Citation: Su ZHANG, Qiu-Hong YANG, Qi-Di LI. Dielectric properties of low-temperature sintered NaBi(WO4)2 ceramics[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1923-1930. doi: 10.11862/CJIC.2023.149 shu

Dielectric properties of low-temperature sintered NaBi(WO4)2 ceramics

  • Corresponding author: Qiu-Hong YANG, yangqiuhong@shu.edu.cn
  • Received Date: 3 March 2023
    Revised Date: 22 August 2023

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  • A novel NaBi(WO4)2 (NBW) ceramic prepared by solid-phase synthesis, the phase structure, morphology, sintering properties, and microwave dielectric properties of NBW ceramic were investigated. NBW is a chemical properties stable compound and was used without special packaging. The NBW ceramic can be sintered densification at temperatures from 625 to 800 ℃ for 1-4 h. The X-ray diffraction showed that the NBW ceramic sintered at temperatures from 625 to 800 ℃ for 2 h is a tetragonal crystal scheelite structure single-phase ceramic. With the increase of sintered temperature, the permittivity and quality factor (Qf value) first increased then decreased, while the temperature coefficient of resonant frequency gradually decreased. The dielectric properties of NBW ceramic sintered at 650 ℃ for 2 h were permittivity of 14.36, Qf of 16 503 GHz, and temperature coefficient of resonant frequency of -1.055 ×10-5 ℃-1. When NBW was co-fired with Ag, it reacted with Ag to form Ag2W2O7, but NBW had chemical compatibility with Au and Al.
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