Citation: Heng LU, Xiao-Hong TAN, Shao-Ru WU, Yan-Mei ZHOU, Guo-Bin HUANG, Jun-Ying ZHANG, Qiao-Wen ZHENG, Zhi-Xiong CAI, Fei-Ming LI, Mao-Sheng ZHANG. Preparation of polymethyl methacrylate-coated (CH₃NH₃)PbBr₃ nanocrystalline electrospinning film and fluorescence sensing of ammonia[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1757-1765. doi: 10.11862/CJIC.2023.135 shu

Preparation of polymethyl methacrylate-coated (CH₃NH₃)PbBr₃ nanocrystalline electrospinning film and fluorescence sensing of ammonia

Heng LU ^{1, 2, #} ,
Xiao-Hong TAN ^{3, #} ,
Shao-Ru WU ^{1, 2} ,
Yan-Mei ZHOU ¹ ,
Guo-Bin HUANG ⁴ ,
Jun-Ying ZHANG ^{1, 2} ,
Qiao-Wen ZHENG ^{1, 2} ,
Zhi-Xiong CAI ^{1, 2} ,
Fei-Ming LI ^{1, 2} ,
Mao-Sheng ZHANG ^{1, 2,,}

1.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou 363000, China
2.
Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou, Fujian 363000, China
3.
College of Chemistry, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000, China
4.
Institute of Food Safety and Environment Monitoring, Fuzhou University, Fuzhou 350108, China

Corresponding author: Mao-Sheng ZHANG, zms0557@mnnu.edu.cn
Received Date: 22 November 2022
Revised Date: 18 May 2023

Figures(7)

In this work, a novel polymethyl methacrylate-coated MAPbBr₃ nanocrystalline (MAPbBr₃@PMMA, MA=methylammonium) electrospinning film was synthesized by in situ growth method, and NH₃ sensor was constructed based on the fluorescence significant quenching of the MAPbBr₃@PMMA electrospinning film after the addition of NH₃ gas. The morphology and structure of MAPbBr₃@PMMA fiber were characterized by scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, and infrared spectroscopy, and its optical properties were characterized by UV-Vis and fluorescence spectroscopy. The results showed that the prepared NH₃ sensor showed a good linear relationship (r=0.995 9) to NH₃ gas concentration in a range of 8-90 mg·L^-1, low detection limit (3 mg·L^-1), and high reproducibility and selectivity. Finally, the standard recovery and the relative standard deviation (RSD) for NH₃ of actual sample gas were 92.2%-102.1% and 1.8%-3.2%, respectively.
- perovskite,
- (CH₃NH₃)PbBr₃,
- electrospinning,
- fluorescence sensing,
- ammonia
1. [1]
  Katilie C J, Simon A G, DeGreeff L E. Quantitative analysis of vaporous ammonia by online derivatization with gas chromatography-mass spectrometry with applications to ammonium nitrate-based explosive[J]. Talanta, 2019,193:87-92. doi: 10.1016/j.talanta.2018.09.099
2. [2]
  Talwar V, Singh O, Singh R C. ZnO assisted polyaniline nanofibers and its application as ammonia gas sensor[J]. Sens. Actuator B-Chem., 2014,191:276-282. doi: 10.1016/j.snb.2013.09.106
3. [3]
  Mani G K, Rayappan J B B. A highly selective room temperature ammonia sensor using spray deposited zinc oxide thin film[J]. Sens. Actuator B-Chem, 2013,183:459-466. doi: 10.1016/j.snb.2013.03.132
4. [4]
  Wright L P, Zhang L, Cheng I, Aherne J, Wentworth G R. Impacts and effects indicators of atmospheric deposition of major pollutants to various ecosystems-A review[J]. Aerosol Air Qual. Res., 2018,18(8):1953-1992. doi: 10.4209/aaqr.2018.03.0107
5. [5]
  Skjøth C A, Geels C. The effect of climate and climate change on ammonia emissions in Europe[J]. Atmos. Chem. Phys., 2013,13(1):117-128. doi: 10.5194/acp-13-117-2013
6. [6]
  Gouma P, Kalyanasundaram K, Yun X, Stanacevic M, Wang L S. Nanosensor and breath analyzer for ammonia detection in exhaled human breath[J]. IEEE Sens. J., 2010,10(1):49-53. doi: 10.1109/JSEN.2009.2036050
7. [7]
  HOU W J, MA Y T, HAN G Y. Secondary crystallization and passivation of perovskite film induced by dithizone post-treatment[J]. Chinese J. Inorg. Chem., 2021,37(8):1414-1420.
8. [8]
  Lu H, Tan X H, Huang G B, Wu S R, Zhou Y M, Zhang J Y, Zheng Q W, Chen T J, Li F M, Cai Z X, Zeng J B, Zhang M S. Green synthesis of highly stable CsPbBr₃ perovskite nanocrystals using natural deep eutectic solvents as solvents and surface ligands[J]. Nanoscale, 2022,14(46):17222-17229. doi: 10.1039/D2NR04173A
9. [9]
  YANG Z S, KE W F, WANG Y X, HUANG L Q, GUO P C, ZHU H. Preparation and characterization of hybrid perovskite (NH₃C₆H₁₂NH₃) CuCl₄[J]. Chinese J. Inorg. Chem., 2017,33(9):1568-1572.
10. [10]
  Sharma S K, Phadnis C, Das T K, Kumar A, Kavaipatti B, Chowdhury A, Yella A. Reversible dimensionality tuning of hybrid perovskites with humidity: Visualization and application to stable solar cells[J]. Chem. Mater., 2019,31(9):3111-3117. doi: 10.1021/acs.chemmater.8b04115
11. [11]
  Stoeckel M A, Gobbi M, Bonacchi S, Liscio F, Ferlauto L, Orgiu E, Samorì P. Reversible, fast, and wide-range oxygen sensor based on nanostructured organometal halide perovskite[J]. Adv. Mater., 2017,29(38)1702469. doi: 10.1002/adma.201702469
12. [12]
  Nickel N H, Lang F, Brus V V, Shargaieva O, Rappich J. Unraveling the light-induced degradation mechanisms of CH₃NH₃PbI₃ perovskite films[J]. Adv. Electron. Mater., 2017,3(12)1700158. doi: 10.1002/aelm.201700158
13. [13]
  Chen X, Hu H W, Xia Z M, Gao W, Gou W Y, Qu Y Q, Ma Y Y. CsPbBr₃ perovskite nanocrystals as highly selective and sensitive spectrochemical probes for gaseous HCl detection[J]. J. Mater. Chem. C, 2017,5(2):309-313. doi: 10.1039/C6TC04136A
14. [14]
  Chen C Q, Cai Q, Luo F, Dong N, Guo L H, Qiu B, Lin Z Y. Sensitive fluorescent sensor for hydrogen sulfide in rat brain microdialysis via CsPbBr₃ quantum dots[J]. Anal. Chem., 2919,91(24):15915-15921.
15. [15]
  Zhang J, Gan X L, Sun H R, Yuan H B, Yu L T, Hu Z Y, Zhu Y J. Pb-site doping of lead halide perovskites for efficient solar cells[J]. Sol. RRL, 2020,4(2)1900227. doi: 10.1002/solr.201900227
16. [16]
  You X, Wu J J, Chi Y W. Superhydrophobic silica aerogels encapsulated fluorescent perovskite quantum dots for reversible sensing of SO₂ in a 3D-printed gas cell[J]. Anal. Chem., 2019,91(8):5058-5066. doi: 10.1021/acs.analchem.8b05253
17. [17]
  Kim S H, Kirakosyan A, Choi J, Kim J H. Detection of volatile organic compounds (VOCs), aliphatic amines, using highly fluorescent organic-inorganic hybrid perovskite nanoparticle[J]. Dyes Pigment., 2017,147:1-5. doi: 10.1016/j.dyepig.2017.07.066
18. [18]
  Singh A K, Singh S, Singh V N, Gupta G, Gupta B K. Probing reversible photoluminescence alteration in CH₃NH₃PbBr₃ colloidal quantum dots for luminescence-based gas sensing application[J]. J. Colloid Interface Sci., 2019,554:668-673. doi: 10.1016/j.jcis.2019.07.054
19. [19]
  Huang W, Manser J S, Sadhu S, Kamat P V, Ptasinska S. Direct observation of reversible transformation of CH₃NH₃PbI₃ and NH₄PbI₃ induced by polar gaseous molecules[J]. J. Phys. Chem. Lett., 2016,7(24):5068-5073. doi: 10.1021/acs.jpclett.6b02499
20. [20]
  Kumar P, Ganesh N, Narayan K S. Electrospun fibers containing emissive hybrid perovskite quantum dots[J]. ACS Appl. Mater. Interfaces, 2019,11(27):24468-24477. doi: 10.1021/acsami.9b08409
21. [21]
  Li G S, Zhang W Q, She C K, Jia S C, Liu S H, Yue F Y, Jing C B, Cheng Y, Chu J H. Stable fluorescent NH₃ sensor based on MAPbBr₃ encapsulated by tetrabutylammonium cations[J]. J. Alloy. Compd., 2020,835155386. doi: 10.1016/j.jallcom.2020.155386
22. [22]
  Huang H, Hao M W, Song Y L, Dang S, Liu X T, Dong Q F. Dynamic passivation in perovskite quantum dots for specific ammonia detection at room temperature[J]. Small, 2020,16(6)1904462. doi: 10.1002/smll.201904462
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of polymethyl methacrylate-coated (CH3NH3)PbBr3 nanocrystalline electrospinning film and fluorescence sensing of ammonia

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通讯作者: 陈斌, bchen63@163.com

Preparation of polymethyl methacrylate-coated (CH₃NH₃)PbBr₃ nanocrystalline electrospinning film and fluorescence sensing of ammonia