Citation: Yan XU, Su-Zhi LI, Xin-Xing LI. Synthesis, structures, and luminescent properties of a series of lanthanide carboxylate-phosphonates[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1950-1958. doi: 10.11862/CJIC.2023.167 shu

Synthesis, structures, and luminescent properties of a series of lanthanide carboxylate-phosphonates

Department of Materials Engineering, Institute of Information Engineering, Suqian University, Suqian, Jiangsu 223800, China

Corresponding author: Yan XU, xuyan0511@126.com
Received Date: 13 May 2023
Revised Date: 16 June 2023

Figures(6)

Three lanthanide carboxylate-phosphonates based on lanthanide nitrate hexahydrate and (5-carboxynaph-thalen-1-yl)phosphonic acid (5-pncH₃) formulated as [Pr(5-pnc)(H₂O)]·2H₂O (1), [Sm(5-pnc)(H₂O)]·H₂O (2), and [Eu(5-pnc)(H₂O)]·H₂O (3) has been obtained as single phases under solvothermal conditions. Complexes 1-3 were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, IR spectra, thermo-gravimetric analysis, and fluorescence spectra. Crystal structures reveal that each lanthanide ion is seven-coordinated by six O atoms from five phosphonate ligands and one O atom from one water molecule. The building blocks [LnO₇] of complexes 1-3 are linked into a 1D double metal chain structure by the O—C—O, O—P—O, or —O— units. The 1D double metal chain is fused into a 3D open-framework structure by 5-pnc^3-. Complex 3 exhibited very strong characteristic emission bands for the Eu (Ⅲ) ion in the visible region under 330 nm excitation. Complexes 1 and 2 displayed very broad ligand -centered emission bands in the blue light region.
- complex,
- carboxylate-phosphonate,
- crystal structure,
- luminescent property
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