Citation: Ding FAN, Li-Ming WANG, Feng-Qiang LIU, Li-Hui XU, Hong PAN. Preparation and photocatalytic properties of ZnFe₂O₄/Ag/TiO₂ composite[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1941-1949. doi: 10.11862/CJIC.2023.159 shu

Preparation and photocatalytic properties of ZnFe₂O₄/Ag/TiO₂ composite

Fashion College, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: Li-Ming WANG, wlm@sues.edu.cn
Received Date: 9 March 2023
Revised Date: 12 September 2023

Figures(9)

ZnCaFe₂O₄/Ag/TiO₂ composites were prepared with silver nitrate, tetrabutyl titanate, anhydrous zinc chloride, and ferric chloride hexahydrate as raw materials by sol-gel and solvothermal methods. The samples were characterized and tested by scanning electron microscope, energy spectrum analyzer, X-ray powder diffractometer, X-ray photoelectron spectrometer, vibrating sample magnetometer, ultraviolet visible spectrophotometer. The results showed that ZnCaFe₂O₄/Ag/TiO₂-10 had the best photocatalytic effect, and the degradation rate of dye can reach more than 90% under both ultraviolet and visible light. It had excellent ultraviolet/visible light photocatalytic activity. And after being compounded with ZnCaFe₂O₄, ZnCaFe₂O₄/Ag/TiO₂ had unique magnetism, which can be recycled under the action of external magnetic field, which makes it possible in practical application. Through magnetic separation technology, the photocatalysis performance of ZnCaFe₂O₄/Ag/TiO₂-10 was still excellent after recycling for five times, which showed excellent magnetism and high photocatalytic cycle stability.
- ZnFe₂O₄/Ag/TiO₂ composite,
- doping,
- photocatalytic degradation,
- visible light,
- reactive dye
1. [1]
  Zeghioud H, Khellaf N, Amrane A, Djelal H, Bouhelassa M, Assadi A A, Rtimi S. Combining photocatalytic process and biological treatment for reactive green 12 degradation: Optimization, mineralization, and phytotoxicity with seed germination[J]. Environ. Sci. Pollut. Res. Int., 2021,28(10):12490-12499. doi: 10.1007/s11356-020-11282-1
2. [2]
  Mashkoor F, Nasar A. Magsorbents: Potential candidates in wastewater treatment technology—A review on the removal of methylene blue dye[J]. J. Magn. Magn. Mater., 2020,500166408. doi: 10.1016/j.jmmm.2020.166408
3. [3]
  Natarajan S, Bajaj H C, Tayade R J. Recent advances based on the synergetic effect of adsorption for removal of dyes from waste water using photocatalytic process[J]. J. Environ. Sci., 2018,65:201-222. doi: 10.1016/j.jes.2017.03.011
4. [4]
  Ida S, Yamada K, Matsuka M, Hagiwara H, Ishihara T. Photoelectrochemical hydrogen production from water using p-type and n-type oxide semiconductor electrodes[J]. Electrochim. Acta, 2012,82:397-401. doi: 10.1016/j.electacta.2012.03.174
5. [5]
  Li X J, Jin B, Huang J W, Zhang Q C, Peng R F, Chu S J. Fe₂O₃/ZnO/ZnFe₂O₄ composites for the efficient photocatalytic degradation of organic dyes under visible light[J]. Solid State Sci., 2018,80:6-14. doi: 10.1016/j.solidstatesciences.2018.03.016
6. [6]
  Wang L, Liu Z, Han J, Li R, Huang M. Stepwise synthesis of Au@CdS-CdS nanoflowers and their enhanced photocatalytic properties[J]. Nanoscale Res. Lett., 2019,14(1):1-9. doi: 10.1186/s11671-018-2843-4
7. [7]
  Nundy S, Ghosh A, Mallick T K. Hydrophilic and superhydrophilic self-cleaning coatings by morphologically varying ZnO microstructures for photovoltaic and glazing applications[J]. ACS Omega, 2020,5(2):1033-1039. doi: 10.1021/acsomega.9b02758
8. [8]
  Chen S J, Di Y J, Li H, Wang M Y, Jia B, Xu R, Liu X Y. Efficient photocatalytic dye degradation by flowerlike MoS₂/SrFe₁₂O₁₉ heterojunction under visible light[J]. Appl. Surf. Sci., 2021,559149855. doi: 10.1016/j.apsusc.2021.149855
9. [9]
  Zhang D. Photocatalytic applications of Au-deposited on TiO₂ nanocomposite catalyst in dye degradation via photoreduction[J]. Russ. J. Phys. Chem. A, 2012,86(3):498-503. doi: 10.1134/S0036024412030363
10. [10]
  Nemiwal M, Zhang T C, Kumar D. Recent progress in g-C₃N₄, TiO₂ and ZnO based photocatalysts for dye degradation: Strategies to improve photocatalytic activity[J]. Sci. Total Environ., 2021,767144896. doi: 10.1016/j.scitotenv.2020.144896
11. [11]
  Sun M J, Han X L, Chen S G. Synthesis and photocatalytic activity of nano-cobalt ferrite catalyst for the photo-degradation various dyes under simulated sunlight irradiation[J]. Mat. Sci. Semicon. Proc., 2019,91:367-376. doi: 10.1016/j.mssp.2018.12.005
12. [12]
  Liu N, Zhu Q, Zhang N, Zhang C, Kawazoe N, Chen G P, Negishi N, Yang Y N. Superior disinfection effect of Escherichia coli by hydrothermal synthesized TiO₂-based composite photocatalyst under LED irradiation: Influence of environmental factors and disinfection mechanism[J]. Environ. Pollut., 2019,247:847-856. doi: 10.1016/j.envpol.2019.01.082
13. [13]
  Krylov I B, Lopat'eva E R, Subbotina I R, Nikishin G I, Yu B, Terent'ev A O. Mixed hetero-/homogeneous TiO₂/N-hydroxyimide photocatalysis in visible-light-induced controllable benzylic oxidation by molecular oxygen[J]. Chinese J Catal., 2021,42(10):1700-1711. doi: 10.1016/S1872-2067(21)63831-7
14. [14]
  Ji L J, Zhang Y H, Miao S Y, Gong M D, Liu X. In situ synthesis of carbon doped TiO₂ nanotubes with an enhanced photocatalytic performance under UV and visible light[J]. Carbon, 2017,125:544-550. doi: 10.1016/j.carbon.2017.09.094
15. [15]
  LI P, ZHANG X X, SI Y, LIANG T T, LIU H, QIU L F, DUAN S Q, DUO S W, CHEN Z. Constructing and photocatalytic performance of g-C₃N₄/Ag/TiO₂ composites[J]. Chinese J. Inorg. Chem., 2020,36(3):566-574.
16. [16]
  Karimi-Maleh H, Kumar B G, Rajendran S, Qin J, Vadivel S, Durgalakshmi D, Gracia F, Soto-Moscoso M, Orooji Y, Karimi F. Tuning of metal oxides photocatalytic performance using Ag nanoparticles integration[J]. J. Mol. Liq., 2020,314113588. doi: 10.1016/j.molliq.2020.113588
17. [17]
  Augustine R, Kalarikkal N, Thomas S. A facile and rapid method for the black pepper leaf mediated green synthesis of silver nanoparticles and the antimicrobial study[J]. Appl. Nanosci., 2014,4:809-818. doi: 10.1007/s13204-013-0260-7
18. [18]
  Brown P K, Qureshi A T, Moll A N, Hayes D J, Monroe W T. Silver nanoscale antisense drug delivery system for photoactivated gene silencing[J]. ACS Nano, 2013,7(4):2948-2959. doi: 10.1021/nn304868y
19. [19]
  Choi H, Ko S J, Choi Y, Joo P, Kim T, Lee B R, Jung J W, Choi H J, Cha M, Jeong J R, Hwang I W, Song M H, Kim B S, Kim J Y. Versatile surface plasmon resonance of carbon-dot-supported silver nanoparticles in polymer optoelectronic devices[J]. Nat. Photonics., 2013,7(9):732-738. doi: 10.1038/nphoton.2013.181
20. [20]
  Song Y L, Qi J Y, Tian J Y, Gao S S, Cui F Y. Construction of Ag/g-C₃N₄ photocatalysts with visible-light photocatalytic activity for sulfamethoxazole degradation[J]. Chem. Eng. J., 2018,341:547-555. doi: 10.1016/j.cej.2018.02.063
21. [21]
  Chakhtouna H, Benzeid H, Zari N, Qaiss A E K, Bouhfid R. Recent progress on Ag/TiO₂ photocatalysts: Photocatalytic and bactericidal behaviors[J]. Environ. Sci. Pollut. Res. Int., 2021,28(33):1-29.
22. [22]
  Sun Y W, Lei J S, Wang Y Z, Tang Q, Kang C L. Fabrication of a magnetic ternary ZnFe₂O₄/TiO₂/RGO Z-scheme system with efficient photocatalytic activity and easy recyclability[J]. RSC Adv., 2020,10(29):17293-17301. doi: 10.1039/D0RA01880E
23. [23]
  Cai C, Zhang Z Y, Liu J, Shan N, Zhang H, Dionysiou D D. Visible light-assisted heterogeneous Fenton with ZnFe₂O₄ for the degradation of orange Ⅱ in water[J]. Appl. Catal. B-Environ., 2016,182:456-468. doi: 10.1016/j.apcatb.2015.09.056
24. [24]
  Guo X, Zhu H J, Li Q. Visible-light-driven photocatalytic properties of ZnO/ZnFe₂O₄ core/shell nanocable arrays[J]. Appl. Catal. B-Environ., 2014,160:408-414.
25. [25]
  Liu T Y, Wang C X, Wang W, Yang G J, Lu Z Y, Xu P, Sun X N, Zhang J T. The enhanced properties in photocatalytic wastewater treatment: Sulfanilamide (SAM) photodegradation and Cr⁶⁺ photoreduction on magnetic Ag/ZnFe₂O₄ nanoarchitectures[J]. J. Alloy. Compd., 2021,867159085. doi: 10.1016/j.jallcom.2021.159085
26. [26]
  Yang G X, Yin H B, Liu W H, Yang Y P, Zou Q, Luo L L, Li H P, Huo Y N, Li H X. Synergistic Ag/TiO₂-N photocatalytic system and its enhanced antibacterial activity towards Acinetobacter baumannii[J]. Appl. Catal. B-Environ., 2018,224:175-182. doi: 10.1016/j.apcatb.2017.10.052
27. [27]
  Jbeli A, Hamden Z, Bouattour S, Ferraria A M, Conceição D S, Ferreira L F V, Chehimi M M, do Rego A M B, Rei Vilar M, Boufi S. Chitosan-Ag-TiO₂ films: An effective photocatalyst under visible light[J]. Carbohydr. Polym., 2018,199:31-40. doi: 10.1016/j.carbpol.2018.06.122
28. [28]
  Mady A H, Baynosa M L, Tuma D, Shim J J. Facile microwave-assisted green synthesis of Ag-ZnFe₂O₄@ rGO nanocomposites for efficient removal of organic dyes under UV-and visible-light irradiation[J]. Appl. Catal. B-Environ., 2017,203:416-427. doi: 10.1016/j.apcatb.2016.10.033
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Preparation and photocatalytic properties of ZnFe₂O₄/Ag/TiO₂ composite