Citation: Xiao-Ning TANG, Shu XIA, Qiu-Yang LUO, Jun-Nan LIU, Xing-Fu YANG, Jiao-Jing SHAO, An XUE. Effect of glycine electrolyte additive on the electrochemical performance of aqueous zinc-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1501-1509. doi: 10.11862/CJIC.2023.128 shu

Effect of glycine electrolyte additive on the electrochemical performance of aqueous zinc-ion batteries

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School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
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School of Materials and Architectural Engineering, Guizhou Normal University, Guiyang 550025, China

Corresponding author: Xiao-Ning TANG, txn2004815@163.com An XUE, xuean1129@163.com
Received Date: 14 April 2023
Revised Date: 18 June 2023

Figures(5)

Aqueous zinc-ion batteries (AZIBs) using the Zn metal anode have been considered one of the next-generation commercial batteries with high security, robust capacity, and low price. However, side reactions, Zn dendrites, and limited lifespan still constrain their practical applications. Herein, the electrolyte additive (glycine, Gly) was introduced into the conventional ZnSO₄ electrolyte (denoted as ZnSO₄-Gly). The abundant polar groups (—COOH and —NH₂) on the Gly can regulate the solvation structure of Zn²⁺ and thus redistribute Zn²⁺ deposition to avoid dendrites and side reactions. As a result, the excellent cycle life (3 000 h, at 1 mA·cm^-2 and 1 mAh·cm^-2) of the Zn||Zn symmetric cell was realized in typical ZnSO₄ electrolytes with only 50 mmol·L^-1 of Gly additive, overwhelmingly larger than bare ZnSO₄ (300 h). The Zn||MnO₂ battery with ZnSO₄-Gly electrolyte displayed much better than the additive-free device in terms of specific capacity and capacity retention.
- aqueous zinc-ion battery,
- electrolyte additive,
- glycine,
- Zn anodes,
- Zn dendrites
1. [1]
  Hao J N, Long J, Li B, Li X L, Zhang S L, Yang F H, Zeng X H, Yang Z H, Pang W K, Guo Z P. Toward high-performance hybrid Zn-based batteries via deeply understanding their mechanism and using electrolyte additive[J]. Adv. Funct. Mater., 2019,29(34)1903605. doi: 10.1002/adfm.201903605
2. [2]
  Hao J, Wang Z Q, Tawiah B, Wang Y D, Chan C Y, Fei B, Feng P. Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries[J]. Nano Energy, 2020,70104523. doi: 10.1016/j.nanoen.2020.104523
3. [3]
  Wang Y Y, Chen Y J, Liu W, Ni X Y, Qing P, Zhao Q W, Wei W F, Ji X B, Ma J M, Chen L B. Uniform and dendrite-free zinc deposition enabled by in situ formed AgZn₃ for the zinc metal anode[J]. J. Mater. Chem. A, 2021,9(13):8452-8461. doi: 10.1039/D0TA12177K
4. [4]
  Cai Z, Ou Y T, Wang J D, Xiao R, Fu L, Zhan R M, Sun Y M. Chemically resistant Cu-Zn/Zn composite anode for long cycling aqueous batteries[J]. Energy Storage Mater., 2020,27:205-211. doi: 10.1016/j.ensm.2020.01.032
5. [5]
  Yang S N, Li Y T, Du H X, Liu Y Q, Xiang Y H, Xiong L Z, Wu X M, Wu X W. Copper nanoparticle-modified carbon nanofiber for seeded Zinc deposition enables stable Zn metal anode[J]. ACS Sustain. Chem. Eng., 2022,10(38):12630-12641. doi: 10.1021/acssuschemeng.2c03328
6. [6]
  Huang Z D, Wang T R, Li X L, Cui H L, Liang G L, Yang Q, Chen Z, Chen A, Guo Y, Fan J, Zhi C Y. Small-dipole-molecule-containing electrolytes for high-voltage aqueous rechargeable batteries[J]. Adv. Mater, 2022,34(4)2106180. doi: 10.1002/adma.202106180
7. [7]
  Huang J Q, Chi X W, Du Y X, Qiu Q L, Liu Y. Ultrastable zinc anodes enabled by anti-dehydration ionic liquid polymer electrolyte for aqueous Zn batteries[J]. ACS Appl. Mater. Interfaces, 2021,13(3):4008-4016. doi: 10.1021/acsami.0c20241
8. [8]
  Wu F F, Chen Y C, Chen Y L, Yin R L, Feng Y C, Zheng D, Xu X L, Shi W H, Liu W X, Cao X H. Achieving highly reversible Zinc anodes via N, N-dimethylacetamide enabled Zn-ion solvation regulation[J]. Small, 2022,18(27)2202363. doi: 10.1002/smll.202202363
9. [9]
  Qin Y, Li H F, Han C P, Mo F N, Wang X. Chemical welding of the electrode-electrolyte interface by Zn-metal-initiated in situ gelation for ultralong-life Zn-ion batteries[J]. Adv. Mater., 2022,34(44)2207118. doi: 10.1002/adma.202207118
10. [10]
  Meng Q, Zhao R Y, Cao P H, Bai Q X, Tang J J, Liu G D, Zhou X Y, Yang J. Stabilization of Zn anode via a multifunctional cysteine additive[J]. Chem. Eng. J., 2022,447137471. doi: 10.1016/j.cej.2022.137471
11. [11]
  Wang R, Yao M J, Huang S, Tian J L, Niu Z Q. An anti-freezing and anti-drying multifunctional gel electrolyte for flexible aqueous zinc-ion batteries[J]. Sci. China Mater., 2022,65:2189-2196. doi: 10.1007/s40843-021-1924-2
12. [12]
  Tang X N, Xia S, Luo Q Y, Liu J N, Yang X F, Luo X Q, Xue A. High-performance aqueous asymmetric supercapacitors based on K⁺ and Na⁺ co-preinserted δ-MnO₂ nanocrystals[J]. J. Mater. Res., 2023. doi: 10.1557/s43578-023-01018-5
13. [13]
  He H B, Qin H Y, Wu J, Chen X F, Huang R S, Shen F, Wu Z R, Chen G N, Yin S B, Liu J. Engineering interfacial layers to enable Zn metal anodes for aqueous zinc-ion batteries[J]. Energy Storage Mater., 2021,43:317-336. doi: 10.1016/j.ensm.2021.09.012
14. [14]
  Wang T T, Li C P, Xie X S, Lu B G, He Z X, Liang S Q, Zhou J. Anode materials for aqueous zinc ion batteries: Mechanisms, properties, and perspectives[J]. ACS Nano, 2020,14(12):16321-16347. doi: 10.1021/acsnano.0c07041
15. [15]
  Han C G, Qian X, Li Q, Deng B, Zhu Y, Han Z, Zhang W, Wang W, Feng S P, Chen G. Giant thermopower of ionic gelatin near room temperature[J]. Nat. Sci. Rev., 2020,368(6494):1091-1098.
16. [16]
  Nguyen M T, Shao Q. Effects of zwitterionic molecules on ionic association in ethylene oxide-based electrolytes[J]. Fluid Phase Equilib., 2020,515112572. doi: 10.1016/j.fluid.2020.112572
17. [17]
  Shang Y, Kumar P, Musso T, Mittal U, Du Q, Liang X, Kundu D. Long-life Zn anode enabled by low volume concentration of a benign electrolyte additive[J]. Adv. Funct. Mater., 2022,32(36)2200606.
18. [18]
  Feng D D, Jiao Y C, Wu P Y. Proton-reservoir hydrogel electrolyte for long-term cycling Zn/PANI batteries in wide temperature range[J]. Angew. Chem. Int. Ed., 2023,135(1)e202215060.
19. [19]
  Zhu J L, Deng W J, Yang N, Xu X Q, Huang C, Zhou Y, Zhang M, Yuan X R, Hu J, Li C, Rui L. Biomolecular regulation of Zinc deposition to achieve ultra-long life and high-rate Zn metal anodes[J]. Small, 2022,18(29)2202509. doi: 10.1002/smll.202202509
20. [20]
  Li Y M, Wang Y Y, Xu Y, Tian W H, Wang J W, Cheng L W, Yue H, Ji R, Zhu Q N, Yuan H. Dynamic biomolecular "mask" stabilizes Zn anode[J]. Small, 2022,18(26)2202214. doi: 10.1002/smll.202202214
21. [21]
  Wang H F, Ye W Q, Yin B W, Wang K X, Riaz M S, Xie B B, Zhong Y J, Hu Y. Modulating cation migration and deposition with xylitol additive and oriented reconstruction of hydrogen bonds for stable zinc anodes[J]. Angew. Chem. Int. Ed., 2023,135(10)202218872.
22. [22]
  Lu K R, Chen C L, Wu Y, Liu C, Song J J, Jing H Y, Zhao P, Liu B Y, Xia M Z, Hao Q L. Versatile 1, 3-dimethyl-2-imidazolidinone electrolyte additive: Enables extremely long life zinc metal batteries with different substrates[J]. Sci. China Mater., 2023,457141287.
23. [23]
  Han D L, Wu S, Zhang S, Deng Y, Cui C, Zhang L, Long Y, Li H, Tao Y, Weng Z, Yang Q H, Kang F Y. A corrosion-resistant and dendrite-free Zinc metal anode in aqueous systems[J]. Small, 2020,16(29)2001736. doi: 10.1002/smll.202001736
24. [24]
  Wang M L, Wu X Y, Yang D, Zhao H N, He L, Su J, Zhang X, Yin X, Zhao K N, Wang Y Z, Wei Y J. A colloidal aqueous electrolyte modulated by oleic acid for durable zinc metal anode[J]. Chem. Eng. J., 2023,451(1)138589.
25. [25]
  Li C P, Xie X S, Liu H, Wang P J, Deng C B, Lu B, Zhou J, Liang S Q. Integrated 'all-in-one' strategy to stabilize zinc anodes for high-performance zinc-ion batteries[J]. Nat. Sci. Rev., 2022,9(3)nwab177. doi: 10.1093/nsr/nwab177
26. [26]
  HANG M M, HUANG J W, WU X W, LIANG S Q, ZHOU J. Electrolyte modulation strategies for rechargeable Zn batteries[J]. Chinese J. Inorg. Chem, 2022,38(8):1451-1469.
27. [27]
  Choi C H, Park J B, Park J H, Yu S, Kim D W. Simultaneous manipulation of electron/Zn²⁺ ion flux and desolvation effect enabled by in-situ built ultra-thin oxide-based artificial interphase for controlled deposition of Zinc metal anodes[J]. Chem. Eng. J., 2023,456(15)141015.
28. [28]
  Zhao Z W, Li P C, Zhang Z Q, Zhang H, Li G. Dendrite-free zinc anode enabled by buffer-like additive via strong cationic specific absorption[J]. Chem. Eng. J., 2023,454(4)140435.
29. [29]
  Huang C, Zhao X, Liu S, Hao Y S, Tang Q L, Hu A P, Liu Z X, Chen X H. Stabilizing zinc anodes by regulating the electrical double layer with saccharin anions[J]. Adv. Mater., 2021,33(38)2100445. doi: 10.1002/adma.202100445
30. [30]
  Li C, Shyamsunder A, Hoane A G, Long D M, Kwok C Y, Kotula P G, Zavadil K R, Gewirth A A, Nazar L F. Highly reversible Zn anode with a practical areal capacity enabled by a sustainable electrolyte and superacid interfacial chemistry[J]. Joule, 2022,6(5):1103-1120. doi: 10.1016/j.joule.2022.04.017
31. [31]
  An Y L, Tian Y, Liu C K, Xiong S L, Feng J K, Qian Y T. Rational design of sulfur-doped three-dimensional Ti₃C₂T_x MXene/ZnS heterostructure as multifunctional protective layer for dendrite-free Zinc-ion batteries[J]. ACS Nano, 2021,15(9):15259-15273. doi: 10.1021/acsnano.1c05934
32. [32]
  Hao J N, Li B, Li X L, Zeng X H, Zhang S L, Yang F H, Liu S L, Li D, Wu C, Guo Z P. An in-depth study of Zn metal surface chemistry for advanced aqueous Zn-ion batteries[J]. Adv. Mater., 2020,32(34)2003021. doi: 10.1002/adma.202003021
33. [33]
  Li G P, Wang X L, Lv S H, Wang J X, Yu W S, Dong X T, Liu D T. In situ constructing a film-coated 3D porous Zn anode byiodine etching strategy toward horizontally arranged dendrite-free Zn deposition[J]. Adv. Funct. Mater., 2022,33(4)2208288.
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