Citation: Xiao-Ning TANG, Shu XIA, Qiu-Yang LUO, Jun-Nan LIU, Xing-Fu YANG, Jiao-Jing SHAO, An XUE. Effect of glycine electrolyte additive on the electrochemical performance of aqueous zinc-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1501-1509. doi: 10.11862/CJIC.2023.128 shu

Effect of glycine electrolyte additive on the electrochemical performance of aqueous zinc-ion batteries

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  • Aqueous zinc-ion batteries (AZIBs) using the Zn metal anode have been considered one of the next-generation commercial batteries with high security, robust capacity, and low price. However, side reactions, Zn dendrites, and limited lifespan still constrain their practical applications. Herein, the electrolyte additive (glycine, Gly) was introduced into the conventional ZnSO4 electrolyte (denoted as ZnSO4-Gly). The abundant polar groups (—COOH and —NH2) on the Gly can regulate the solvation structure of Zn2+ and thus redistribute Zn2+ deposition to avoid dendrites and side reactions. As a result, the excellent cycle life (3 000 h, at 1 mA·cm-2 and 1 mAh·cm-2) of the Zn||Zn symmetric cell was realized in typical ZnSO4 electrolytes with only 50 mmol·L-1 of Gly additive, overwhelmingly larger than bare ZnSO4 (300 h). The Zn||MnO2 battery with ZnSO4-Gly electrolyte displayed much better than the additive-free device in terms of specific capacity and capacity retention.
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