Citation: Yan-Rui LEI, Hai-Lang ZHU, Jie HUANG, Ren-He ZHOU, Tao LIU. Structure and magnetism of cyanide-bridged [FeCo]-based chain-like complexes[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1969-1979. doi: 10.11862/CJIC.2023.147 shu

Structure and magnetism of cyanide-bridged [FeCo]-based chain-like complexes

State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Tao LIU, liutao@dlut.edu.cn
Received Date: 28 March 2023
Revised Date: 5 June 2023

Figures(7)

We report two cyanide-bridged mixed-valence chain-like coordination polymers by the self-assembly reaction of tricyanoferrate(Ⅲ) building blocks (Bu₄N)[Fe(PzTp)(CN)₃] (PzTp=tetrakis(pyrazolyl)borate) and Co(Ⅱ) ions in the presence of monodentate ligand (E)-1-styryl-1H-imidazole (Bzi). X-ray diffraction analysis indicated that complex [Fe(PzTp)(CN)₃]₂[Co(Bzi)₄]₂(ClO₄)₂·H₂O (1) adopts a square-wave type chain structure, while complex [Fe(PzTp) (CN)₃]₂[Co(Bzi)₂]·CH₃OH (2) forms double zigzag chains that contain methanol solvent molecules. Magnetic studies revealed that complex 1 displayed a thermally induced spin transition at around 360 K, while complex 2 exhibited a solvent-induced two-step spin transition at approximately 200 K. Variable-temperature infrared spectra confirmed the thermally induced intermetallic charge transfer behavior. Additionally, photomagnetic experiments revealed that complex 1 displayed reversible light-induced charge transfer behavior when alternately irradiated with 808 and 532 nm light, while the charge transfer behavior of complex 2 could be induced by 808 nm irradiation. The magneto-structural relationship analysis indicates that the different hydrogen bonding interactions and local coordination environments of the cobalt sites in complexes 1 and 2 are the main factors contributing to their distinct charge transfer and light-responsive properties.
- intermetallic charge transfer,
- tricyanometallate,
- cyanide-bridged,
- coordination polymer
1. [1]
  Sato O, Iyoda T, Fujishima A, Hashimoto K. Photoinduced magnetization of a cobalt-iron cyanide[J]. Science, 1996,272(5262):704-705. doi: 10.1126/science.272.5262.704
2. [2]
  Cambi L, Szegö L. Über die magnetische Susceptibilität der komplexen Verbindungen[J]. Berichte der deutschen chemischen Gesellschaft (Reihe A und B), 1931,64(10):2591-2598. doi: 10.1002/cber.19310641002
3. [3]
  Wang M, Li Z Y, Ishikawa R, Yamashita M. Spin crossover and valence tautomerism conductors[J]. Coord. Chem. Rev., 2021,435213819. doi: 10.1016/j.ccr.2021.213819
4. [4]
  Wang J H, Li Z Y, Yamashita M, Bu X H. Recent progress on cyanobridged transition-metal-based single-molecule magnets and singlechain magnets[J]. Coord. Chem. Rev., 2021,428213617. doi: 10.1016/j.ccr.2020.213617
5. [5]
  Hu J X, Luo L, Lv X J, Liu L, Liu Q, Yang Y K, Duan C Y, Luo Y, Liu T. Light-induced bidirectional metal-to-metal charge transfer in a linear Fe₂Co complex[J]. Angew. Chem. Int. Ed., 2017,56(26):7663-7668. doi: 10.1002/anie.201703768
6. [6]
  Phonsri W, Harding P, Liu L J, Telfer S G, Murray K S, Moubaraki B, Ross T M, Jameson G N L, Harding D J. Solvent modified spin crossover in an iron(Ⅲ) complex: Phase changes and an exceptionally wide hysteresis[J]. Chem. Sci., 2017,8(5):3949-3959. doi: 10.1039/C6SC05317C
7. [7]
  Chen X Y, Shi H Y, Huang R B, Zheng L S, Tao J. Temperature, light and solvent-induced spin transition in a 3D 2-fold interpenetrated PtStype porous coordination polymer[J]. Chem. Commun., 2013,49(93):10977-10979. doi: 10.1039/c3cc45691a
8. [8]
  Nihei M, Sekine Y, Suganami N, Nakazawa K, Nakao A, Nakao H, Murakami Y, Oshio H. Controlled intramolecular electron transfers in cyanide- bridged molecular squares by chemical modifications and external stimuli[J]. J. Am. Chem. Soc., 2011,133(10):3592-3600. doi: 10.1021/ja109721w
9. [9]
  Lescouëzec R, Toma L M, Vaissermann J, Verdaguer M, Delgado F S, Ruiz- Pérez C, Lloret F, Julve M. Design of single chain magnets through cyanide- bearing six- coordinate complexes[J]. Coord. Chem. Rev., 2005,249(23):2691-2729. doi: 10.1016/j.ccr.2005.09.017
10. [10]
  Molnár G, Rat S, Salmon L, Nicolazzi W, Bousseksou A. Spin crossover nanomaterials: From fundamental concepts to devices[J]. Adv. Mater., 2018,30(5)1703862. doi: 10.1002/adma.201703862
11. [11]
  Zlobin I S, Nelyubina Y V, Novikov V V. Molecular compounds in spintronic devices: An intricate marriage of chemistry and physics[J]. Inorg. Chem., 2022,61(33):12919-12930. doi: 10.1021/acs.inorgchem.2c00859
12. [12]
  Kipgen L, Bernien M, Tuczek F, Kuch W. Spin-crossover molecules on surfaces: From isolated molecules to ultrathin films[J]. Adv. Mater., 2021,33(24)2008141. doi: 10.1002/adma.202008141
13. [13]
  HE Y L, MENG Y S, SUN H Y, JIANG W J, JIAO C Q, LIU T. Synthesis and magnetism of cyano-bridged Fe₂Ni double-zigzag chains[J]. Chinese J. Inorg. Chem., 2019,35(9):1570-1578.
14. [14]
  Jiao C Q, Meng Y S, Yu Y, Jiang W J, Wen W, Oshio H, Luo Y, Duan C Y, Liu T. Effect of intermolecular interactions on metal-to-metal charge transfer: A combined experimental and theoretical investigation[J]. Angew. Chem. Int. Ed., 2019,58(47):17009-17015. doi: 10.1002/anie.201909495
15. [15]
  WANG J L, ZHU H L, LIU Q, DUAN C Y, LIU T. The properties of light- induced single- chain magnets and its research progress[J]. Scientia Sinica Chimica, 2017,47(6):724-733.
16. [16]
  Wei R J, Nakahara R, Cameron J M, Newton G N, Shiga T, Sagayama H, Kumai R, Murakami Y, Oshio H. Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex[J]. Dalton Trans., 2016,45(43):17104-17107. doi: 10.1039/C6DT03416K
17. [17]
  WU J Q, MENG Y S, ZHU H L, JIAO C Q, LIU T. Synthesis and magnetism of cyano-bridged Fe₂Ni₂ single-molecule magnets[J]. Chinese J. Inorg. Chem., 2020,36(12):2331-2339.
18. [18]
  Sato O. Optically switchable molecular solids: Photoinduced spin- crossover, photochromism, and photoinduced magnetization[J]. Acc. Chem. Res., 2003,36(9):692-700. doi: 10.1021/ar020242z
19. [19]
  Aguilà D, Prado Y, Koumousi E S, Mathonière C, Clérac R. Switchable Fe/Co Prussian blue networks and molecular analogues[J]. Chem. Soc. Rev., 2016,45(1):203-224. doi: 10.1039/C5CS00321K
20. [20]
  Verdaguer M, Bleuzen A, Marvaud V, Vaissermann J, Seuleiman M, Desplanches C, Scuiller A, Train C, Garde R, Gelly G, Lomenech C, Rosenman I, Veillet P, Cartier C, Villain F. Molecules to build solids: High TC molecule-based magnets by design and recent revival of cyano complexes chemistry[J]. Coord. Chem. Rev., 1999,190-192:1023-1047. doi: 10.1016/S0010-8545(99)00156-3
21. [21]
  Yang Y K, Jiao C Q, Meng Y S, Yao N T, Jiang W J, Liu T. Substituent effect on metal- to- metal charge transfer behavior of cyanide- bridged {Fe₂Co₂} square[J]. Inorg. Chem. Commun., 2021,130108712. doi: 10.1016/j.inoche.2021.108712
22. [22]
  Kamilya S, Ghosh S, Li Y, Dechambenoit P, Rouzières M, Lescouëzec R, Mehta S, Mondal A. Two-step thermoinduced metal-to-metal electron transfer and ON/OFF photoswitching in a molecular [Fe₂Co₂] square complex[J]. Inorg. Chem., 2020,59(17):11879-11888. doi: 10.1021/acs.inorgchem.0c02053
23. [23]
  Jiang W J, Jiao C Q, Meng Y S, Zhao L, Liu Q, Liu T. Switching single chain magnet behavior via photoinduced bidirectional metal- to-metal charge transfer[J]. Chem. Sci., 2018,9(3):617-622. doi: 10.1039/C7SC03401F
24. [24]
  Avila Y, Acevedo-Peña P, Reguera L, Reguera E. Recent progress in transition metal hexacyanometallates: From structure to properties and functionality[J]. Coord. Chem. Rev., 2022,453214274. doi: 10.1016/j.ccr.2021.214274
25. [25]
  Gütlich P, Garcia Y, Woike T. Photoswitchable coordination compounds[J]. Coord. Chem. Rev., 2001,219-221:839-879. doi: 10.1016/S0010-8545(01)00381-2
26. [26]
  Hoshino N, Iijima F, Newton G N, Yoshida N, Shiga T, Nojiri H, Nakao A, Kumai R, Murakami Y, Oshio H. Three-way switching in a cyanide-bridged [CoFe] chain[J]. Nat. Chem., 2012,4(11):921-926. doi: 10.1038/nchem.1455
27. [27]
  Meng L Y, Deng Y F, Holmes S M, Zhang Y Z. Thermo- and photoinduced electron transfer in a series of [Fe₂Co₂] capsules[J]. Dalton Trans., 2023,52(6):1616-1622. doi: 10.1039/D2DT03328C
28. [28]
  Liu Q, Hu J X, Meng Y S, Jiang W J, Wang J L, Wen W, Wu Q, Zhu H L, Zhao L, Liu T. Asymmetric coordination toward a photoinduced single- chain magnet showing high coercivity values[J]. Angew. Chem. Int. Ed., 2021,60(19):10537-10541. doi: 10.1002/anie.202017249
29. [29]
  Liu Q, Yao N T, Sun H Y, Hu J X, Meng Y S, Liu T. Light actuated single- chain magnet with magnetic coercivity[J]. Inorg. Chem. Front., 2022,9(19):5093-5104. doi: 10.1039/D2QI01371A
30. [30]
  Dobbelaar E, Jakobsen V B, Trzop E, Lee M, Chikara S, Ding X, Müller Bunz H, Esien K, Felton S, Carpenter M A, Collet E, Morgan G G, Zapf V S. Thermal and magnetic field switching in a two-step hysteretic Mn^Ⅲ spin crossover compound coupled to symmetry breakings[J]. Angew. Chem. Int. Ed., 2022,61e202114021. doi: 10.1002/anie.202114021
31. [31]
  Huang X D, Wen G H, Bao S S, Jia J G, Zheng L M. Thermo- and light-triggered reversible interconversion of dysprosium-anthracene complexes and their responsive optical, magnetic and dielectric properties[J]. Chem. Sci., 2021,12(3):929-937. doi: 10.1039/D0SC04851H
32. [32]
  JIAO C Q, JIANG W J, WEN W, ZREN Y, WANG J L. LIU T, HE C. Tuning assembly and magnetic interactions of cyano-bridged Fe(Ⅲ)- Mn(Ⅱ) bimetallic chains[J]. Chinese J. Inorg. Chem., 2016,32(9):1637-1646.
33. [33]
  Habarakada U, Boonprab T, Harding P, Murray K S, Phonsri W, Neville S M, Ahmed M, Harding D J. Solvent effects on the structural and magnetic properties of Fe^Ⅲ spin- crossover complexes[J]. Cryst Growth Des., 2022,22(8):4895-4905. doi: 10.1021/acs.cgd.2c00390
34. [34]
  Díaz- Torres R, Boonprab T, Gómez- Coca S, Ruiz E, Chastanet G, Harding P, Harding D J. Structural and theoretical insights into solvent effects in an iron(Ⅲ) SCO complex[J]. Inorg. Chem. Front., 2022,9(20):5317-5326. doi: 10.1039/D2QI01159J
35. [35]
  Zhao X H, Shao D, Chen J T, Gan D X, Yang J, Zhang Y Z. A trinu- clear {Fe₂^ⅢFe^Ⅱ} complex involving both spin and non- spin transitions exhibits three- step and wide thermal hysteresis[J]. Sci. China Chem., 2022,65(3):532-538. doi: 10.1007/s11426-021-1153-0
36. [36]
  Shen G D, Lv X, Qian W X, Bao W L. Cu₂O-catalyzed Ullmann-type reaction of vinyl bromides with imidazole and benzimidazole[J]. Tetrahedron Lett., 2008,49(29/30):4556-4559.
37. [37]
  Gu Z G, Liu W, Yang Q F, Zhou X H, Zuo J L, You X Z. Cyano-bridged Fe^Ⅲ₂Cu^Ⅱ₃ and Fe^Ⅲ₄Ni^Ⅱ₄ complexes: Syntheses, structures, and magnetic properties[J]. Inorg. Chem., 2007,46(8):3236-3244. doi: 10.1021/ic062267q
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