Citation: Ming-Hui LI, Qun YANG, Xing-Yu ZOU, Wu-Lin SONG, Da-Wen ZENG. Synthesis of erythrocyte-like CuS with twin structure and photo-Fenton catalytic performance[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2143-2150. doi: 10.11862/CJIC.2023.178 shu

Synthesis of erythrocyte-like CuS with twin structure and photo-Fenton catalytic performance

Ming-Hui LI ^{1, 2} ,
Qun YANG ³ ,
Xing-Yu ZOU ¹ ,
Wu-Lin SONG ^{1, 2,,} ,
Da-Wen ZENG ¹

1.
State Key Laboratory of Materials Processing and Die& Mould Technology, College of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
2.
Analytical and Testing Center, Huazhong University of Science and Technology, Wuhan 430074, China
3.
Wuhan Maritime Communication Research Institute, Wuhan 430205, China

Corresponding author: Wu-Lin SONG, wulins@126.com
Received Date: 17 February 2023
Revised Date: 4 October 2023

Figures(10)

An erythrocyte-like copper sulfide material with twins was synthesized by a solvothermal method. It was found that the different precursor proportions and reaction times play key roles in the formation of erythrocyte-like CuS. The formation mechanism of twin erythrocyte-like CuS was systematically elaborated. The Fenton-like system composed of CuS and H₂O₂ showed excellent degradation performance under visible light irradiation, and the degradation rate of methylene blue reached 95% after 50 min under visible light. The catalytic performance of the erythrocyte-like CuS and the synthetic flower ball-like CuS was compared, and the degradation performance of the erythrocyte-like CuS was better, indicating that the twin crystals accelerate the separation of photogenerated electrons-holes.
- erythrocyte-like CuS,
- twin boundary,
- photo-Fenton,
- pollutant degradation
1. [1]
  Wang L, Jin P X, Duan S H, Huang J W, She H D, Wang Q Z, An T C. Accelerated Fenton-like kinetics by visible-light-driven catalysis over iron(Ⅲ) porphyrin functionalized zirconium MOF: Effective promotion on the degradation of organic contaminants[J]. Environ. Sci.: Nano, 2019,6(8):2652-2661. doi: 10.1039/C9EN00460B
2. [2]
  Qin Y X, Li G Y, Zhang L Z, An T C. Protocatechuic acid promoted catalytic degradation of rhodamine B with Fe@Fe₂O₃ core-shell nanowires by molecular oxygen activation mechanism[J]. Catal. Today, 2019,335:144-150. doi: 10.1016/j.cattod.2018.10.058
3. [3]
  Zhang Y, Zhou M H. A critical review of the application of chelating agents to enable Fenton and Fenton-like reactions at high pH values[J]. J. Hazard. Mater., 2019,362:436-450. doi: 10.1016/j.jhazmat.2018.09.035
4. [4]
  Ganiyu S O, Sable S, Eidin M G. Advanced oxidation processes for the degradation of dissolved organics in produced water: A review of process performance, degradation kinetics and pathway[J]. Chem. Eng. J., 2022,429132492. doi: 10.1016/j.cej.2021.132492
5. [5]
  Metin S, Çifçi D İ. Chemical industry wastewater treatment by coagulation combined with Fenton and photo-Fenton processes[J]. J. Chem. Technol. Biotechnol., 2023,98(5):1158-1165. doi: 10.1002/jctb.7321
6. [6]
  Tanveer R, Yasar A, Tabinda A, Ikhlaq A, Nissar H, Nizami A. Comparison of ozonation, Fenton, and photo-Fenton processes for the treatment of textile dye-bath effluents integrated with electrocoagulation[J]. J. Water Process Eng., 2022,46102547. doi: 10.1016/j.jwpe.2021.102547
7. [7]
  Isik M, Terlemezoglu M, Gasanly N, Parlak M. Structural, morphological and temperature-tuned bandgap characteristics of CuS nano-flake thin films[J]. Physica E, 2022,144115407. doi: 10.1016/j.physe.2022.115407
8. [8]
  Zhang F, Zhuang H Q, Zhang W, Yin J, Cao F H, Pan Y X. Noble-metal-free CuS/CdS photocatalyst for efficient visible-light-driven photocatalytic H₂ production from water[J]. Catal. Today, 2019,330:203-208. doi: 10.1016/j.cattod.2018.03.060
9. [9]
  HOU L M, QING H, JI Q H. Research progress on catalysts, principles and mechanisms of Fenton-like reactions[J]. Environmental Chemistry, 2022,41(6):1843-1855.
10. [10]
  Lu L, Shen Y F, Chen X H, Qian L H, Lu K. Ultrahigh strength and high electrical conductivity in copper[J]. Science, 2004,304(5669):422-426. doi: 10.1126/science.1092905
11. [11]
  Liu M C, Jing D W, Zhou Z H, Guo L J. Twin-induced one-dimensional homojunctions yield high quantum efficiency for solar hydrogen generation[J]. Nat. Commun., 2013,42278. doi: 10.1038/ncomms3278
12. [12]
  Sun S D, Song X P, Kong C C, Liang S H, Ding B J, Yang Z M. Unique polyhedral 26-facet CuS hollow architectures decorated with nanotwinned, mesostructural and single crystalline shells[J]. CrystEngComm, 2011,13(20):6200-6205. doi: 10.1039/c1ce05563a
13. [13]
  Xu J, Teng F, Xu C Y, Yang Y, Yang L M, Kan Y D. Unique anatase TiO₂ twinning crystals formed by high-energy {001} facets and the improved photocatalytic activity[J]. J. Phys. Chem. C, 2015,119(23):13011-13020. doi: 10.1021/acs.jpcc.5b01993
14. [14]
  Liu M C, Wang L Z, Lu G Q, Yao X D, Guo L J. Twins in Cd_1-xZn_xS solid solution: Highly efficient photocatalyst for hydrogen generation from water[J]. Energy Environ. Sci., 2011,4:1372-1378. doi: 10.1039/c0ee00604a
15. [15]
  Sun S D, Zhang X C, Cui J, Yang Q, Liang S H. Twin engineering of photocatalysts: A minireview[J]. Catal. Sci. Technol., 2020,10(13):4164-4178. doi: 10.1039/D0CY00917B
16. [16]
  Fang Z M, Liu Y B, Qi J J, Xu Z F, Qi T Y, Wang L D. Establishing a high-speed electron transfer channel via CuS/MIL-Fe heterojunction catalyst for photo-Fenton degradation of acetaminophen[J]. Appl. Catal. B-Environ., 2023,320121979. doi: 10.1016/j.apcatb.2022.121979
17. [17]
  Bott R C, Bowmaker G A, Davis C A, Hope G A, Jones B E. Crystal structure of[Cu₄(tu)₇](SO₄)₂]·H₂O and vibrational spectroscopic studies of some copper(Ⅰ) thiourea complexes[J]. Inorg. Chem., 1998,37(4):651-657. doi: 10.1021/ic970910q
18. [18]
  Adhikari S, Sarkar D, Madras G. Hierarchical design of CuS architectures for visible light photocatalysis of 4-chlorophenol[J]. ACS Omega, 2017,2(7):4009-4021. doi: 10.1021/acsomega.7b00669
19. [19]
  Qi H, Huang J F, Cao L Y, Wu J P, Wang D Q. One-dimensional CuS microstructures prepared by a PVP-assisted microwave hydrothermal method[J]. Ceram. Int., 2012,38(3):2195-2200. doi: 10.1016/j.ceramint.2011.10.066
20. [20]
  Wang Y H, Huo Q H, Shi L, Feng G, Wang J C, Han L N, Chang L P. Adsorption of mercury species on selected CuS surfaces and the effects of HCl[J]. Chem. Eng. J., 2020,393124773. doi: 10.1016/j.cej.2020.124773
21. [21]
  Chu L M, Zhou B B, Mu H C, Sun Y Z, Ping X. Mild hydrothermal synthesis of hexagonal CuS nanoplates[J]. J. Cryst. Growth, 2008,310(24):5437-5440. doi: 10.1016/j.jcrysgro.2008.09.159
22. [22]
  Yang Z G, Wu Z G, Liu J, Liu Y X, Gao S Y, Wang J A, Xiao Y, Zhong Y J, Zhong B H, Guo X D. Platelet-like CuS impregnated with twin crystal structures for high performance sodium-ion storage[J]. J. Mater. Chem. A, 2020,8(16):8049-8057. doi: 10.1039/D0TA00763C
23. [23]
  Chung C Y, Hsu C H, Lu C H. Preparation and mechanism of nest-like YBO₃: Tb³⁺ phosphors synthesized via the microemulsion-mediated hydrothermal process[J]. J. Am. Ceram. Soc., 2011,94(9):2884-2889. doi: 10.1111/j.1551-2916.2011.04466.x
24. [24]
  Dilena E, Dorfs D, George C, Miszta K, Povia M, Genovese A, Casu A, Prato M, Manna L. Colloidal Cu_2-x(S_ySe_1-y) alloy nanocrystals with controllable crystal phase: Synthesis, plasmonic properties, cation exchange and electrochemical lithiation[J]. J. Mater. Chem., 2012,22(26):13023-13031. doi: 10.1039/c2jm30788j
25. [25]
  Lie S Q, Wang D M, Gao M X, Huang C Z. Controllable copper deficiency in Cu_2-xSe nanocrystals with tunable localized surface plasmon resonance and enhanced chemiluminescence[J]. Nanoscale, 2014,6:10289-10296. doi: 10.1039/C4NR02294G
1. [1]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
2. [2]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
3. [3]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
4. [4]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
5. [5]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
6. [6]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
7. [7]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
8. [8]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
9. [9]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
10. [10]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
11. [11]
  Xin Lv , Hongxing Zhang , Kaibo Duan , Wenhui Dai , Zhihui Wen , Wei Guo , Junsheng Hao . Lighting the Way Against Cancer: Photodynamic Therapy. University Chemistry, 2024, 39(5): 70-79. doi: 10.3866/PKU.DXHX202309090
12. [12]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
13. [13]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
14. [14]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
15. [15]
  Yuhang Jiang , Weijie Liu , Jiaqi Cai , Jiayue Chen , Yanping Ren , Pingping Wu , Liulin Yang . A Journey into the Science and Art of Sugar: “Dispersion of Light and Optical Rotation of Matter” Science Popularization Experiment. University Chemistry, 2024, 39(9): 288-294. doi: 10.12461/PKU.DXHX202401054
16. [16]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
17. [17]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
18. [18]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
19. [19]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
20. [20]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(448)
HTML views(73)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142