Citation: Peng XU, Wei DAI, Wei-Shan SHI, Gang XING, Zhao-Gui WANG, Sha-Sha WANG, Qun LI, Chao-Qun YOU, De-Jun HAO. Preparation of zeolitic imidazolate frameworks-8/modified polyacrylonitrile electrospun nanofibers for efficient removal of malachite green from water[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1959-1968. doi: 10.11862/CJIC.2023.154 shu

Preparation of zeolitic imidazolate frameworks-8/modified polyacrylonitrile electrospun nanofibers for efficient removal of malachite green from water

Peng XU ¹ ,
Wei DAI ¹ ,
Wei-Shan SHI ² ,
Gang XING ² ,
Zhao-Gui WANG ³ ,
Sha-Sha WANG ¹ ,
Qun LI ¹ ,
Chao-Qun YOU ¹ ,
De-Jun HAO ^3,,

1.
College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Jiangsu Aijin Crop Science and Technology Group Co., Ltd., Nanjing 210000, China
3.
College of Forestry, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: De-Jun HAO, djhao@njfu.edu.cn
Received Date: 30 March 2023
Revised Date: 28 June 2023

Figures(9)

A simple in-situ growth method was presented to synthesize zeolitic imidazolate framework-8 (ZIF-8), one of the most common metal-organic frameworks (MOFs) crystals, onto a carboxymethylated polyacrylonitrile electrospun nanofibers (PAN-COOH NFs). The synthesized ZIF-8/PAN-COOH NFs were characterized by field-emission scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), and Fourier-transform infrared (FTIR) spectroscopy. The characterization results confirmed that the ZIF-8 particles were successfully loaded on the surface of the PAN-COOH NFs. The ability of ZIF-8/PAN-COOH NFs to remove malachite green (MG), a model organic dye, from wastewater was evaluated to examine the potential of this novel material as an adsorbent. The adsorption to MG was consistent with the pseudo -second -order kinetic equation, and the adsorption process was expressed by the Langmuir isotherm model. The maximum adsorption capacity for MG was examined as 3 604 mg·g^-1. It is noteworthy that the ZIF-8/PAN-COOH NFs could be easily separated from the dye solution and regenerated through a simple washing process for recycling.
- ZIF-8,
- electrospinning,
- nanofiber,
- polyacrylonitrile,
- adsorption,
- malachite green
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