Citation: Qi WANG, Jia-Na WU, Wen-Bin WU, Ya-Ling ZHANG, Ji-Xin ZHANG, Jin-Yu YANG, Qian-Hui WANG, Sheng-Ling LI, Cui-Hong ZHANG, Li-Feng DING, Yu-Lan NIU. Medical gauze templated manganese dioxide nanoparticles for methylene blue decontamination[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1729-1737. doi: 10.11862/CJIC.2023.132 shu

Medical gauze templated manganese dioxide nanoparticles for methylene blue decontamination

1.
Chemistry & Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, 030008, China
2.
Department of Environment and Safety Engineering, Taiyuan Institute of Technology, Taiyuan, 030008, China

Corresponding author: Qi WANG, wangq@tit.edu.cn Cui-Hong ZHANG, 15536631061@126.com
Received Date: 21 February 2023
Revised Date: 19 June 2023

Figures(8)

Using medical gauze (MG) as both template and reductant, MG templated manganese dioxide nanoparticle (MnO₂ NPs/MG) was facilely synthesized through an in situ redox reaction. The morphology and composition were characterized. MnO₂ NPs were evenly loaded and dispersed on the surface of MG fibers. Combing the adsorption property of MnO₂ NPs with ease of operation of MG, MnO₂ NPs/MG were further applied to the removal of methylene blue. The results indicated that, by simple soaking and stirring under neutral conditions, the removal efficiency can reach 85.09%, and it can be improved by increasing the ratio of adsorption material dosage to the initial amount of dye. Through isothermal adsorption and kinetic studies, it was proved that the adsorption of methylene blue by MnO₂ NPs/MG conformed to Langmuir adsorption isothermal model and pseudo-second-order kinetic model.
- medical gauze,
- MnO₂ nanoparticles,
- methylene blue,
- removal
1. [1]
  Dragan E S, Dinu M V. Spectacular selectivity in the capture of methyl orange by composite anion exchangers with the organic part hosted by DAISOGEL microspheres[J]. ACS Appl. Mater. Interfaces, 2018,10:20499-20511. doi: 10.1021/acsami.8b04498
2. [2]
  Sharma A K, Priya , Kaith B S, Bajaj S, Bhatia J K, Panchal S, Sharma N, Tanwar V. Efficient capture of eosin yellow and crystal violet with high performance xanthan-acacia hybrid super-adsorbent optimized using response surface methodology[J]. Colloid Surf. B-Biointerfaces, 2019,175:314-323. doi: 10.1016/j.colsurfb.2018.12.017
3. [3]
  Qi X L, Wei W, Su T, Zhang J F, Dong W. Fabrication of a new polysaccharide-based adsorbent for water purification[J]. Carbohydr. Polym., 2018,195:368-377. doi: 10.1016/j.carbpol.2018.04.112
4. [4]
  Lyu H H, Gao B, He F, Zimmerman A R, Ding C, Tang J C, Crittenden J C. Experimental and modeling investigations of ball-milled biochar for the removal of aqueous methylene blue.[J]. Chem. Eng. J., 2018,335:110-119. doi: 10.1016/j.cej.2017.10.130
5. [5]
  Hu X S, Liang R, Sun G X. Super-adsorbent hydrogel for removal of methylene blue dye from aqueous solution.[J]. J. Mater. Chem. A, 2018,6(36):17612-17624. doi: 10.1039/C8TA04722G
6. [6]
  El-Sharkawy E A, Soliffian A Y, Al-Amer K M. Comparative study for the removal of methylene blue via adsorption and photocatalytic degradation.[J]. J. Colloid Interf. Sci., 2007,310(2):498-508. doi: 10.1016/j.jcis.2007.02.013
7. [7]
  HUANG J, CHEN H J, FENG X M. Micromotors based on Ni-Mn binary oxide and its application for effective dye adsorption.[J]. Chinese J. Inorg. Chem., 2022,38(7):1411-1420.
8. [8]
  Zhang S H, Fan X L, Xue J. A novel magnetic manganese oxide halloysite composite by one-pot synthesis for the removal of methylene blue from aqueous solution.[J]. J. Alloy. Compd., 2023,930167050. doi: 10.1016/j.jallcom.2022.167050
9. [9]
  Zhang Y, Shen B X, Ahmad M S, Zhou W J, Khalid R R, Ibrahim M, Bokhari A. A three-dimensional active biochar for sintering in steel industry and remove methylene blue by synergistic activation of H₃PO₄ and ZnCl₂.[J]. Fuel, 2023,336127079. doi: 10.1016/j.fuel.2022.127079
10. [10]
  Huang D Q, Ma J F, Fan C H, Wang K, Zhao W C, Peng M G, Komarneni S. Co-Mn-Fe complex oxide catalysts from layered double hydroxides for decomposition of methylene blue: Role of Mn.[J]. Appl. Clay Sci., 2018,152:230-238. doi: 10.1016/j.clay.2017.11.018
11. [11]
  Zhang Y B, Liu J J, Du X F, Shao W. Preparation of reusable glass hollow fiber membranes and methylene blue adsorption.[J]. J. Eur. Ceram. Soc., 2019,39(15):4891-4900. doi: 10.1016/j.jeurceramsoc.2019.06.038
12. [12]
  Ghaemi N, Safari P. Nano-porous SAPO-34 enhanced thin-film nanocomposite polymeric membrane: Simultaneously high water permeation and complete removal of cationic/anionic dyes from water.[J]. J. Hazard. Mater., 2018,358:376-388. doi: 10.1016/j.jhazmat.2018.07.017
13. [13]
  Jorfi S, Barzegar G, Ahmadi M, Soltani R D C, Haghighifard N A J, Takdastan A, Saeedi R, Abtahi M. Enhanced coagulation-photocatalytic treatment of acid red 73 dye and real textile wastewater using UVA/synthesized MgO nanoparticles.[J]. J. Environ. Manage., 2016,177:111-118. doi: 10.1016/j.jenvman.2016.04.005
14. [14]
  Thenmozhi E, Harshavardhan M, Kamala-Kannan S, Janaki V. Synthesis and characterization of mesoporous silica-MnO₂ nanocomposite — An efficient nanocatalyst for methylene blue degradation.[J]. Mater. Lett., 2022,309131367. doi: 10.1016/j.matlet.2021.131367
15. [15]
  Belousov A S, Suleimanov E V, Parkhacheva A A, Fukina D G, Koryagin A V, Koreleva A V, Zhizhin E V, Gorshkov A P. Regulating of MnO₂ photocatalytic activity in degradation of organic dyes.[J]. Solid State Sci., 2022,132106997. doi: 10.1016/j.solidstatesciences.2022.106997
16. [16]
  Pereira M D, Mendes R P, Bellettini G C, Benetti R M, Elyseu F, Bernardin A M. Photocatalytic discoloration of methylene blue by TiO₂ P25 under UV light using ISO 10678 standard as a guide.[J]. J. Photochem. Photobiol. A-Chem., 2023,435114304. doi: 10.1016/j.jphotochem.2022.114304
17. [17]
  XIA Q, LIAO X G, SHEN H L, ZHENG L, LI G, TIAN T. Co₃O₄ with different morphologies: Synthesis and performances in activating peroxymonosulfate for methylene blue degradation.[J]. Chinese J. Inorg. Chem., 2022,38(11):2191-2201. doi: 10.11862/CJIC.2022.221
18. [18]
  Wang X, Liu X R, Yuan F, Wang B Y, Peng Q A. Selective decolorization of methylene blue from methyl orange in heterogeneous Fenton-like reaction.[J]. Int. J. Environ. Res., 2023,17(1)17. doi: 10.1007/s41742-023-00509-x
19. [19]
  Ama O M, Khoele K, Anku W W, Ray S S, Osifo P O, Delport D J. Synthesis and application of MnO₂/exfoliated graphite electrodes for enhanced photoelectrochemical degradation of methylene blue and Congo red dyes in water.[J]. Electrocatalysis, 2020,11(4):413-421. doi: 10.1007/s12678-020-00601-2
20. [20]
  Wang L L, Wang L, Shi Y W, Zhao B, Zhang Z H, Ding G H, Zhang H W. Blue TiO₂ nanotube electrocatalytic membrane electrode for efficient electrochemical degradation of organic pollutants.[J]. Chemosphere, 2022,306135628. doi: 10.1016/j.chemosphere.2022.135628
21. [21]
  Yang Y C, Zhu Q L, Peng X W, Sun J J, Li C, Zhang X M, Zhang H, Chen J B, Zhou X F, Zeng H B, Zhang Y L. Hydrogels for the removal of the methylene blue dye from wastewater: A review.[J]. Environ. Chem. Lett., 2022,20:2665-2685. doi: 10.1007/s10311-022-01414-z
22. [22]
  Uddin M K. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade.[J]. Chem. Eng. J., 2017,308:438-462. doi: 10.1016/j.cej.2016.09.029
23. [23]
  Zhou G Y, Luo J M, Liu C B, Chu L, Crittenden J. Efficient heavy metal removal from industrial melting effluent using fixed-bed process based on porous hydrogel adsorbents.[J]. Water Res., 2018,131:246-254. doi: 10.1016/j.watres.2017.12.067
24. [24]
  Xue H J, Wang X M, Xu Q, Dhaouadi F, Sellaoui L, Seliem M K, Lamine A B, Belmabrouk H, Bajahzar A, Bonilla-Petriciolet A, Li Z C, Li Q. Adsorption of methylene blue from aqueous solution on activated carbons and composite prepared from an agricultural waste biomass: A comparative study by experimental and advanced modeling analysis.[J]. Chem. Eng. J., 2022,430132801. doi: 10.1016/j.cej.2021.132801
25. [25]
  Guo R F, Zhao X J, Li X Y, Liu Z H. Preparation and formation mechanism of graphene oxide supported hollow mesoporous Mg₂Si₃O₆(OH)₄ micro-nanospheres with highly efficient methylene blue dye removal from wastewater[J]. Colloid Surf.Physicochem.A-Eng. Asp., 2021,610125936. doi: 10.1016/j.colsurfa.2020.125936
26. [26]
  Zhang X, Zhang P Y, Wu Z, Zhang L, Zeng G M, Zhou C J. Adsorption of methylene blue onto humic acid-coated Fe₃O₄ nanoparticles.[J]. Colloid Surf. A-Physicochem. Eng. Asp., 2013,435:85-90. doi: 10.1016/j.colsurfa.2012.12.056
27. [27]
  Li Y W, Yin X L, Huang X H, Tian J, Wu W, Liu X L. The novel and facile preparation of 2D MoS₂@C composites for dye adsorption application[J]. Appl. Surf. Sci., 2019,495143626. doi: 10.1016/j.apsusc.2019.143626
28. [28]
  Zhang Y, Li Y H, Wang M Z, Chen B, Sun Y H, Chen K W, Du Q J, Pi X X, Wang Y Q. Adsorption of methylene blue from aqueous solution using gelatin-based carboxylic acid-functionalized carbon nanotubes@metal-organic framework composite beads.[J]. Nanomaterials, 2022,12(15)2533. doi: 10.3390/nano12152533
29. [29]
  Gong J Y, Rong S P, Wang X H, Zhou Y F. Critical review of catalytic degradation of formaldehyde via MnO₂: From the perspective of process intensification.[J]. J. Clean. Prod., 2022,377134242. doi: 10.1016/j.jclepro.2022.134242
30. [30]
  Chiam S L, Pung S Y, Yeoh F Y. Recent developments in MnO₂-based photocatalysts for organic dye removal: A review.[J]. Environ. Sci. Pollut. Res., 2020,27:5759-5778. doi: 10.1007/s11356-019-07568-8
31. [31]
  Husnain S M, Asim U, Yaqub A, Shahzad F, Abbsa N. Recent trends of MnO₂-derived adsorbents for water treatment: A review.[J]. New J. Chem., 2020,44:6096-6120. doi: 10.1039/C9NJ06392G
32. [32]
  Zhou L, Huang Y F, Qiu W W, Sun Z X, Liu Z L, Song Z G. Adsorption properties of nano-MnO₂-biochar composites for copper in aqueous solution.[J]. Molecules, 2017,22(1)173. doi: 10.3390/molecules22010173
33. [33]
  Ma J P, Wang C, Xi W K, Zhao Q Y, Wang S Y, Qiu M Q, Wang J J, Wang X K. Removal of radionuclides from aqueous solution by manganese dioxide-based Nanomaterials and mechanism research: A review.[J]. ACS EST Engg., 2021,1:684-705.
34. [34]
  Meftahi A, Khajavi R, Rashidi A, Sattari M, Yazdanshenas M E, Torabi M. The effects of cotton gauze coating with microbial cellulose.[J]. Cellulose, 2010,17(1):199-204. doi: 10.1007/s10570-009-9377-y
35. [35]
  Chacon-Patino M L, Blanco-Tirado C, Hinestroza J P, Combariza M Y. Biocomposite of nanostructured MnO₂ and fique fibers for efficient dye degradation.[J]. Green Chem., 2019,15(10):2920-2928.
36. [36]
  CHENG Y, LIU Y B, ZHAO H Y, NAN X D, FAN X Q, LI S L, DING L F, WANG Q, NIU Y L. Construction of MnO₂ nanoparticles mediated UV-visible absorption-fluorescence dual channel sensor and detection of D-penicillamine.[J]. Chinese J. Inorg. Chem., 2023,39(4):617-626.
37. [37]
  Hashem A M, Abuzeid H M, Kaus M, Indris S, Ehrenberg H, Mauger A, Julien C M. Green synthesis of nanosized manganese dioxide as positive electrode for lithium-ion batteries using lemon juice and citrus peel.[J]. Electrochim. Acta, 2018,262:74-81. doi: 10.1016/j.electacta.2018.01.024
38. [38]
  Hashem A M, Abdel-Latif A M, Abuzerd H M, Abbas H M, Ehrenberg H, Farag R S, Mauger A, Julien C M. Improvement of the electrochemical performance of nanosized α-MnO₂ used as cathode material for Li-batteries by Sn-doping.[J]. J. Alloy. Compd., 2011,509(40):9669-9674. doi: 10.1016/j.jallcom.2011.07.075
39. [39]
  Tamura H, Oda T, Nagayama M, Furuichi R. Acid-base dissociation of surface hydroxyl groups on manganese dioxide in aqueous solutions.[J]. J. Electrochem. Soc., 1989,136:2782-2786. doi: 10.1149/1.2096286
40. [40]
  Wang Q, Ma C L, Tang J K, Zhang C H, Ma L H. Eggshell membrane-templated MnO₂ nanoparticles: Facile synthesis and tetracycline hydrochloride decontamination.[J]. Nanoscale Res. Lett., 2018,13255. doi: 10.1186/s11671-018-2679-y
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