detection of Ag⁺ and biothiols in living cells[J]. Analyst, 2020,145:3029-3037. doi: 10.1039/D0AN00164C
12. [12]
  Lee E, Hosoi Y, Temma H, Ju H, Ikeda M, Kuwahara S, Habata Y. Silver ion-induced chiral enhancement by argentivorous molecules[J]. Chem. Commun., 2020,56:3373-3376. doi: 10.1039/D0CC00798F
13. [13]
  Feng W X, Huang Y J, Zhao Y, Tian W, Yan H X. Water-soluble cationic Eu³⁺-metallopolymer with high quantum yield and sensitivity for intracellular temperature sensing[J]. ACS Appl. Mater. Interfaces, 2023,15:17211-17221. doi: 10.1021/acsami.3c00478
14. [14]
  Li X L, Wang A L, Li Y N, Gao C L, Cui M H, Xiao H P, Zhou L M. Two chiral Yb^Ⅲ enantiomeric pairs with distinct enantiomerically pure N-donor ligands presenting significant differences in photoluminescence, circularly polarized luminescence, and second-harmonic generation[J]. Inorg. Chem., 2023,62:4351-4360. doi: 10.1021/acs.inorgchem.3c00106
15. [15]
  Gildenast H, Hempelmann G, Gruszien L, Englert U. A rigid linker for site-selective coordination of transition metal cations: Combining an acetylacetone with a caged phosphine[J]. Inorg. Chem., 2023,62:3178-3185. doi: 10.1021/acs.inorgchem.2c04101
16. [16]
  Mao P D, Yao N T, Sun H Y, Yan F F, Zhang Y Q, Meng Y S, Liu T. Design of heterometallic {Ln^Ⅲ-M^Ⅴ} (Ln=Dy, Er; M=W, Mo) molecular nanomagnets: Protonation induced structural diversification[J]. Cryst. Growth Des., 2023,23:450-464. doi: 10.1021/acs.cgd.2c01112
17. [17]
  Sakovich M, Sokolova D, Alekseev I, Lentin I, Gorbunov A, Malakhova M, Ershov I, Zairov R, Korniltsev I, Podyachev S, Bezzubov S, Kovalev V, Vatsouro I. Enriching calixarene functionality with 1, 3-diketone groups[J]. Org. Chem. Front., 2023,10:3619-3636. doi: 10.1039/D3QO00759F
18. [18]
  ZHANG Q L, SUN L T, YANG X J, XU H, LI L L, YANG X S. Synthesis and crystal structure of Cu(Ⅱ)/Zn(Ⅱ)/Mn(Ⅱ) complexes containing 3-((5-(pyridin-3-yl)-1, 3, 4-oxadiazol-2-yl)thio)pentane-2, 4-dione ligand[J]. Chinese J. Inorg. Chem., 2021,37(6):989-994.
19. [19]
  Titov A A, Filippov O A, Smol'yakov A F, Godovikov I A, Shakirova J R, Tunik S P, Podkorytov I S, Shubina E S. Luminescent complexes of the trinuclear silver(Ⅰ) and copper(Ⅰ) pyrazolates supported with bis(diphenylphosphino)methane[J]. Inorg. Chem., 2019,58:8645-8656. doi: 10.1021/acs.inorgchem.9b00991
20. [20]
  Singh M P, Baruah J B. Photophysical properties of Ag, Zn and Cd-N-(4-pyridylmethyl)-1, 8-naphthalimide complexes: Influences of π-stacking and C—H…O interactions[J]. CrystEngComm, 2020,22:4374-4385. doi: 10.1039/D0CE00555J
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
4. [4]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
13. [13]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
14. [14]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
15. [15]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
16. [16]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
17. [17]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
18. [18]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
19. [19]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
20. [20]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(692)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, crystal structures of two silver coordination polymers based on β-diketone ligand

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com