Citation: Yan XU, Su-Zhi LI, Xin-Xing LI. Synthesis, structures, and luminescent properties of a series of lanthanide carboxylate-phosphonates[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1950-1958. doi: 10.11862/CJIC.2023.167 shu

Synthesis, structures, and luminescent properties of a series of lanthanide carboxylate-phosphonates

Department of Materials Engineering, Institute of Information Engineering, Suqian University, Suqian, Jiangsu 223800, China

Corresponding author: Yan XU, xuyan0511@126.com
Received Date: 13 May 2023
Revised Date: 16 June 2023

Figures(6)

Three lanthanide carboxylate-phosphonates based on lanthanide nitrate hexahydrate and (5-carboxynaph-thalen-1-yl)phosphonic acid (5-pncH₃) formulated as [Pr(5-pnc)(H₂O)]·2H₂O (1), [Sm(5-pnc)(H₂O)]·H₂O (2), and [Eu(5-pnc)(H₂O)]·H₂O (3) has been obtained as single phases under solvothermal conditions. Complexes 1-3 were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, IR spectra, thermo-gravimetric analysis, and fluorescence spectra. Crystal structures reveal that each lanthanide ion is seven-coordinated by six O atoms from five phosphonate ligands and one O atom from one water molecule. The building blocks [LnO₇] of complexes 1-3 are linked into a 1D double metal chain structure by the O—C—O, O—P—O, or —O— units. The 1D double metal chain is fused into a 3D open-framework structure by 5-pnc^3-. Complex 3 exhibited very strong characteristic emission bands for the Eu (Ⅲ) ion in the visible region under 330 nm excitation. Complexes 1 and 2 displayed very broad ligand -centered emission bands in the blue light region.
- complex,
- carboxylate-phosphonate,
- crystal structure,
- luminescent property
1. [1]
  O'Keeffe M, Yaghi O M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets[J]. Chem. Rev., 2012,112:675-702. doi: 10.1021/cr200205j
2. [2]
  Furukawa H, Cordova K E, O'Keeffe M, Yaghi O M. The chemistry and applications of metal -organic frameworks[J]. Science, 2013,3411230444. doi: 10.1126/science.1230444
3. [3]
  Li J R, Sculley J, Zhou H C. Metal -organic frameworks for separations[J]. Chem. Rev., 2012,112:869-932. doi: 10.1021/cr200190s
4. [4]
  Zhao J P, Xu J, Han S D, Wang Q L, Bu X H. A Niccolite structural multiferroic metal -organic framework possessing four different types of bistability in response to dielectric and magnetic modulation[J]. Adv. Mater., 2017,291606966. doi: 10.1002/adma.201606966
5. [5]
  JU Z F, YUAN D Q. Initial theoretical evaluation of pore structure for metal-organic frameworks[J]. Chinese J. Inorg. Chem., 2013,29(8):1633-1638.
6. [6]
  Li A L, Gao Q, Xu J, Bu X H. Proton-conductive metalorganic frameworks: Recent advances and perspectives[J]. Coord. Chem. Rev., 2017,344:54-82. doi: 10.1016/j.ccr.2017.03.027
7. [7]
  Qiu X, Zhong X, Bai C H, Li Y W. Encapsulation of a metal-organic polyhedral in the pores of a metal -organic framework[J]. J. Am. Chem. Soc., 2016,138(4):1138-1141. doi: 10.1021/jacs.5b12189
8. [8]
  Rojas S, Rodríguez-Diéguez A, Horcajada P. Metal -organic frameworks in agriculture[J]. ACS Appl. Mater. Interfaces, 2022,14(15):16983-17007. doi: 10.1021/acsami.2c00615
9. [9]
  Thorarinsdottir A E, Harris T D. Metal -organic framework magnets[J]. Chem. Rev., 2020,120(16):8716-8789. doi: 10.1021/acs.chemrev.9b00666
10. [10]
  Zhao X, Wang Y X, Li D S, Bu X H, Feng P Y. Metal-organic frameworks for separation[J]. Adv. Mater., 2018,301705189. doi: 10.1002/adma.201705189
11. [11]
  Li R J, Li M, Zhou X P, Li D, O'Keeffe M. A highly stable MOF with a rod SBU and a tetracarboxylate linker: Unusual topology and CO₂adsorption behaviour under ambient conditions[J]. Chem. Commun., 2014,50:4047-4049. doi: 10.1039/C3CC49684H
12. [12]
  Wang Z, Li X Y, Liu L W, Yu S Q, Feng Z Y, Tung C H, Sun D. Beyond clusters: Supramolecular networks self-assembled from nano-sized silver clusters and inorganic anions[J]. Chem. -Eur. J., 2016,22:6830-6836. doi: 10.1002/chem.201504728
13. [13]
  Lusi M, Fechine P B A, Chen K J, Perry J J, Zaworotko M J. A rare cationic building block that generates a new type of polyhedral network with"cross-linked"topology[J]. Chem. Commun., 2016,52:4160-4162. doi: 10.1039/C5CC10203K
14. [14]
  Ahmed A, McHugh D, Papatriantafyllopoulou C. Synthesis and biomedical applications of highly porous metal -organic frameworks[J]. Molecules, 2022,27:6585-6595. doi: 10.3390/molecules27196585
15. [15]
  Wu G D, Huang J H, Zang Y, He J, Xu G. Porous field-effect transistors based on a semiconductive metal -organic framework[J]. J. Am. Chem. Soc., 2017,139(4):1360-1363. doi: 10.1021/jacs.6b08511
16. [16]
  Shu Y, Ye Q Y, Dai T, Xu Q, Hu X Y. Encapsulation of luminescent guests to construct luminescent metal-organic frameworks for chemical sensing[J]. ACS Sens., 2021,6(3):641-658. doi: 10.1021/acssensors.0c02562
17. [17]
  Guo B B, Yin J C, Li N, Fu Z X, Han X, Xu J, Bu X H. Recent progress in luminous particle -encapsulated host -guest metal -organic frameworks for optical applications[J]. Adv. Opt. Mater., 2021,92100283. doi: 10.1002/adom.202100283
18. [18]
  Xu D D, Dong W W, Li M K, Han H M, Zhao J, Li D S, Zhang Q H. Encapsulating organic dyes in metal -organic frameworks for color -tunable and high -efficiency white-light-emitting properties[J]. Inorg. Chem., 2022,61(51):21107-21114. doi: 10.1021/acs.inorgchem.2c03736
19. [19]
  Tao X L, Pan M C, Yang X, Yuan Y, Zhuo Y. CDs assembled metal-organic framework: Exogenous coreactant -free biosensing platform with pore confinement -enhanced electrochemiluminescence[J]. Chin. Chem. Lett., 2022,33(11):4803-4807. doi: 10.1016/j.cclet.2022.01.010
20. [20]
  Firmino A D G, Figueira F, Tome J P C, Paz F A A, Rocha J. Metal-organic frameworks assembled from tetraphosphonic ligands and lanthanides[J]. Coord. Chem. Rev., 2018,355:133-149. doi: 10.1016/j.ccr.2017.08.001
21. [21]
  Jia J G, Zheng L M. Metal -organic nanotubes: Designs, structures and functions[J]. Coord. Chem. Rev., 2020,403213083. doi: 10.1016/j.ccr.2019.213083
22. [22]
  Weng G G, Zheng L M. Chiral metal phosphonates: Assembly, structures and functions[J]. Sci. China Chem., 2020,63(5):619-636. doi: 10.1007/s11426-020-9707-4
23. [23]
  Liu B, Liu J C, Shen Y, Feng J S, Bao S S, Zheng L M. Polymorphic layered copper phosphonates: Exfoliation and proton conductivity studies[J]. Dalton Trans., 2019,48:6539-6545. doi: 10.1039/C9DT00970A
24. [24]
  Huang J, Ding H M, Xu Y, Zeng D, Zhu H, Zang D M, Bao S S, Ma Y Q, Zheng L M. Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination compounds[J]. Nat. Commun., 2017,8:2131-2142. doi: 10.1038/s41467-017-02260-2
25. [25]
  Huang X D, Wen G H, Bao S S, Jia J G, Zheng L M. Thermo -and light -triggered reversible interconversion of dysprosium -anthracene complexes and their responsive optical, magnetic and dielectric properties[J]. Chem. Sci., 2021,12:929-937. doi: 10.1039/D0SC04851H
26. [26]
  Wen G H, Chen X M, Xu K, Xu X J, Bao S S, Zheng L M. Uranyl phosphonates: Crystalline materials and nanosheets for temperature sensing[J]. Dalton Tran., 2021,50:17129-17139. doi: 10.1039/D1DT02977K
27. [27]
  Zeng D, Ren M, Bao S S, Cai Z S, Xu C, Zheng L M. Polymorphic lanthanide phosphonates showing distinct magnetic behavior[J]. Inorg. Chem., 2016,55(11):5297-5304. doi: 10.1021/acs.inorgchem.6b00280
28. [28]
  Li G M, Xu F, Han S D, Pan J, Wang G M. Hybrid photochromic lanthanide phosphonate with multiple photoresponsive functionalities[J]. Inorg. Chem., 2022,61(21):8379-8385. doi: 10.1021/acs.inorgchem.2c01217
29. [29]
  Fu R B, Hua S G, Wu X T. Rapid and sensitive detection of nitroaro-matic explosives by using new 3D lanthanide phosphonates[J]. J. Mater. Chem. A, 2017,5:1952-1956. doi: 10.1039/C6TA10152F
30. [30]
  Tang S F, Song J L, Li X L, Mao J G. Luminescent lanthanide(Ⅲ) carboxylate -phosphonates with helical tunnels[J]. Cryst. Growth Des., 2006,6(10):2322-2326. doi: 10.1021/cg060248l
31. [31]
  Zhou T H, Yi F Y, Li P X, Mao J G. Synthesis, crystal structures, and luminescent properties of two series of new lanthanide(Ⅲ) amino-carboxylate-phosphonates[J]. Inorg. Chem., 2010,49(3):905-915. doi: 10.1021/ic901621x
32. [32]
  Tang S F, Song J L, Mao J G. Syntheses, crystal structures, and characterizations of a series of new layered lanthanide carboxylate-phos-phonates[J]. Eur. J. Inorg. Chem., 2006:2011-2019.
33. [33]
  Ayi A A, Kinnibrugh T L, Clearfield A. Hydrothermal synthesis and structural characterization of ammonium ion-templated lanthanide(Ⅲ) carboxylate-phosphonates[J]. Front. Chem., 2014,2:1-8.
34. [34]
  Liu B, Xu Y, Bao S S, Huang X D, Liu M, Zheng L M. Enantioen-riched cobalt phosphonate containing Δ -type chains and showing slow magnetization relaxation[J]. Inorg. Chem., 2016,55:9521-9523. doi: 10.1021/acs.inorgchem.6b01854
35. [35]
  Eliseevaa S V, Bünzli J C. Lanthanide luminescence for functional materials and bio-sciences[J]. Chem. Soc. Rev., 2010,39:189-227. doi: 10.1039/B905604C
36. [36]
  Kariaka N S, Trush V A, Dyakonenko V V, Shishkina S V, Smola S S, Rusakova N V, Sliva T Y, Gawryszewska P, Carneiro Neto A N, Malta O L, Amirkhanov V M. New luminescent lanthanide tetrakis-complexes NEt₄[LnL₄] based on dimethyl-N-benzoylamidophos-phate[J]. ChemPhysChem, 2022,23e202200129. doi: 10.1002/cphc.202200129
1. [1]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
2. [2]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
3. [3]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
4. [4]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
5. [5]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
6. [6]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
7. [7]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
8. [8]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
9. [9]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
10. [10]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
11. [11]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
12. [12]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
13. [13]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
14. [14]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
15. [15]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
16. [16]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
17. [17]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
18. [18]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(453)
HTML views(76)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142