Citation: Xing-Han CHEN, Min SHU, Feng LI, Rui ZHANG, Jian LIU. Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2279-2286. doi: 10.11862/CJIC.2023.196 shu

Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers

Xing-Han CHEN ¹ ,
Min SHU ¹ ,
Feng LI ^2,, ,
Rui ZHANG ¹ ,
Jian LIU ^1,,

1.
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Shandong Peninsula Engineering Research Center of Comprehensive Brine Utilization, Weifang University of Science and Technology, Weifang, Shandong 262700, China

Corresponding author: Feng LI, fengli81@163.com Jian LIU, liu.jian@njfu.edu.cn
Received Date: 15 August 2023
Revised Date: 1 November 2023

Figures(7)

In this work, novel terpyridine-Fe(Ⅱ) coordination polymers were prepared by introducing an aromatic ring as a π-spacer between two terpyridine units to construct multi-dented ligands, which were coordinated with Iron(Ⅱ) tetrafluoroborate hexahydrate. The electrochromic properties of the terpyridine-Fe(Ⅱ) coordination polymers were investigated. The results indicated that the introduction of fluorine atoms on the aromatic ring had a certain effect on their electrochromic properties. Among them, coordination polymer Fe-F2 prepared derived from the ligand F2 containing two fluorine atoms showed excellent electrochromic properties (optical contrast up to 69%, response time as short as 0.5 s, coloration efficiency over 320 cm²·C^-1).
- terpyridine,
- Fe(Ⅱ) coordination polymers,
- electrochromism
1. [1]
  Chen H J, Wang W Y, Zhu J J, Han Y Y, Liu J. Electropolymerization of D-A type EDOT-based monomers consisting of camphor substituted quinoxaline unit for electrochromism with enhanced performance[J]. Polymer, 2022,240124485. doi: 10.1016/j.polymer.2021.124485
2. [2]
  Fu W A, Chen H J, Han Y Y, Wang W Y, Zhang R, Liu J. Electropolymerization of D-A-D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices[J]. New J. Chem., 2021,45(40):19082-19087. doi: 10.1039/D1NJ04074J
3. [3]
  Zhu J J, Wang W Y, Chen H J, Han Y Y, Liu J. Electropolymerization of D-A-D type monomers consisting of thiophene and quionaxline moieties for electrochromic devices and supercapacitors[J]. J. Solid State Chem., 2022,307122739. doi: 10.1016/j.jssc.2021.122739
4. [4]
  Cong S, Geng F X, Zhao Z G. Tungsten oxide materials for optoelectronic applications[J]. Adv. Mater., 2016,28(47):10518-10528. doi: 10.1002/adma.201601109
5. [5]
  Guo W B, Cong Z F, Guo Z H, Zhang P P, Chen Y H, Hu W G, Wang Z L, Pu X. Multifunctional self-charging electrochromic supercapacitors driven by direct-current triboelectric nanogenerators[J]. Adv. Funct. Mater., 2021,31(36)2104348. doi: 10.1002/adfm.202104348
6. [6]
  Jo M H, Kim K H, Ahn H J. P-doped carbon quantum dot graft-functionalized amorphous WO₃ for stable and flexible electrochromic energy-storage devices[J]. Chem. Eng. J., 2022,445136826. doi: 10.1016/j.cej.2022.136826
7. [7]
  Banasz R, Wałęsa-Chorab M. Polymeric complexes of transition metal ions as electrochromic materials: Synthesis and properties[J]. Coord. Chem. Rev., 2019,389:1-18. doi: 10.1016/j.ccr.2019.03.009
8. [8]
  Lu H C, Kao S Y, Yu H F, Chang T H, Kung C W, Ho K C. Achieving low-energy driven viologens-based electrochromic devices utilizing polymeric ionic liquids[J]. ACS Appl. Mater. Interfaces, 2016,8(44):30351-30361. doi: 10.1021/acsami.6b10152
9. [9]
  Lo C K, Shen D E, Reynolds J R. Fine-tuning the color hue of π-conjugated black-to-clear electrochromic random copolymers[J]. Macromolecules, 2019,52(17):6773-6779. doi: 10.1021/acs.macromol.9b01443
10. [10]
  Sato T, Higuchi M. An alternately introduced heterometallo-supramolecular polymer: synthesis and solid-state emission switching by electrochemical redox[J]. Chem. Commun., 2013,49(46):5256-5258. doi: 10.1039/c3cc41176a
11. [11]
  XING J N, SHU M, WANG W Y, ZHANG R, LIU J. Synthesis and properties of electrochromic material based on phenanthroline Fe(Ⅱ) complex with triphenylamine moiety[J]. Chinese J. Inorg. Chem., 2021,37(10):1847-1852.
12. [12]
  Malik N, Dov N E, de Ruiter G, Lahav M, van der Boom M E. On-surface self-assembly of stimuli-responsive metallo-organic films: Automated ultrasonic spray-coating and electrochromic devices[J]. ACS Appl. Mater. Interfaces, 2019,11(25):22858-22868. doi: 10.1021/acsami.9b05512
13. [13]
  Schott M, Szczerba W, Posset U, Vuk A S, Beck M, Riesemeier H, Thünemann A F, kurth D G. In operando XAFS experiments on flexible electrochromic devices based on Fe(Ⅱ)-metallo-supramolecular polyelectrolytes and vanadium oxide[J]. Sol. Energy Mater. Sol. Cells, 2016,147:61-67. doi: 10.1016/j.solmat.2015.10.015
14. [14]
  Shu M, Tao J Y, Han Y Y, Fu W A, Li X W, Zhang R, Liu J. Molecular engineering of terpyridine-Fe(Ⅱ) coordination polymers consisting of quinoxaline-based π-spacers toward enhanced electrochromic performance[J]. Polymer, 2022,256125231. doi: 10.1016/j.polymer.2022.125231
15. [15]
  Xing J N, Yue Y F, Zhang R, Liu J. Molecular engineering of head-tail terpyridine-Fe(Ⅱ) coordination polymers employing alkyl chain linkers toward enhanced electrochromic performance[J]. Dyes Pigment., 2021,189109233. doi: 10.1016/j.dyepig.2021.109233
16. [16]
  Mukkatt I, Mohanachandran A P, Nirmala A, Patra D, Sukumaran P A, Pillai R S, Rakhi R B, Shankar S, Ajayaghosh A. Tunable capacitive behavior in metallopolymer-based electrochromic thin film supercapacitors[J]. ACS Appl. Mater. Interfaces, 2022,14(28):31900-31910. doi: 10.1021/acsami.2c05744
17. [17]
  Mondal S, Santra D C, Ninomiya Y, Yoshida T, Higuchi M. Dualredox system of metallo-supramolecular polymers for visible-to-near-IR modulable electrochromism and durable device fabrication[J]. ACS Appl. Mater. Interfaces, 2020,12(52):58277-58286. doi: 10.1021/acsami.0c18109
18. [18]
  Chen W, Xue G. Low potential electrochemical syntheses of heteroaromatic conducting polymers in a novel solvent system based on trifluroborate-ethyl ether[J]. Prog. Polym. Sci., 2005,30(7):783-811. doi: 10.1016/j.progpolymsci.2005.03.002
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com