Citation: Gao-Feng WANG, Shu-Wen SUN, Shao-Fei SONG, Mei LÜ. Synthesis of a Cd(Ⅱ)-based coordination polymer for luminescence detecting 2, 4, 6-trinitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2407-2414. doi: 10.11862/CJIC.2023.197 shu

Synthesis of a Cd(Ⅱ)-based coordination polymer for luminescence detecting 2, 4, 6-trinitrophenol

Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Gao-Feng WANG, wgf1979@126.com
Received Date: 11 June 2023
Revised Date: 31 October 2023

Figures(8)

A novel Cd(Ⅱ)-based coordination polymer (CP), {[Cd(adc)(dppc)(H₂O)]·2H₂O}_n (1), was synthesized by a solvothermal method based on adamantane-1, 3-dicarboxylic acid (H₂adc) and 3, 6-di(pyridin-4-yl)-9-(4-(pyridin-4-yl) phenyl)-9H-carbazole (dppc). Complex 1 belongs to the monoclinic system with space group C2/c, which exhibits a layer structure. The adjacent layers are extended via weak interactions to form a 3D supramolecular structure. Moreover, 1 displayed an excellent photoluminescence property, which can be used as a"turn-off"fluorescence probe to detect 2, 4, 6-trini-trophenol in DMF solution with high selectivity and sensitivity with K_sv of 7.6×10⁴ L·mol^-1.
- carbazole,
- coordination polymer,
- Cd(Ⅱ),
- luminescence detecting,
- nitroaromatic compounds
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