Anthraquinone-based metal-organic cages as efficient photocatalysts for oxidation reactions
- Corresponding author: Cheng HE, hecheng@dlut.edu.cn
Citation: Yi-Cai YU, Hai-Ling WANG, Li-Li LI, Cheng HE. Anthraquinone-based metal-organic cages as efficient photocatalysts for oxidation reactions[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1649-1660. doi: 10.11862/CJIC.2023.139
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The data was collected under N2 followed by a ramp of 10 ℃·min-1 up to 1 000 ℃.
Solvent molecules and anions are omitted for clarity; from (a) a-axis, (b) b-axis, and (c) c-axis view of the crystal structure of 2-Fe showing cluster geometry.
The circle was the peak of the metal-organic cages and the triangle was the peak of the host-guest complexes.
Reaction conditions: 0.03 mmol substrate, 0.1 μmol photocatalyst, 0.03 mmol scavenger, 3 mL solvent MeCN/H2O (1∶1, V/V), 365 nm LED light, O2, room temperature; Yields were determined by GC analysis.
Standard reaction conditions: 0.03 mmol substrate, 0.1 μmol photocatalyst, 0.03 mmol scavenger, 3 mL solvent MeCN/H2O (1∶1, V/V), 365 nm LED light, O2, room temperature; Yields were determined by GC analysis.