Citation: Kai-Min WANG, Xiong ZHAO, Xu-Ling BAI, Yan-Qiu DONG, Rui-Feng FAN, Hong-Mei YU, Huai-Jun TANG, Yu-Lu MA. A fluorescence sensor based on Cd(Ⅱ) coordination polymer for recognition of nitrofurantoin[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1587-1596. doi: 10.11862/CJIC.2023.125 shu

A fluorescence sensor based on Cd(Ⅱ) coordination polymer for recognition of nitrofurantoin

1.
School of Chemistry & Environment, Yunnan Minzu University, Kunming 650504, China
2.
School of Pharmaceutical Sciences and Yunnan Key Laboratory of Pharmacology for Natural Products, Kunming Medical University, Kunming 650500, China

Corresponding author: Kai-Min WANG, kmwang041684@163.com Rui-Feng FAN, 171951246@qq.com Yu-Lu MA, yuluma163@163.com
Received Date: 13 February 2023
Revised Date: 24 May 2023

Figures(6)

A new 2D coordination polymer (CP) [Cd₂(L)(dbpy)₂(HCOO)(H₂O)]•3H₂O (1), where H₃L=5-((4-carboxybenzyl)amino)isophthalic acid and dbpy=5, 5′-dimethyl-2, 2′-bipyridine, was successfully synthesized by solvothermal method. The structure of CP 1 was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, IR, thermogravimetric analysis, and solid fluorescence spectroscopy. The structure of CP 1 can be simplified into a 3-connected 2D hcb layer with the point symbol of (6³). More importantly, CP 1 could selectively and sensitively recognize antibiotic nitrofurantoin in an aqueous medium by fluorescence quenching effect and had a low detection limit (LOD=0.19 μmol•L^-1). In addition, the fluorescence quenching mechanism may be caused by the fluorescence resonance energy transfer.
- Cd(Ⅱ),
- coordination polymer,
- fluorescence sensor,
- nitrofurantoin,
- antibiotic residue
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沈阳化工大学材料科学与工程学院沈阳 110142