Citation: Tian-Yue ZUO, Lan ZHANG, Hong-Yi WANG, Wu-Xiu DING. Hydrophobic metal-organic framework material based on fluorosilane-modified UIO-66-OH: Preparation and application in the conservation of limestone cultural relics[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1817-1831. doi: 10.11862/CJIC.2023.142 shu

Hydrophobic metal-organic framework material based on fluorosilane-modified UIO-66-OH: Preparation and application in the conservation of limestone cultural relics

Tian-Yue ZUO ¹ ,
Lan ZHANG ² ,
Hong-Yi WANG ³ ,
Wu-Xiu DING ^{1, 3,,}

1.
School of Civil Engineering, Henan University of Technology, Zhengzhou 450001, China
2.
School of Environmental Engineering and Chemistry, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, China
3.
School of Civil Engineering, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, China

Corresponding author: Wu-Xiu DING, wuxiu-ding@163.com
Received Date: 25 December 2022
Revised Date: 9 June 2023

Figures(15)

The development of hydrophobic materials has always been a difficult issue in the protection of stone cultural relics. In this work, a new hydrophobic metal-organic framework material was synthesized by modifying the Zr-based MOFs containing 2-hydroxyterephthalic acid linkers with fluorosilane to obtain UIO-O-FS material, and characterization tests such as FTIR, X-ray diffraction, N₂ adsorption-desorption, thermogravimetry, scanning electron microscope, and transmission electron microscope, as well as erosion resistance tests, were carried out on the material. Based on the results, the material possesses good hydrophobicity, consolidation ability, acid resistance, and salt resistance, and is a new type of stone heritage conservation material.
- metal-organic framework,
- UIO-66-OH,
- hydrophobic,
- post-synthetic modification,
- conservation of limestone heritage
1. [1]
  Castro N F, Becerra J E, Bellopede R, Marini P, Dino G A. Introduction to 'natural stones and cultural heritage promotion and preservation'[J]. Resour. Policy, 2022,78102775. doi: 10.1016/j.resourpol.2022.102775
2. [2]
  Orlowsky J, Groh M, Braun F. About the effectiveness of a hydrophobic surface treatment of Baumberger Sandstones[J]. Environ. Earth Sci., 2022,8190. doi: 10.1007/s12665-022-10186-2
3. [3]
  LIU Y, LV X Y, YANG F W, ZHANG K, YANG L, SUN M L, WANG L Q. Application of inorganic materials in consolidation of bone relics[J]. Chinese J. Inorg. Chem., 2022,38(5):777-786.
4. [4]
  Graziani G, Sassoni E, Scherer G W, Franzoni E. Resistance to simulated rain of hydroxyapatite- and calcium oxalate-based coatings for protection of marble against corrosion[J]. Corros. Sci., 2017,127:168-174. doi: 10.1016/j.corsci.2017.08.020
5. [5]
  Tesser E, Lazzarini L, Bracci S. Investigation on the chemical structure and ageing transformations of the cycloaliphaticepoxy resin EP2101 used as stone consolidant[J]. J. Cult. Herit., 2017,31:72-82.
6. [6]
  Shu H, Song Y J, Liu Q, Luo M B. The study of rod-shaped TiO₂ composite material in the protection of stone cultural relics[J]. Green Process. Synth., 2020,9:359-365. doi: 10.1515/gps-2020-0034
7. [7]
  Liu Q, Zhu Z, Zhang J, Zhang B. Application of TiO₂ photocatalyst to the stone conservation[J]. Mater. Res. Innov., 2015,19:51-54. doi: 10.1179/1433075X14Y.0000000209
8. [8]
  Aldoasri M A, Darwish S S, Adam M A, Elmarzugi N A, Ahmed S M. Protecting of marble stone facades of historic buildings using multifunctional TiO₂ nanocoatings[J]. Sustainability, 2017,92002. doi: 10.3390/su9112002
9. [9]
  Shu H, Yang M, Liu Q, Luo M B. Study of TiO₂-modified sol coating material in the protection of stone-built cultural heritage[J]. Coatings, 2020,10:179-190. doi: 10.3390/coatings10020179
10. [10]
  Tokarsky J, Martinec P, Kutláková K M, Ovcacikova H, Studentova S, Scucka J. Photoactive and hydrophobic nano-ZnO/poly(alkyl siloxane) coating for the protection of sand-stone[J]. Constr. Build. Mater., 2019,199:549-559. doi: 10.1016/j.conbuildmat.2018.12.045
11. [11]
  Aslanidou D, Karapanagiotis I, Lampakis D. Waterborne superhydrophobic and superoleophobic coatings for the protection of marble and sandstone[J]. Materials, 2018,11585. doi: 10.3390/ma11040585
12. [12]
  Al-Dosari M A, Darwish S S, Adam M A, Elmarzugi N A, Al-Mouallimi N, Ahmed S M. Ca(OH)₂ nanoparticles based on acrylic copolymers for the consolidation and protection of ancient Egypt calcareous stone monuments[J]. Journal of Physics Conference Series, 2017,829012009. doi: 10.1088/1742-6596/829/1/012009
13. [13]
  Fadwa J, Mara S, Encarnacionón R, Kerstin E, Inés M, María T G, Carlos R. Protection and consolidation of stone heritage by self-inoculation with indigenous carbonatogenic bacterial communities[J]. Nat. Commun., 2017,8279. doi: 10.1038/s41467-017-00372-3
14. [14]
  DONG T L, YANG F W, LIU Y. Research progress on calcium alkoxide material for the conservation of stone cultural relic[J]. New Chemical Materials, 2022,50(10):27-30.
15. [15]
  YANG W, WANG C Y, LIU J M, WANG Y Y, YANG G P. Studies on inorganic nanomaterials for restoration and protection of cultural heritages[J]. Chinese J. Inorg. Chem., 2021,37(8):1345-1352.
16. [16]
  Zhu J M, Jia C, Li Y K, Zhang P Y, Ding J H, Xu G, Zhao X C, Li X H. Polydopamine-modified nanolime with high kinetic stability in water for the consolidation of stone relics[J]. ACS Appl. Mater. Interfaces, 2022,14:13622-13630. doi: 10.1021/acsami.1c24699
17. [17]
  Zhu J M, Ding J H, Zhang P Y, Dong W Q, Zhao X C, Camaiti M, Li X H. In-situ growth synthesis of nanolime/kaolin nanocomposite for strongly consolidating highly porous dinosaur fossil[J]. Constr. Build. Mater., 2021,300124312. doi: 10.1016/j.conbuildmat.2021.124312
18. [18]
  Chai Y M, Wang G, Shi P, Luo H J, Zhao X C, Zhang B, Zhu J F. Nanosized ZnO/SiO₂-based amphiphobic coatings for stone heritage protection[J]. ACS Appl. Nano Mater., 2022,5:18708-18717. doi: 10.1021/acsanm.2c04463
19. [19]
  Sun D G, Adiyala P R, Yim S J, Kim D P. Pore-surface engineering by decorating metal-oxo nodes with phenylsilane to give versatile super-hydrophobic metal-organic frameworks (MOFs)[J]. Angew. Chem., 2019,131:7483-7487. doi: 10.1002/ange.201902961
20. [20]
  Fakhri H, Bagheri H. Two novel sets of UIO-66@metal oxide/graphene oxide Z-scheme heterojunction: Insight into tetracycline and malathion photodegradation[J]. J. Environ. Sci., 2020,91:222-236. doi: 10.1016/j.jes.2020.01.013
21. [21]
  XU C J, WANG C, HUANG Y M. Cu-MOFs-derived flake-like CuO to activate PMS for degrading levofloxacin antibiotics pollutant[J]. Journal of Southwest University (Natural Science Edition), 2023,45(4):178-188. doi: 10.13718/j.cnki.xdzk.2023.04.017
22. [22]
  LIU H T, DING L, ZHOU C C, ZOU H Q, LU J, WANG S N, LI Y W. Synthesis, structure, and proton conductivity of a Co-MOF based on 3-(3',5'-dicarboxyphenyl)-6-carboxylic pyridine[J]. Chinese J. Inorg. Chem., 2023,39(4):596-606.
23. [23]
  Wang H, Wang X L, Kong R M, Xia L, Qu F L. Metal-organic framework as a multi-component sensor for detection of Fe³⁺, ascorbic acid and acid phosphatase[J]. Chin. Chem. Lett., 2020,32:198-202.
24. [24]
  Shi L H, Zou X, Wang T F, Wang D M, Fan M K. Sunlight photocatalytic degradation of ofloxacin using UIO-66/wood composite photocatalysts[J]. Chin. Chem. Lett., 2021,33:442-446.
25. [25]
  QIN C, WANG B, WANG Y D. Applications of metal-organic frameworks and their derived metal oxides in resistive gas sensors[J]. Chinese J. Inorg. Chem., 2022,38(3):377-398.
26. [26]
  BAI Y F, YANG Z H, FENG Y, LIU F L, CHEN X T, CHANG J Y. Preparation and electrocatalytic performance of Zn/N co-doped carbon catalyst derived from MOF[J]. Chinese J. Inorg. Chem., 2021,37(6):1055-1061.
27. [27]
  LI S X, HUANG F L, BIN Y J, WEI Y C, TANG X L, LIAO B L. Effect of ions on photocatalytic performance of UIO-66-2OH[J]. Chinese J. Inorg. Chem., 2021,37(8):1465-1474.
28. [28]
  Wang L, Zheng M, Xie Z G. Nanoscale metal-organic frameworks for drug delivery: A conventional platform with new promise[J]. J. Mater. Chem. B, 2018,6:707-717. doi: 10.1039/C7TB02970E
29. [29]
  YU J Y, HE Z Z, CAO W, ZHANG J J, WEI Y F, GAO Y, QIAN S. Research progress of bio-metal organic frameworks in drug delivery system[J]. J. China Pharm. Univ., 2023,54(1):23-33.
30. [30]
  GUO H, LI X, QU D, CHEN Y. Research progress on Fe-based metal-organic frameworks in antitumor drug delivery[J]. Acta Pharmaceutica Sinica, 2022,57(5):1252-1262.
31. [31]
  Vo T K, Nguyen V C, Quang D T, Park B J, Kim J. Formation of structural defects within UIO-66(Zr)-(OH)₂ framework for MOF-74 CO₂ adsorption using a microwave assisted continuous-flow tubular reactor[J]. Microporous Mesoporous Mat., 2021,312:110746-1107556.
32. [32]
  LI Z H, LIU H, SONG L Y, HUANG T H. Synthesis of dual-metal functionalized MOF-74 and its adsorption properties[J]. Chinese J. Inorg. Chem., 2017,33(2):237-242.
33. [33]
  DONG W, ZHOU S A, TANG G, XIANG T F, LONG H M, DING L, ZHANG K, QIAN F P, LI G. Ultra-superhydrophobic Ti-MOF coated PET composite filter media for efficient removal of fine particulate matter[J]. China Environmental Science, 2023,43(5):2171-2181.
34. [34]
  ZHANG Z M, YANG J F, WANG Y, LI J P. Effect of water molecules on structure and properties of metal-organic frameworks[J]. Chinese J. Inorg. Chem., 2015,31(4):637-634.
35. [35]
  Jayaramulu K, Geyer F, Schneemann A, Otyepka S K M, Zboril R, Vollmer D, Fischer R A. Hydrophobic metal-organic frameworks[J]. Adv. Mater., 2019,31e1900820.
36. [36]
  Yoon Y, Lee T S. Preparation of liquid marbles using an azobenzene-based metal-organic framework particles[J]. Mol. Cryst. Liquid Cryst., 2018,660:90-97.
37. [37]
  Antwi-Baah R, Liu H Y. Recent hydrophobic metal-organic frameworks and their applications[J]. Materials, 2018,112225.
38. [38]
  Fakhri H, Bagheri H. Highly efficient Zr-MOF@WO₃/graphene oxide photocatalyst: Synthesis, characterization and photodegradation of tetracycline and malathion[J]. Mater. Sci. Semicond. Process, 2020,107104815.
39. [39]
  Zhang X W, Yang Y X, Qin P G, Han L Z, Zhu W L, Duan S F, Lu M H, Cai Z W. Facile preparation of Nano-g-C₃N₄/UIO-66-NH₂ composite as sorbent for high-efficient extraction and preconcentration of food colorants prior to HPLC analysis[J]. Chin. Chem. Lett., 2021,33:903-906.
40. [40]
  Xue R X, Liu N, Bao L Y, Lai C, Su Y F, Lu Y, Dong J Y, Chen S, Wu F. UIO-66 type metal-organic framework as a multifunctional additive to enhance the interfacial stability of Ni-rich layered cathode material[J]. J. Energy. Chem., 2020,50:378-386.
41. [41]
  Ichrafa C, Ounisb D Y, Slimc S. X-ray diffraction analysis by modified Scherrer, Williamson-Hall and size-strain plot methods of ZnO nanocrystals synthesized by oxalate route: A potential antimicrobial candidate against foodborne pathogens[J]. J. Clust. Sci., 2022,34:623-638.
42. [42]
  Xu T T, Shehzad M A, Wang X, Wu B, Ge L, Xu T W. Engineering leaf-like UIO-66-SO₃H membranes for selective transport of cations[J]. Nano-Micro Lett., 2020,12:65-75.
43. [43]
  ZHANG J H, LI Z X, GE Y Y, TANG J J, ZHOU Z, SUN L L, ZHANG H W, ZHOU D Y. Highly efficient synthesis of medium-chain structured phospholipids using HPMo@UiO-66-SO₃H[J]. Fine Chemicals, 2023. doi: 10.13550/j.jxhg.20221093
44. [44]
  HE Y P, JIN X Y, LI W Z, YANG S J, LÜ B L. Synthesis and photocatalytic properties of Bi₂WO₆/UiO-66 composite[J]. Chinese J. Inorg. Chem., 2019,35(6):996-1004.
45. [45]
  Hu Z G, Peng Y W, Kang Z X, Qian Y H, Zhao D. A modulated hydrothermal (MHT) approach for the facile synthesis of UIO-66-type MOFs[J]. Inorg. Chem., 2015,54:4862-4868.
46. [46]
  LI H L, WU J H, LIU M Z, PENG Y, ZHAO J M, QIU Y, WU J H, GAO Z X. Removal of lincomycin from water by magnetic metalorganic framework materials[J]. Journal of Food Safety & Quality, 2022,13(17):5656-5663.
1. [1]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
2. [2]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
3. [3]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
4. [4]
  Xue-Zhi Wang , Yi-Tong Liu , Chuang-Wei Zhou , Bei Wang , Dong Luo , Mo Xie , Meng-Ying Sun , Yong-Liang Huang , Jie Luo , Yan Wu , Shuixing Zhang , Xiao-Ping Zhou , Dan Li . Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars. Chinese Chemical Letters, 2024, 35(10): 109380-. doi: 10.1016/j.cclet.2023.109380
5. [5]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
6. [6]
  Ruowen Liang , Chao Zhang , Guiyang Yan . Enhancing CO2 cycloaddition through ligand functionalization: A case study of UiO-66 metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(2): 100211-100211. doi: 10.1016/j.cjsc.2023.100211
7. [7]
  Hao Wang , Meng-Qi Pan , Ya-Fei Wang , Chao Chen , Jian Xu , Yuan-Yuan Gao , Chuan-Song Qi , Wei Li , Xian-He Bu . Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes. Chinese Chemical Letters, 2024, 35(10): 109581-. doi: 10.1016/j.cclet.2024.109581
8. [8]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
9. [9]
  Zixu Xie , Pengfei Zhang , Ziyao Zhang , Chen Chen , Xing Wang . The choice of antimicrobial polymers: Hydrophilic or hydrophobic?. Chinese Chemical Letters, 2024, 35(9): 109768-. doi: 10.1016/j.cclet.2024.109768
10. [10]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
11. [11]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
12. [12]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
13. [13]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
16. [16]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
17. [17]
  Menglu Guo , Ying-Qi Song , Junfei Cheng , Guoqiang Dong , Xun Sun , Chunquan Sheng . Hydrophobic tagging-induced degradation of NAMPT in leukemia cells. Chinese Chemical Letters, 2024, 35(9): 109392-. doi: 10.1016/j.cclet.2023.109392
18. [18]
  Benjian Xin , Rui Wang , Lili Liu , Zhiqiang Niu . Metal-organic framework derived MnO@C/CNTs composite for high-rate lithium-based semi-solid flow batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100116-100116. doi: 10.1016/j.cjsc.2023.100116
19. [19]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
20. [20]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(556)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142