Citation: Hong-Jian LI, Jun GU, Xiao-Fei SHI, Fu-Liang LIU, Xiao-Tao CHEN. High CO-tolerant intermetallic PtBi nanoplates for methanol electrooxidation[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2074-2082. doi: 10.11862/CJIC.2023.185 shu

High CO-tolerant intermetallic PtBi nanoplates for methanol electrooxidation

Guizhou Meiling Power Source Co. Ltd., State Key Laboratory of Advanced Chemical Power Source, Zunyi, Guizhou 563003, China

Corresponding author: Hong-Jian LI, 18380235038@163.com
Received Date: 23 April 2023
Revised Date: 17 October 2023

Figures(8)

We prepared an intermetallic PtBi nanoplate with high CO tolerance by thermal injection. The prepared intermetallic PtBi nanoplates showed excellent catalytic performance and stability for methanol oxidation reaction (MOR). The peak mass activity was up to 4.09 A·mg_Pt^-1, which was nearly 3.2 times that of commercial Pt/C. After the current-time (I-t) stability test, the property decreased by only 5.7%, much lower than commercial Pt/C. CO-Stripping curves and evolution of cyclic voltammetric (CV-Evolution) curves confirmed high CO tolerance of inter-metallic PtBi nanoplates.
- fuel cells,
- methanol oxidation reaction,
- CO tolerance,
- intermetallic PtBi nanoplates
1. [1]
  CHANG L Y, WANG R Z. Research progress and design strategy of membrane electrode assembly for high-performance proton exchange membrane fuel cell[J]. Journal of Beijing University of Technology, 2022,43(3):345-354.
2. [2]
  Bu L Z, Liang J S, Ning F D, Huang J, Huang B L, Sun M Z, Zhan C H, Ma Y H, Zhou X C, Li Q, Huang X Q. Low-coordination trimetallic PtFeCo nanosaws for practical fuel cells[J]. Adv. Mater., 2023,35(11)2208672. doi: 10.1002/adma.202208672
3. [3]
  Wang X P, Xi S B, Lee W S V, Huang P R, Cui P, Zhao L, Hao W C, Zhao X S, Wang Z B, Wu H J, Wang H, Diao C Z, Borgna A, Du Y H, Yu Z G, Pennycook S, Xue J M. Materializing efficient methanol oxidation via electron delocalization in nickel hydroxide nanoribbon[J]. Nat. Commun., 2020,11(1)4647. doi: 10.1038/s41467-020-18459-9
4. [4]
  Chen X T, Granda-Marulanda L P, McCrum I T, Koper M T M. How palladium inhibits CO poisoning during electrocatalytic formic acid oxidation and carbon dioxide reduction[J]. Nat. Commun., 2022,13(1)38. doi: 10.1038/s41467-021-27793-5
5. [5]
  Bao Y F, Liu H, Liu Z, Wang F L, Feng L G. Pd/FeP catalyst engineering via thermal annealing for improved formic acid electrochemical oxidation[J]. Appl. Catal. B-Environ., 2020,274119106. doi: 10.1016/j.apcatb.2020.119106
6. [6]
  Tian X L, Lu X F, Xia B Y, Lou X W. Advanced electrocatalysts for the oxygen reduction reaction in energy conversion technologies[J]. Joule, 2020,4(1):45-68. doi: 10.1016/j.joule.2019.12.014
7. [7]
  Chang J F, Wang G Z, Li C, He Y Q, Zhu Y M, Zhang W, Sajid M, Kara A, Gu M, Yang Y. Rational design of septenary high-entropy alloy for direct ethanol fuel cells[J]. Joule, 2023,7(3):587-602. doi: 10.1016/j.joule.2023.02.011
8. [8]
  Wang K L, Huang D Y, Guan Y C, Liu F, He J, Ding Y. Fine-tuning the electronic structure of dealloyed PtCu nanowires for efficient methanol oxidation reaction[J]. ACS Catal., 2021,11(23):14428-14438. doi: 10.1021/acscatal.1c04424
9. [9]
  Chen S P, Li M F, Gao M Y, Jin J B, van Spronsen M A, Salmeron M B, Yang P D. High-performance Pt-Co nanoframes for fuel-cell electrocatalysis[J]. Nano Lett., 2020,20(3):1974-1979. doi: 10.1021/acs.nanolett.9b05251
10. [10]
  Zhang S, Zeng Z C, Li Q Q, Huang B L, Zhang X Y, Du Y P, Yan C H. Lanthanide electronic perturbation in Pt-Ln (La, Ce, Pr and Nd) alloys for enhanced methanol oxidation reaction activity[J]. Energy Environ. Sci., 2021,14(11):5911-5918. doi: 10.1039/D1EE02433G
11. [11]
  Xia T Y, Zhao K, Zhu Y Q, Bai X Y, Gao H, Wang Z Y, Gong Y, Feng M L, Li S F, Zheng Q, Wang S G, Wang R M, Guo H Z. Mixed-dimensional Pt-Ni alloy polyhedral nanochains as bifunctional electrocatalysts for direct methanol fuel cells[J]. Adv. Mater., 2023,35(2)2206508. doi: 10.1002/adma.202206508
12. [12]
  Shen T, Gong M X, Xiao D D, Shang T T, Zhao X, Zhang J, Wang D L. Engineering location and supports of atomically ordered L10-PdFe intermetallics for ultra-anticorrosion electrocatalysis[J]. Adv. Funct. Mater., 2022,32(35)2203921. doi: 10.1002/adfm.202203921
13. [13]
  Zhao T H, Wang G J, Gong M X, Xiao D D, Chen Y, Shen T, Lu Y, Zhang J, Xin H L, Li Q, Wang D L. Self-optimized ligand effect in L12-PtPdFe intermetallic for efficient and stable alkaline hydrogen oxidation reaction[J]. ACS Catal., 2020,10(24):15207-15216. doi: 10.1021/acscatal.0c03938
14. [14]
  Wang X C, Liu Y, Ma X Y, Chang L Y, Zhong Q X, Pan Q, Wang Z Q, Yuan X L, Cao M H, Lyu F L, Yang Y Y, Chen J X, Sham T K, Zhang Q. The role of bismuth in suppressing the CO poisoning in alkaline methanol electrooxidation: Switching the reaction from the CO to formate pathway[J]. Nano Lett., 2023,23(2):685-693. doi: 10.1021/acs.nanolett.2c04568
15. [15]
  Chen Y J, Pei J J, Chen Z, Li A, Ji S F, Rong H P, Xu Q, Wang T, Zhang A J, Tang H L, Zhu J F, Han X D, Zhuang Z B, Zhou G, Wang D S. Pt atomic layers with tensile strain and rich defects boost ethanol electrooxidation[J]. Nano Lett., 2022,22(18):7563-7571. doi: 10.1021/acs.nanolett.2c02572
16. [16]
  Wu X Q, Jiang Y, Yan Y C, Li X, Luo S, Huang J B, Li J J, Shen R, Yang D R, Zhang H. Tuning surface structure of Pd₃Pb/PtnPb nano-crystals for boosting the methanol oxidation reaction[J]. Adv. Sci., 2019,6(24)1902249. doi: 10.1002/advs.201902249
17. [17]
  Shen T, Wang S, Zhao T H, Hu Y Z, Wang D L. Recent advances of single-atom-alloy for energy electrocatalysis[J]. Adv. Energy Mater., 2022,12(39)2201823. doi: 10.1002/aenm.202201823
18. [18]
  Ji X L, Lee K T, Holden R, Zhang L, Zhang J J, Botton G A, Couillard M, Nazar L F. Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes[J]. Nat. Chem., 2010,2(4):286-293. doi: 10.1038/nchem.553
19. [19]
  Casado-Rivera E, Volpe D J, Alden L, Lind C, Downie C, Vázquez-Alvarez T, Angelo A C D, DiSalvo F J, Abruña H D. Electrocatalytic activity of ordered intermetallic phases for fuel cell applications[J]. J. Am. Chem. Soc., 2004,126(12):4043-4049. doi: 10.1021/ja038497a
20. [20]
  Liu Y C, Li X H, Shi Y, Wang Y J, Zhao X J, Gong X Y, Cai R, Song G S, Chen M, Zhang X B. Two-dimensional intermetallic PtBi/Pt core/shell nanoplates overcome tumor hypoxia for enhanced cancer therapy[J]. Nanoscale, 2021,13(33):14245-14253. doi: 10.1039/D1NR02561A
21. [21]
  Luo S P, Chen W, Cheng Y, Song X, Wu Q L, Li L X, Wu X T, Wu T H, Li M R, Yang Q, Deng K R, Quan Z W. Trimetallic synergy in intermetallic PtSnBi nanoplates boosts formic acid oxidation[J]. Adv. Mater., 2019,31(40)1903683. doi: 10.1002/adma.201903683
22. [22]
  Yang S, Lee H. Atomically dispersed platinum on gold nano-octahedra with high catalytic activity on formic acid oxidation[J]. ACS Catal., 2013,3(3):437-443. doi: 10.1021/cs300809j
23. [23]
  Huang W J, Wang H T, Zhou J G, Wang J, Duchesne P N, Muir D, Zhang P, Han N, Zhao F P, Zeng M, Zhong J, Jin C H, Li Y G, Lee S T, Dai H J. Highly active and durable methanol oxidation electrocatalyst based on the synergy of platinum-nickel hydroxide-graphene[J]. Nat. Commun., 2015,610035. doi: 10.1038/ncomms10035
24. [24]
  Chen G J, Dai Z F, Sun L, Zhang L, Liu S, Bao H W, Bi J L, Yang S C, Ma F. Synergistic effects of platinum-cerium carbonate hydroxides-reduced graphene oxide on enhanced durability for methanol electro-oxidation[J]. J. Mater. Chem. A, 2019,7(11):6562-6571. doi: 10.1039/C9TA00226J
25. [25]
  Zhang W Q, Yang J Z, Lu X M. Tailoring galvanic replacement reaction for the preparation of Pt/Ag bimetallic hollow nanostructures with controlled number of voids[J]. ACS Nano, 2012,6(8):7397-7405. doi: 10.1021/nn302590k
26. [26]
  Ren F F, Wang C Q, Zhai C Y, Jiang F X, Yue R R, Du Y K, Yang P, Xu J K. One-pot synthesis of a RGO-supported ultrafine ternary PtAuRu catalyst with high electrocatalytic activity towards methanol oxidation in alkaline medium[J]. J. Mater. Chem. A, 2013,1(24):7255-7261. doi: 10.1039/c3ta11291h
27. [27]
  Zhang Z C, Luo Z M, Chen B, Wei C, Zhao J, Chen J Z, Zhang X, Lai Z C, Fan Z X, Tan C L, Zhao M T, Lu Q P, Li B, Zong Y, Yan C C, Wang G X, Xu Z C J, Zhang H. One-pot synthesis of highly anisotropic five-fold-twinned PtCu nanoframes used as a bifunctional electrocatalyst for oxygen reduction and methanol oxidation[J]. Adv. Mater., 2016,28(39):8712-8717. doi: 10.1002/adma.201603075
28. [28]
  Lou Y, Li C G, Gao X D, Bai T Y, Chen C L, Huang H, Liang C, Shi Z, Feng S H. Porous Pt nanotubes with high methanol oxidation electrocatalytic activity based on original bamboo-shaped Te nanotubes[J]. ACS Appl. Mater. Interfaces, 2016,8(25):16147-16153. doi: 10.1021/acsami.6b05350
29. [29]
  Qi Z Y, Xiao C X, Liu C, Goh T W, Zhou L, Maligal-Ganesh R, Pei Y C, Li X L, Curtiss L A, Huang W Y. Sub-4 nm PtZn intermetallic nanoparticles for enhanced mass and specific activities in catalytic electrooxidation reaction[J]. J. Am. Chem. Soc., 2017,139(13):4762-4768. doi: 10.1021/jacs.6b12780
30. [30]
  Guo K, Liu Y, Han M, Xu D D, Bao J C. Highly branched ultrathin Pt-Ru nanodendrites[J]. Chem. Commun., 2019,55(74):11131-11134. doi: 10.1039/C9CC05686F
31. [31]
  Lu S Q, Li H M, Sun J Y, Zhuang Z B. Promoting the methanol oxidation catalytic activity by introducing surface nickel on platinum nanoparticles[J]. Nano Res., 2018,11(4):2058-2068. doi: 10.1007/s12274-017-1822-x
32. [32]
  Liu G G, Zhou W, Ji Y R, Chen B, Fu G T, Yun Q B, Chen S M, Lin Y X, Yin P F, Cui X Y, Liu J W, Meng F Q, Zhang Q H, Song L, Gu L, Zhang H. Hydrogen-intercalation-induced lattice expansion of Pd@Pt core-shell nanoparticles for highly efficient electrocatalytic alcohol oxidation[J]. J. Am. Chem. Soc., 2021,143(29):11262-11270. doi: 10.1021/jacs.1c05856
33. [33]
  Chen L, Zhou L Z, Lu H B, Zhou Y Q, Huang J L, Wang J, Wang Y, Yuan X L, Yao Y. Shape-controlled synthesis of planar PtPb nano-plates for highly efficient methanol electro-oxidation reaction[J]. Chem. Commun., 2020,56(64):9138-9141. doi: 10.1039/D0CC03704D
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