Citation: Shuang-Yan QIU, Jun GUO, Dan ZHANG, Lin LU, Yi-Ju ZHANG, Tai-Wen ZHANG. POMOF based on H₃PW₁₂O₄₀·xH₂O and 3, 5-diamino-1, 2, 4-triazole: Synthesis, characterization, and catalytic oxidation performance for iodine ion[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2113-2120. doi: 10.11862/CJIC.2023.168 shu

POMOF based on H₃PW₁₂O₄₀·xH₂O and 3, 5-diamino-1, 2, 4-triazole: Synthesis, characterization, and catalytic oxidation performance for iodine ion

Shuang-Yan QIU ¹ ,
Jun GUO ^{1, 2,,} ,
Dan ZHANG ² ,
Lin LU ¹ ,
Yi-Ju ZHANG ¹ ,
Tai-Wen ZHANG ¹

1.
School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, China
2.
State Key Laboratory for Efficient Utilization of Medium and Low Grade Phosphate Rock and Its Associated Resources, Wengfu(Group) Co., Ltd., Guiyang 550014, China

Corresponding author: Jun GUO, justin_gixt@163.com
Received Date: 6 April 2023
Revised Date: 3 August 2023

Figures(8)

A novel and rare case of Keggin-type polyoxometalate-based metal-organic framework compound was synthesized by solvothermal method, namely[Cu₄(3, 5-datrz)₄] [PW₉^ⅥW₃^ⅤO₃₉]·H₂O (1) (3, 5-datrz=3, 5-diamino-1, 2, 4-triazole). Compound 1 was characterized by single-crystal X-ray diffraction, Fourier transform infrared spectroscopy, Thermogravimetric analysis, powder X-ray diffraction, and elemental analysis. The single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the monoclinic system with space group C2/c. The asymmetric unit contains two Cu⁺ ions, two 3, 5-datrz ligands, one-half of Keggin-type phosphotungstic acid anions, and one water molecule. Except for lattice water, the components are linked by covalent bonding to form Keggin-type polyoxometa-late-based metal-organic framework compounds. Compound 1 was used as a heterogeneous catalyst to catalyze the oxidation of iodine ions by H₂O₂ at a temperature of 55℃, and the study showed that the variation of iodine generation by compound 1 was 6.11×10^-7 mol·L^-1·s^-1, and the conversion rate could still reach as high as 99.6% when it was reused six times.
- polyoxometalates,
- metal-organic framework,
- crystal structure,
- catalytic performance
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POMOF based on H3PW12O40·xH2O and 3, 5-diamino-1, 2, 4-triazole: Synthesis, characterization, and catalytic oxidation performance for iodine ion

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通讯作者: 陈斌, bchen63@163.com

POMOF based on H₃PW₁₂O₄₀·xH₂O and 3, 5-diamino-1, 2, 4-triazole: Synthesis, characterization, and catalytic oxidation performance for iodine ion