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Citation: Jin-Yang MA, Ya-Nan XU, Yu ZHANG, Hong-Bin DU. Preparation of SiOx-C composite materials with a reinforced concrete-like structure for lithium-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1766-1774. doi: 10.11862/CJIC.2023.144 shu

Preparation of SiOx-C composite materials with a reinforced concrete-like structure for lithium-ion batteries

  • State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

  • Corresponding author: Hong-Bin DU, hbdu@nju.edu.cn
  • Received Date: 20 April 2023
    Revised Date: 8 July 2023

Figures(6)

  • This work reports a simple method to prepare a Si-O-C anode material with a reinforced concrete-like structure, in which carbon nanotubes (CNTs) were embedded and acted like steel bars to provide stress support, and the silicon atoms were wrapped with atomically dispersed carbon and oxygen concrete matrix. An outermost carbon layer was plated via chemical vapor deposition to further inhibit the volume change of the material. Thanks to the unique structural design, the prepared CNTs/SiOx-C/C anode showed excellent electrochemical performance with a high-capacity retention rate of 80% after 970 cycles at 0.5 A·g-1.
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