Citation: Dan-Dan DU, Ya-Fan HAO, Xin-Xin WANG, Jin-Jin ZHAO, Ning REN, Jian-Jun ZHANG. Crystal structure, spectra, and thermal behavior of lanthanide complexes with 2-chloro-4-fluorobenzoic acid and 5,5'-dimethyl-2,2'-bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1807-1816. doi: 10.11862/CJIC.2023.138 shu

Crystal structure, spectra, and thermal behavior of lanthanide complexes with 2-chloro-4-fluorobenzoic acid and 5,5'-dimethyl-2,2'-bipyridine

Dan-Dan DU ¹ ,
Ya-Fan HAO ¹ ,
Xin-Xin WANG ¹ ,
Jin-Jin ZHAO ^1,, ,
Ning REN ^2,, ,
Jian-Jun ZHANG ^1,,

1.
Testing and Analysis Center, College of Chemistry& Material Science, Hebei Normal University, Shijiazhuang 050024, China
2.
Hebei Key Laboratory of Heterocyclic Compounds, College of Chemical Engineering & Material, Handan University, Handan, Hebei 056005, China

Corresponding author: Jin-Jin ZHAO, zhaojinjin@hebtu.edu.cn Ning REN, ningren9@163.com Jian-Jun ZHANG, jjzhang6@126.com
Received Date: 27 February 2023
Revised Date: 24 June 2023

Figures(9)

Two binuclear complexes[Pr(2-Cl-4-FBA)₃(5,5'-DM-2,2'-bipy)]₂ (1) and[Dy(2-Cl-4-FBA)₃(5,5'-DM-2,2'-bipy)]₂·2(2-Cl-4-FHBA) (2), where 2-Cl-4-FHBA=2-chloro-4-fluorobenzoic acid and 5,5'-DM-2,2'-bipy=5,5'-dimethyl-2,2'-bipyridine, have been fabricated and characterized. The two complexes crystallize in the P1 space group of the triclinic crystal system, featuring 1D and 2D supramolecular structures. The structure of complex 2 is fascinating, containing two free 2-Cl-4-FHBA molecules, which are rare in lanthanide complexes. A three-dimensional infrared stacking diagram of the gas phase products indicates that the main gaseous products released over the whole decomposition process are water, carbon dioxide, some gaseous molecules, and the gaseous organic fragments. Also, the fluorescence property of complex 2 has been studied.
- crystal structure,
- lanthanide complex,
- thermochemical property,
- spectroscopy
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