Citation: Xing-Han CHEN, Min SHU, Feng LI, Rui ZHANG, Jian LIU. Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2279-2286. doi: 10.11862/CJIC.2023.196 shu

Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers

Xing-Han CHEN ¹ ,
Min SHU ¹ ,
Feng LI ^2,, ,
Rui ZHANG ¹ ,
Jian LIU ^1,,

1.
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Shandong Peninsula Engineering Research Center of Comprehensive Brine Utilization, Weifang University of Science and Technology, Weifang, Shandong 262700, China

Corresponding author: Feng LI, fengli81@163.com Jian LIU, liu.jian@njfu.edu.cn
Received Date: 15 August 2023
Revised Date: 1 November 2023

Figures(7)

In this work, novel terpyridine-Fe(Ⅱ) coordination polymers were prepared by introducing an aromatic ring as a π-spacer between two terpyridine units to construct multi-dented ligands, which were coordinated with Iron(Ⅱ) tetrafluoroborate hexahydrate. The electrochromic properties of the terpyridine-Fe(Ⅱ) coordination polymers were investigated. The results indicated that the introduction of fluorine atoms on the aromatic ring had a certain effect on their electrochromic properties. Among them, coordination polymer Fe-F2 prepared derived from the ligand F2 containing two fluorine atoms showed excellent electrochromic properties (optical contrast up to 69%, response time as short as 0.5 s, coloration efficiency over 320 cm²·C^-1).
- terpyridine,
- Fe(Ⅱ) coordination polymers,
- electrochromism
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