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Citation: Ya-Hui GUAN, Liang ZHAO, Nian-Tao YAO, Oshio Hiroki, Tao LIU. Two cyano-bridged {FeⅢ2NiⅡ} single-chain magnets with huge magnetic hysteresis[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1775-1781. doi: 10.11862/CJIC.2023.136 shu

Two cyano-bridged {FeⅢ2NiⅡ} single-chain magnets with huge magnetic hysteresis

  • State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Figures(3)

  • Herein, two compounds[NiⅡ (L1)] [FeⅢ (Tp)(CN)3]2·3.5H2O (1) and[NiⅡ (L2)] [FeⅢ (Tp)(CN)3]2·3H2O (2), where Tp=hydrotris(pyrazolyl) borate, L1=3,4-bis(1H-imidazol-1-yl) thiophen, L2=1,2-bis(1H-imidazol-1-yl) thiophen, were successfully synthesized by using isomers with different symmetries to change the intermolecular hydrogen bonding network and manipulate the single-chain magnet behavior. The magnetic performance showed that 1 and 2 displayed single-chain magnet behavior with huge coercive fields of 8.41 and 3.84 kOe, respectively.
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