Citation: Xiu-Qi KANG, Jia-Hao WANG, Jin-Zhong GU. Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), nickel(Ⅱ) and cobalt(Ⅱ) coordination polymers constructed from 4, 4′-(pyridin-3, 5-diyl)dibenzoic acid[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2385-2392. doi: 10.11862/CJIC.2023.190 shu

Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), nickel(Ⅱ) and cobalt(Ⅱ) coordination polymers constructed from 4, 4′-(pyridin-3, 5-diyl)dibenzoic acid

College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Jin-Zhong GU, gujzh@lzu.edu.cn
Received Date: 21 June 2023
Revised Date: 7 October 2023

Figures(14)

Three zinc(Ⅱ), nickel(Ⅱ), and cobalt(Ⅱ) coordination polymers, namely {[Zn(μ₃-pdba)(phen)]•H₂O}_n (1), {[Ni(μ₃-pdba)(bipy)]•3H₂O}_n (2), and {[Co(μ₃-pdba)(H₂biim)(H₂O)]•H₂O}_n (3) have been constructed hydrothermally using 4, 4′-(pyridin-3, 5-diyl)dibenzoic acid (H₂pdba), 1, 10-phenanthroline (phen), 2, 2′-bipyridine (bipy), 2, 2′-biimdazole (H₂biim), and zinc, nickel and cobalt chlorides at 160 ℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses reveal that the three compounds crystallize in the monoclinic system, space groups P2₁/c or P2₁/n. Compounds 1 and 2 show 2D networks. Compound 3 discloses a 1D ladder chain structure. The catalytic activities in the Henry reaction of these compounds were investigated. Compound 1 exhibited an effective catalytic activity in the Henry reaction at 70 ℃. For this reaction, various parameters were optimized, followed by the investigation of the substrate scope.
- coordination polymer,
- dicarboxylic acid,
- catalytic property,
- Henry reaction
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