Citation: Pei-Pei CUI, Yue SUN, Yi ZHA, Sheng-Nan LIU, Meng-Xin ZHANG, Ji-Yun CAO, Qi WANG, Xiao-Qing WANG. Synthesis, structural characterization, and fluorescence property of three coordination polymers with dicarboxylate ligands[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2358-2366. doi: 10.11862/CJIC.2023.191 shu

Synthesis, structural characterization, and fluorescence property of three coordination polymers with dicarboxylate ligands

Pei-Pei CUI ^{1, 2,,} ,
Yue SUN ¹ ,
Yi ZHA ¹ ,
Sheng-Nan LIU ¹ ,
Meng-Xin ZHANG ¹ ,
Ji-Yun CAO ¹ ,
Qi WANG ¹ ,
Xiao-Qing WANG ²

1.
School of Life Science, Dezhou University, Dezhou, Shandong 253023, China
2.
School of Chemistry and Chemical Engineering, North University of China, Taiyuan 030051, China

Corresponding author: Pei-Pei CUI, 1cuipeipei1@163.com
Received Date: 16 June 2023
Revised Date: 18 October 2023

Figures(7)

Three coordination polymers (CPs), namely, {[Ni(L¹)(H₂O)₄]·2H₂O}_n (1), [Zn(L¹)(DMA)₂]_n (2), and [Co(L²)(DMF)₂]_n (3) (DMA=N, N-dimethylacetamide, DMF=N, N-dimethylformamide) were synthesized based on dicarboxylate ligands 2, 2′-(1, 4-phenylenebis(methylene))bis(sulfanediyl)dibenzoic acid (H₂L¹) and 2, 2′-(2, 3, 5, 6-tetramethyl-1, 4-phenylene)bis(methylene)bis(sulfanediyl)dibenzoic acid (H₂L²) under solvothermal conditions. Complexes 1-3 have been structurally characterized by single-crystal X-ray diffraction analyses and characterized by elemental analysis, infrared spectra, thermogravimetric analysis, powder X-ray diffraction, and solid-state UV-Vis spectrum. They have zigzag chain structures and the ligands all display anti-conformation. Besides, the chains in 1-3 further form 3D frameworks by hydrogen bonding interactions. Furthermore, the solid-state fluorescence property of 2 was investigated.
- dicarboxylate ligand,
- coordination polymer,
- crystal structure,
- hydrogen bonding interaction,
- fluorescence property
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