Citation: Yu ZHANG, Ying HE, Qing HE, Hui LIU, Jun-Feng MIAO, Ling-Lan LI. Preparation of Ni-Co@C-N catalysts for application to nitroaromatic-azoxybenzene reduction coupling reaction[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1738-1750. doi: 10.11862/CJIC.2023.129 shu

Preparation of Ni-Co@C-N catalysts for application to nitroaromatic-azoxybenzene reduction coupling reaction

Yu ZHANG ¹ ,
Ying HE ¹ ,
Qing HE ¹ ,
Hui LIU ^1,, ,
Jun-Feng MIAO ² ,
Ling-Lan LI ^2,,

1.
School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China
2.
College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China

Corresponding author: Hui LIU, iamliuhui@live.cn Ling-Lan LI, lilinglan@126.com
Received Date: 31 January 2023
Revised Date: 18 June 2023

Figures(10)

The low-cost supported nickel nanoparticle catalysts Ni-Co@C-N were prepared with ZIF-67 as a precursor by pyrolysis and then ethylene glycol reduction. The characterization results of X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray photoelectron spectroscopy (XPS) indicated the successful preparation of supported nickel nanoparticle catalysts Ni-Co@C-N, Ni and Co nanoparticles uniformly dispersed. Weak bases such as Na₂CO₃ and low molecular weight PVPk18 dispersants contribute to the loading of Ni nanoparticles. The results of N₂ adsorption-desorption indicated that the specific surface areas of the Ni-Co@C-N materials were between 107 and 211 m²·g^-1, and the average pore widths were between 7.4 and 11.2 nm. The catalytic performance of the Ni-Co@C-N catalysts for the synthesis of nitroaromatic compounds into the corresponding oxide azobenzene compounds was studied, and the effects of the types of alkali and dispersant on the structure and properties of catalysts were also discussed. The results demonstrated that the alkaline enhancement accelerated the nucleation rate of nanoparticles while increasing the molecular weight of dispersants limited the size growth of nanoparticles. Among them, Ni-Co@C-N-4 prepared by the weak base and low molecular weight dispersant possessed the best catalytic performance, the conversion rate and yield of raw materials reached 92.8% and 89.3% respectively after 30 min of reaction, and the cycle test showed that Ni-Co@C-N-4 had good stability.
- azoxybenzene,
- metal-organic framework,
- reduction coupling,
- bimetallic catalyst
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