Citation: Ting-Ting GUO, Yan-Yan AN, Dan ZHAO, Juan-Zhi YAN. Polyoxometalate-directing calix[4]resorcinarene-based giant [Co₈] coordination cage: Self-assembly and electrochemical performance[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1791-1799. doi: 10.11862/CJIC.2023.143 shu

Polyoxometalate-directing calix[4]resorcinarene-based giant [Co₈] coordination cage: Self-assembly and electrochemical performance

Department of Materials Science and Chemical Engineering, Taiyuan University, Taiyuan 030032, China

Corresponding author: Ting-Ting GUO, guott223@nenu.edu.cn Juan-Zhi YAN, yanjuanzhi@tyu.edu.cn
Received Date: 15 March 2023
Revised Date: 8 July 2023

Figures(5)

Polyoxometalate(POM)-based supramolecular coordination cages have aroused wide interest in terms of their design and fabrication, however, it still be challenging. Herein, we report a POM-calixarene-based giant[Co₈] coordination cage, [Co₈(MTR4A)₆Cl₈](α-SiW₁₂O₄₀)₂·30DMF·74EtOH (cage-1), assembled with six bowl-shaped calix[4]resorcinarene(MTR4A) molecules, eight Co (Ⅱ) cations, two α-SiW₁₂O₄₀^4- counter anions, and eight Cl^- anions. Remarkably, α-SiW₁₂O₄₀^4- anions were sandwiched between layers via hydrogen-bonded to form a 3D supramolecular architecture. Moreover, cage-1 showed a good lithium-ion storage capacity as an anode material in lithium-ion batteries (LIBs). Furthermore, it was shown to be a highly active bifunctional electrocatalytic performance for reducing nitrite (NO₂^-) and oxidizing ascorbic acid (AA).
- coordination cages,
- calix[4]resorcinarene,
- polyoxometalate,
- electrocatalytic property
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Polyoxometalate-directing calix[4]resorcinarene-based giant [Co8] coordination cage: Self-assembly and electrochemical performance

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Polyoxometalate-directing calix[4]resorcinarene-based giant [Co₈] coordination cage: Self-assembly and electrochemical performance