Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers
- Corresponding author: Feng LI, fengli81@163.com Jian LIU, liu.jian@njfu.edu.cn
Citation:
Xing-Han CHEN, Min SHU, Feng LI, Rui ZHANG, Jian LIU. Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry,
;2023, 39(12): 2279-2286.
doi:
10.11862/CJIC.2023.196
Chen H J, Wang W Y, Zhu J J, Han Y Y, Liu J. Electropolymerization of D-A type EDOT-based monomers consisting of camphor substituted quinoxaline unit for electrochromism with enhanced performance[J]. Polymer, 2022,240124485. doi: 10.1016/j.polymer.2021.124485
Fu W A, Chen H J, Han Y Y, Wang W Y, Zhang R, Liu J. Electropolymerization of D-A-D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices[J]. New J. Chem., 2021,45(40):19082-19087. doi: 10.1039/D1NJ04074J
Zhu J J, Wang W Y, Chen H J, Han Y Y, Liu J. Electropolymerization of D-A-D type monomers consisting of thiophene and quionaxline moieties for electrochromic devices and supercapacitors[J]. J. Solid State Chem., 2022,307122739. doi: 10.1016/j.jssc.2021.122739
Cong S, Geng F X, Zhao Z G. Tungsten oxide materials for optoelectronic applications[J]. Adv. Mater., 2016,28(47):10518-10528. doi: 10.1002/adma.201601109
Guo W B, Cong Z F, Guo Z H, Zhang P P, Chen Y H, Hu W G, Wang Z L, Pu X. Multifunctional self-charging electrochromic supercapacitors driven by direct-current triboelectric nanogenerators[J]. Adv. Funct. Mater., 2021,31(36)2104348. doi: 10.1002/adfm.202104348
Jo M H, Kim K H, Ahn H J. P-doped carbon quantum dot graft-functionalized amorphous WO3 for stable and flexible electrochromic energy-storage devices[J]. Chem. Eng. J., 2022,445136826. doi: 10.1016/j.cej.2022.136826
Banasz R, Wałęsa-Chorab M. Polymeric complexes of transition metal ions as electrochromic materials: Synthesis and properties[J]. Coord. Chem. Rev., 2019,389:1-18. doi: 10.1016/j.ccr.2019.03.009
Lu H C, Kao S Y, Yu H F, Chang T H, Kung C W, Ho K C. Achieving low-energy driven viologens-based electrochromic devices utilizing polymeric ionic liquids[J]. ACS Appl. Mater. Interfaces, 2016,8(44):30351-30361. doi: 10.1021/acsami.6b10152
Lo C K, Shen D E, Reynolds J R. Fine-tuning the color hue of π-conjugated black-to-clear electrochromic random copolymers[J]. Macromolecules, 2019,52(17):6773-6779. doi: 10.1021/acs.macromol.9b01443
Sato T, Higuchi M. An alternately introduced heterometallo-supramolecular polymer: synthesis and solid-state emission switching by electrochemical redox[J]. Chem. Commun., 2013,49(46):5256-5258. doi: 10.1039/c3cc41176a
XING J N, SHU M, WANG W Y, ZHANG R, LIU J. Synthesis and properties of electrochromic material based on phenanthroline Fe(Ⅱ) complex with triphenylamine moiety[J]. Chinese J. Inorg. Chem., 2021,37(10):1847-1852.
Malik N, Dov N E, de Ruiter G, Lahav M, van der Boom M E. On-surface self-assembly of stimuli-responsive metallo-organic films: Automated ultrasonic spray-coating and electrochromic devices[J]. ACS Appl. Mater. Interfaces, 2019,11(25):22858-22868. doi: 10.1021/acsami.9b05512
Schott M, Szczerba W, Posset U, Vuk A S, Beck M, Riesemeier H, Thünemann A F, kurth D G. In operando XAFS experiments on flexible electrochromic devices based on Fe(Ⅱ)-metallo-supramolecular polyelectrolytes and vanadium oxide[J]. Sol. Energy Mater. Sol. Cells, 2016,147:61-67. doi: 10.1016/j.solmat.2015.10.015
Shu M, Tao J Y, Han Y Y, Fu W A, Li X W, Zhang R, Liu J. Molecular engineering of terpyridine-Fe(Ⅱ) coordination polymers consisting of quinoxaline-based π-spacers toward enhanced electrochromic performance[J]. Polymer, 2022,256125231. doi: 10.1016/j.polymer.2022.125231
Xing J N, Yue Y F, Zhang R, Liu J. Molecular engineering of head-tail terpyridine-Fe(Ⅱ) coordination polymers employing alkyl chain linkers toward enhanced electrochromic performance[J]. Dyes Pigment., 2021,189109233. doi: 10.1016/j.dyepig.2021.109233
Mukkatt I, Mohanachandran A P, Nirmala A, Patra D, Sukumaran P A, Pillai R S, Rakhi R B, Shankar S, Ajayaghosh A. Tunable capacitive behavior in metallopolymer-based electrochromic thin film supercapacitors[J]. ACS Appl. Mater. Interfaces, 2022,14(28):31900-31910. doi: 10.1021/acsami.2c05744
Mondal S, Santra D C, Ninomiya Y, Yoshida T, Higuchi M. Dualredox system of metallo-supramolecular polymers for visible-to-near-IR modulable electrochromism and durable device fabrication[J]. ACS Appl. Mater. Interfaces, 2020,12(52):58277-58286. doi: 10.1021/acsami.0c18109
Chen W, Xue G. Low potential electrochemical syntheses of heteroaromatic conducting polymers in a novel solvent system based on trifluroborate-ethyl ether[J]. Prog. Polym. Sci., 2005,30(7):783-811. doi: 10.1016/j.progpolymsci.2005.03.002
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
.
Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
Mingxin LU , Liyang ZHOU , Xiaoyu XU , Xiaoying FENG , Hui WANG , Bin YAN , Jie XU , Chao CHEN , Hui MEI , Feng GAO . Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 329-338. doi: 10.11862/CJIC.20240206
Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
Tongyu Zheng , Teng Li , Xiaoyu Han , Yupei Chai , Kexin Zhao , Quan Liu , Xiaohui Ji . A DIY pH Detection Agent Using Persimmon Extract for Acid-Base Discoloration Popularization Experiment. University Chemistry, 2024, 39(5): 27-36. doi: 10.3866/PKU.DXHX202309107
Yingying Chen , Di Xu , Congmin Wang . Exploration and Practice of the “Four-Level, Three-Linkage” General Chemistry Course System. University Chemistry, 2024, 39(8): 119-125. doi: 10.3866/PKU.DXHX202401057
Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
Electrolyte: 0.1 mol·L-1 aqueous solution of LiBF4, scan rate: 100 mV·s-1.