Advanced Search

Citation: Jin-Yang MA, Ya-Nan XU, Yu ZHANG, Hong-Bin DU. Preparation of SiOx-C composite materials with a reinforced concrete-like structure for lithium-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1766-1774. doi: 10.11862/CJIC.2023.144 shu

Preparation of SiOx-C composite materials with a reinforced concrete-like structure for lithium-ion batteries

  • State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

  • Corresponding author: Hong-Bin DU, hbdu@nju.edu.cn
  • Received Date: 20 April 2023
    Revised Date: 8 July 2023

Figures(6)

  • This work reports a simple method to prepare a Si-O-C anode material with a reinforced concrete-like structure, in which carbon nanotubes (CNTs) were embedded and acted like steel bars to provide stress support, and the silicon atoms were wrapped with atomically dispersed carbon and oxygen concrete matrix. An outermost carbon layer was plated via chemical vapor deposition to further inhibit the volume change of the material. Thanks to the unique structural design, the prepared CNTs/SiOx-C/C anode showed excellent electrochemical performance with a high-capacity retention rate of 80% after 970 cycles at 0.5 A·g-1.
  • 加载中
    1. [1]

      Li Y Z, Yan K, Lee H W, Lu Z D, Liu N, Cui Y. Growth of conformal graphene cages on micrometre-sized silicon particles as stable battery anodes[J]. Nat. Energy, 2016,1(2)15029. doi: 10.1038/nenergy.2015.29

    2. [2]

      Zhang H, Zong P, Chen M, Jin H, Bai Y, Li S W, Ma F, Xu H, Lian K. In situ synthesis of multilayer carbon matrix decorated with copper particles: enhancing the performance of Si as anode for Li-ion batteries[J]. ACS Nano, 2019,13(3):3054-3062. doi: 10.1021/acsnano.8b08088

    3. [3]

      Yang W, Liu H, Ren Z H, Jian N, Gao M X, Wu Y J, Liu Y F, Pan H G. A novel multielement, multiphase, and B-containing SiOx composite as a stable anode material for Li-ion batteries[J]. Adv. Mater. Interfaces, 2019,6(5)1801631. doi: 10.1002/admi.201801631

    4. [4]

      Shi L R, Pang C L, Chen S L, Wang M H, Wang K X, Tan Z J, Gao P, Ren J G, Huang Y Y, Peng H L, Liu Z F. Vertical graphene gowth on SiO microparticles for stable lithium ion battery anodes[J]. Nano Lett., 2017,17(6):3681-3687. doi: 10.1021/acs.nanolett.7b00906

    5. [5]

      Tang C J, Liu Y N, Xu C, Zhu J X, Wei X J, Zhou L, He L, Yang W, Mai L Q. Ultrafine nickel-nanoparticle-enabled SiO2 hierarchical hollow spheres for high-performance lithium storage[J]. Adv. Funct. Mater., 2018,28(3)1704561. doi: 10.1002/adfm.201704561

    6. [6]

      Zhou N, Wu Y F, Zhou Q, Li Y R, Liu S H, Zhang H B, Zhou Z, Xia M. Enhanced cycling performance and rate capacity of SiO anode material by compositing with monoclinic TiO2(B)[J]. Appl. Surf. Sci., 2019,486:292-302. doi: 10.1016/j.apsusc.2019.05.025

    7. [7]

      Li G, Li J Y, Yue F S, Xu Q, Zuo T T, Yin Y X, Guo Y G. Reducing the volume deformation of high capacity SiOx/G/C anode toward industrial application in high energy density lithium-ion batteries[J]. Nano Energy, 2019,60:485-492. doi: 10.1016/j.nanoen.2019.03.077

    8. [8]

      Yang J P, Wang Y X, Li W, Wang L J, Fan Y C, Jiang W, Luo W, Wang Y, Kong B, Selomulya C, Liu H K, Dou S X, Zhao D Y. Amorphous TiO2 shells: A vital elastic buffering layer on silicon nanoparticles for high-performance and safe lithium storage[J]. Adv. Mater., 2017,29(48)1700523. doi: 10.1002/adma.201700523

    9. [9]

      Ma T Y, Xu H Y, Yu X G, Li H Y, Zhang W G, Cheng X L, Zhu W T, Qiu X P. Lithiation behavior of coaxial hollow nanocables of carbonsilicon composite[J]. ACS Nano, 2019,13(2):2274-2280.

    10. [10]

      Sun L, Su T T, Xu L, Liu M P, Du H B. Two-dimensional ultra-thin SiOx (0<x<2) nanosheets with long-term cycling stability as lithium ion battery anodes[J]. Chem. Commun., 2016,52(23):4341-4344. doi: 10.1039/C6CC00723F

    11. [11]

      Zhou X M, Liu Y, Ren Y, Mu T S, Yin X C, Du C Y, Huo H, Cheng X Q, Zuo P J, Yin G P. Engineering molecular polymerization for template-free SiOx/C hollow spheres as ultrastable anodes in lithiumion batteries[J]. Adv. Funct. Mater., 2021,31(21)2101145. doi: 10.1002/adfm.202101145

    12. [12]

      Chen R X, Zhou Y C, Li X D. Cotton-derived Fe/Fe3C-encapsulated carbon nanotubes for high-performance lithium-sulfur batteries[J]. Nano Lett., 2022,22(3):1217-1224. doi: 10.1021/acs.nanolett.1c04380

    13. [13]

      Zeng Y X, Zhang X Y, Qin R F, Liu X Q, Fang P P, Zheng D Z, Tong Y X, Lu X H. Dendrite-free zinc deposition induced by multi-functional CNT frameworks for stable flexible Zn-ion batteries[J]. Adv. Mater., 2019,31(36)e1903675. doi: 10.1002/adma.201903675

    14. [14]

      Zhang Y P, Wang L L, Xu H, Gao J M, Chen D, Han W. 3D chemical cross-linking structure of black phosphorus@CNTs hybrid as a promising anode material for lithium ion batteries[J]. Adv. Funct. Mater., 2020,30(12)1909372. doi: 10.1002/adfm.201909372

    15. [15]

      Xu Q, Sun J K, Li G, Li J Y, Yin Y X, Guo Y G. Facile synthesis of a SiOx/asphalt membrane for high performance lithium-ion battery anodes[J]. Chem. Commun., 2017,53(89):12080-12083. doi: 10.1039/C7CC05816K

    16. [16]

      Guo X T, Li W T, Geng P B, Zhang Q Y, Pang H, Xu Q. Construction of SiOx/nitrogen-doped carbon superstructures derived from rice husks for boosted lithium storage[J]. J. Colloid Interf. Sci., 2022,606(1):784-792.

    17. [17]

      Chen X C, Kierzek K, Jiang Z W, Chen H M, Tang T, Wojtoniszak M, Kalenczuk R J, Chu P K, Borowiak-Palen E. Synthesis, growth mechanism, and electrochemical properties of hollow mesoporous carbon spheres with controlled diameter[J]. J. Phys. Chem. C, 2011,115(36):17717-17724. doi: 10.1021/jp205257u

    18. [18]

      Pimenta M A, Dresselhaus G, Dresselhaus M S, Cancado L G, Jorio A, Saito R. Studying disorder in graphite-based systems by Raman spectroscopy[J]. Phys. Chem. Chem. Phys., 2007,9(11):1276-1291. doi: 10.1039/B613962K

    19. [19]

      Sasikala S P, Henry L, Yesilbag Tonga G, Huang K, Das R, Giroire B, Marre S, Rotello V M, Penicaud A, Poulin P, Aymonier C. High yield synthesis of aspect ratio controlled graphenic materials from anthracite coal in supercritical fluids[J]. ACS Nano, 2016,10(5):5293-5303. doi: 10.1021/acsnano.6b01298

    20. [20]

      Lim K, Park H, Ha J, Kim Y T, Choi J. Dualcarbon-confined hydrangea-like SiO cluster for high-performance and stable lithium ion batteries[J]. J. Ind. Eng. Chem., 2021,101:397-404. doi: 10.1016/j.jiec.2021.05.043

    21. [21]

      Guo L, He H, Ren Y, Wang C, Li M. Core-shell SiO@F-doped C composites with interspaces and voids as anodes for high-performance lithium-ion batteries[J]. Chem. Eng. J., 2018,335:32-40. doi: 10.1016/j.cej.2017.10.145

    22. [22]

      Kim S J, Kim M C, Han S B, Lee G H, Choe H S, Moon S H, Kwak D H, Hong S, Park K W. 3-D Si/carbon nanofiber as a binder/current collector-free anode for lithium-ion batteries[J]. J. Ind. Eng. Chem., 2017,49:105-111. doi: 10.1016/j.jiec.2017.01.014

    23. [23]

      Jang J Y, Kang I, Choi J K, Jeong H, Yi K W, Hong J Y, Lee M. Molecularly tailored lithium-arene complex enables chemical prelithiation of high-capacity lithium-ion battery anodes[J]. Angew. Chem. Int. Ed., 2020,59(34):14473-14480. doi: 10.1002/anie.202002411

    24. [24]

      Raza A, Jung J Y, Lee C H, Kim B G, Choi J H, Park M S, Lee S M. Swelling-controlled double-layered SiOx/Mg2SiO4/SiOx composite with enhanced initial coulombic efficiency for lithium-ion battery[J]. ACS Appl. Mater. Inter., 2021,13(6):7161-7170. doi: 10.1021/acsami.0c19975

    25. [25]

      Wang C, Wu H, Chen Z, McDowell M T, Cui Y, Bao Z N. Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries[J]. Nat. Chem., 2013,5(12):1042-1048. doi: 10.1038/nchem.1802

    26. [26]

      Tokur M, Jin M Y, Sheldon B W, Akbulut H. Stress bearing mechanism of reduced graphene oxide in silicon-based composite anodes for lithium ion batteries[J]. ACS Appl. Mater. Inter., 2020,12(30):33855-33869. doi: 10.1021/acsami.0c10064

    27. [27]

      Ian B, Ji W. Asymmetric membranes containing micron-size silicon for high performance lithium ion battery anode[J]. Electrochim. Acta, 2016,213:46-54. doi: 10.1016/j.electacta.2016.07.106

    28. [28]

      Shi H B, Shao G Q, Wu B B, Yang Z X, Zhang H G, Lv P P, Zhu Q S. Scalable synthesis of a dual-confined SiO/one-dimensional carbon/amorphous carbon anode based on heterogeneous carbon structure evolution[J]. J. Mater. Chem. A, 2021,9(46):26236-26247. doi: 10.1039/D1TA07821F

    29. [29]

      Chen S Y, Xu Y N, Du H B. One-step synthesis of uniformly distributed SiOx-C composites as stable anodes for lithium-ion batteries[J]. Dalton Trans., 2022,51(31):11909-11915. doi: 10.1039/D2DT01843H

    30. [30]

      Fu R S, Ji J J, Yun L, Jiang Y B, Zhang J, Zhou X F, Liu Z P. Graphene wrapped silicon suboxides anodes with suppressed Li-uptake behavior enabled superior cycling stability[J]. Energy Stor. Mater., 2021,35:317-326.

    31. [31]

      Li H, Peng J, Wu Z Y, Liu X L, Liu P, Chang B B, Wang X Y. Constructing novel SiOx hybridization materials by a double-layer interface engineering for high-performance lithium-ion batteries[J]. Chem. Eng. J., 2023,462142172. doi: 10.1016/j.cej.2023.142172

  • 加载中
    1. [1]

      Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216

    2. [2]

      Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164

    3. [3]

      Yang LIU , Lijun WANG , Hongyu WANG , Zhidong CHEN , Lin SUN . Surface and interface modification of porous silicon anodes in lithium-ion batteries by the introduction of heterogeneous atoms and hybrid encapsulation. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 773-785. doi: 10.11862/CJIC.20250015

    4. [4]

      Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444

    5. [5]

      Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004

    6. [6]

      Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550

    7. [7]

      Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785

    8. [8]

      Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452

    9. [9]

      Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776

    10. [10]

      Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421

    11. [11]

      Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715

    12. [12]

      Mianying Huang ,  Zhiguang Xu ,  Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309

    13. [13]

      Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO2/SnO2 nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428

    14. [14]

      Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166

    15. [15]

      Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402

    16. [16]

      Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    17. [17]

      Shimei Wu , Yining Li , Lantao Chen , Yufei Zhang , Lingxing Zeng , Haosen Fan . Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes. Chinese Chemical Letters, 2025, 36(4): 109796-. doi: 10.1016/j.cclet.2024.109796

    18. [18]

      Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143

    19. [19]

      Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590

    20. [20]

      Huanyan Liu , Jiajun Long , Hua Yu , Shichao Zhang , Wenbo Liu . Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes. Chinese Chemical Letters, 2025, 36(3): 109712-. doi: 10.1016/j.cclet.2024.109712

Get Citation
PDF
XML
Metrics
  • PDF Downloads(7)
  • Abstract views(543)
  • HTML views(111)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return