Citation: Gao-Feng WANG, Shu-Wen SUN, Shao-Fei SONG, Mei LÜ. Synthesis of a Cd(Ⅱ)-based coordination polymer for luminescence detecting 2, 4, 6-trinitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2407-2414. doi: 10.11862/CJIC.2023.197 shu

Synthesis of a Cd(Ⅱ)-based coordination polymer for luminescence detecting 2, 4, 6-trinitrophenol

Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Gao-Feng WANG, wgf1979@126.com
Received Date: 11 June 2023
Revised Date: 31 October 2023

Figures(8)

A novel Cd(Ⅱ)-based coordination polymer (CP), {[Cd(adc)(dppc)(H₂O)]·2H₂O}_n (1), was synthesized by a solvothermal method based on adamantane-1, 3-dicarboxylic acid (H₂adc) and 3, 6-di(pyridin-4-yl)-9-(4-(pyridin-4-yl) phenyl)-9H-carbazole (dppc). Complex 1 belongs to the monoclinic system with space group C2/c, which exhibits a layer structure. The adjacent layers are extended via weak interactions to form a 3D supramolecular structure. Moreover, 1 displayed an excellent photoluminescence property, which can be used as a"turn-off"fluorescence probe to detect 2, 4, 6-trini-trophenol in DMF solution with high selectivity and sensitivity with K_sv of 7.6×10⁴ L·mol^-1.
- carbazole,
- coordination polymer,
- Cd(Ⅱ),
- luminescence detecting,
- nitroaromatic compounds
1. [1]
  Meaney M S, McGuffin V L. Investigation of common fluorophores for the detection of nitrated explosives by fluorescence quenching[J]. Anal. Chim. Acta, 2008,610:57-67. doi: 10.1016/j.aca.2008.01.016
2. [2]
  Pramanik S, Zheng C, Zhang X, Emge T J, Li J. New microporous metal- organic framework demonstrating unique selectivity for detection of high explosives and aromatic compounds[J]. J. Am. Chem. Soc., 2001,133:4153-4155.
3. [3]
  Nagarkar S S, Desai A V, Ghosh S K. Engineering metal - organic frameworks for aqueous phase 2, 4, 6 - trinitrophenol (TNP) sensing[J]. CrystEngComm, 2016,18:2994-3007. doi: 10.1039/C6CE00244G
4. [4]
  Nagarkar S S, Desai A V, Samanta P, Ghosh S K. Aqueous phase selective detection of 2, 4, 6-trinitrophenol using a fluorescent metalorganic framework with a pendant recognition site[J]. Dalton. Trans., 2015,44:15175-15180. doi: 10.1039/C5DT00397K
5. [5]
  Gole B, Bar A K, Mukherjee P S. Multicomponent assembly of fluorescent-tag functionalized ligands in metal-organic frameworks for sensing explosives[J]. Chem.-Eur. J., 2014,20:13321-13326. doi: 10.1002/chem.201402791
6. [6]
  He G, Peng H N, Liu T H, Yang M N, Zhang Y, Fang Y. A novel picric acid film sensor via combination of the surface enrichment effect of chitosan films and the aggregation - induced emission effect of siloles[J]. J. Mater. Chem., 2009,19:7347-7353. doi: 10.1039/b906946a
7. [7]
  Li A, Li L, Lin Z, Song L, Wang Z H, Chen Q, Yang T, Zhou X H, Xiao H P, Yin X J. Guest - induced reversible structural transitions and concomitant on/off luminescence switching of an Eu(Ⅲ) metal - organic framework and its application in detecting picric acid[J]. New J. Chem., 2015,39:2289-2295. doi: 10.1039/C4NJ01946F
8. [8]
  Li Y H, Han X J, Song Y. An azo-phenol derivative probe: Colorimetric and"turn-on"fluorescent detection of copper(Ⅱ) ions and pH value in aqueous solution[J]. RSC Adv., 2017,7:20537-20541. doi: 10.1039/C7RA01109A
9. [9]
  Harper R J, Almirall J R, Furton K G. Identification of dominant odor chemicals emanating from explosives for use in developing optimal training aid combinations and mimics for canine detection[J]. Talanta, 2005,67:313-327. doi: 10.1016/j.talanta.2005.05.019
10. [10]
  Hasegawa S, Horike S, Matsuda R, Furukawa S, Mochizuki K, Kinoshita Y, Kitagawa S. Three - dimensional porous coordination polymer functionalized with amide groups based on tridentate ligand: Selective sorption and catalysis[J]. J. Am. Chem. Soc., 2007,129:2607-2614. doi: 10.1021/ja067374y
11. [11]
  Li J R, Kuppler R J, Zhou H C. Selective gas adsorption and separation in metal- organic frameworks[J]. Chem. Soc. Rev., 2009,38:1477-1504. doi: 10.1039/b802426j
12. [12]
  Hu Z, Deibert B J, Li J. Luminescent metal-organic frameworks for chemical sensing and explosive detection[J]. Chem. Soc. Rev., 2014,43:5815-5840. doi: 10.1039/C4CS00010B
13. [13]
  Jia C, He T, Wang G M. Zirconium-based metal-organic frameworks for fluorescent sensing[J]. Coord. Chem. Rev., 2023,476214930. doi: 10.1016/j.ccr.2022.214930
14. [14]
  Li J R, Sculley J, Zhou H C. Metal- organic frameworks for separations[J]. Chem. Rev., 2012,112:869-932. doi: 10.1021/cr200190s
15. [15]
  Stock N, Biswas S. Synthesis of metal- organic frameworks (MOFs): Routes to various MOF topologies, morphologies, and composites[J]. Chem. Rev., 2012,112:933-969. doi: 10.1021/cr200304e
16. [16]
  Guillerm V, Kim D, Eubank J F, Luebke R, Liu X, Adil K, Lah M S, Eddaoudi M. A supermolecular building approach for the design and construction of metal-organic frameworks[J]. Chem. Soc. Rev., 2014,43:6141-6172. doi: 10.1039/C4CS00135D
17. [17]
  Zhang J F, Wu J J, Tang G D, Feng J Y, Luo F M, Xu B, Zhang C. Multiresponsive water - stable luminescent Cd coordination polymer for detection of TNP and Cu²⁺[J]. Sens. Actuator B-Chem., 2018,272:166-174. doi: 10.1016/j.snb.2018.05.121
18. [18]
  Wang G F, Yang H Y, Peng D Q, Sun S W. Two zinc and cadmium coordination polymers constructed with bis(4 - (1H - imidazol - 1 - yl) phenyl)methanone and naphthalene-1, 4-dicarboxylate ligands: Synthesis and structural characterization[J]. Z. Naturforsch., 2022,77b:643-649.
19. [19]
  Wang G F. Structural diversity of two coordination polymers based on bis(4-(1H-Imidazol-1- yl)phenyl)methanone and polycarboxylate coligands: Syntheses, structures, and fluorescent properties[J]. Russ. J. Coord. Chem., 2018,44:540-546. doi: 10.1134/S1070328418090075
20. [20]
  Shi H P, Xin D H, Dong X Q, Dai J X, Wu X H, Miao Y Q, Fang L, Wang H, Choi M M F. A star-shaped bipolar host material based on carbazole and dimesitylboron moieties for fabrication of highly efficient red, green and blue electrophosphorescent devices[J]. J. Mater. Chem. C, 2014,2:2160-2168. doi: 10.1039/C3TC32236J
21. [21]
  Sheldrick G M. SADABS, Program for empirical adsorption correction of area detector data. University of Göttingen, Germany, 2003.
22. [22]
  Sheldrick G M. SHELXL 2014/7, Program for crystal structure refinement. University of Göttingen, Germany, 2014.
23. [23]
  Sheldrick G M. A short history of SHELX[J]. Acta Crystallogr. Sect. A, 2008,A64:112-122.
24. [24]
  Tian D, Li Y, Chen R Y, Chang Z, Wang G. Y, Bu X H. , Bu X H[J]. A luminescent metal- organic framework demonstrating ideal detection ability for nitroaromatic explosives. J. Mater. Chem. A, 2014,2:1465-1470.
25. [25]
  Rachuri Y, Parmar B, Bishta K K, Suresh E. Mixed ligand two dimensional Cd(Ⅱ)/Ni(Ⅱ) metal organic frameworks containing dicarboxylate and tripodal N - donor ligands: Cd(Ⅱ) MOF is an efficient luminescent sensor for detection of picric acid in aqueous media[J]. Dalton. Trans., 2016,45:7881-7892. doi: 10.1039/C6DT00753H
26. [26]
  Parmar B, Rachuri Y, Bisht K K, Suresh E. Syntheses and structural analyses of new 3D isostructural Zn(Ⅱ) and Cd(Ⅱ) luminescent MOFs and their application towards detection of nitroaromatics in aqueous media[J]. ChemistrySelect, 2016,1:6308-6315. doi: 10.1002/slct.201601134
27. [27]
  Blatov V A. Multipurpose crystallochemical analysis with the program package TOPOS. [2023-11-03]. https://www.iucr.org/resources/commissions/crystallographic-computing/newsletters/7/topos
28. [28]
  XU H, PAN Z R, QI Z P, SUN J. Three luminescent Zn-MOFs based on V-shaped ligands for fluorescence sensing of 2, 4, 6-trinitrophenol and Fe³⁺ in aqueous solution[J]. Chinese J. Inorg. Chem, 2022,38(12):2479-2490.
29. [29]
  Zhang J F, Wu J J, Gong L P, Feng J Y, Zhang C. Water-stable luminescent Zn(Ⅱ) metal-organic framework as rare multifunctional sensor for Cr(Ⅵ) and TNP[J]. ChemistrySelect, 2017,2:7465-7473. doi: 10.1002/slct.201701253
30. [30]
  Wang J, Wu X R, Liu J Q, Li B H, Singh A, Kumar A, Batten S R. An uncommon (5, 5)-connected 3D metal organic material for selective and sensitive sensing of nitroaromatics and ferric ion: Experimental studies and theoretical analysis[J]. CrystEngComm, 2017,19:3519-3525. doi: 10.1039/C7CE00912G
31. [31]
  He H M, Chen S H, Zhang D Y, Yan E C, Zhao X J. A luminescent metal- organic framework as an ideal chemosensor for nitroaromatic compounds[J]. RSC Adv., 2017,7:38871-38876. doi: 10.1039/C7RA06320B
32. [32]
  He H M, Song Y, Sun F X, Bian Z, Gao L X, Zhu G S. A porous metal-organic framework formed by a V-shaped ligand and Zn(Ⅱ) ion with highly selective sensing for nitroaromatic explosives[J]. J. Mater. Chem. A, 2015,3:16598-16603. doi: 10.1039/C5TA03537F
33. [33]
  Deng Y J, Chen N J, Li Q Y, Wu X J, Huang X L, Lin Z H, Zhao Y G. Highly fluorescent metal-organic frameworks based on a benzenecored tetraphenylethene derivative with the ability to detect 2, 4, 6 - trinitrophenol in water[J]. Cryst. Growth Des., 2017,17:3170-3177. doi: 10.1021/acs.cgd.7b00131
34. [34]
  Yang Y, Shen K, Lin J Z, Zhou Y, Liu Q Y, Hang C, Abdelhamid H N, Zhang Z Q, Chen H. A Zn-MOF constructed from electron-rich π- conjugated ligands with an interpenetrated graphene-like net as an efficient nitroaromatic sensor[J]. RSC Adv., 2016,6:45475-45481. doi: 10.1039/C6RA00524A
35. [35]
  Song X Z, Song S Y, Zhao S N, Hao Z M, Zhu M, Meng X, Wu L L, Zhang H J. Single-crystal-to-single-crystal transformation of a europium(Ⅲ) metal-organic framework producing a multi-responsive luminescent sensor[J]. Adv. Funct. Mater., 2014,24:4034-4041. doi: 10.1002/adfm.201303986
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