Citation: Guo-Ling LI, Meng-Meng WANG, Xin-Xue TANG, Ran ZHANG, Zhong-Hai NI. Synthesis, crystal structure, and magnetic properties of a cyanide-bridged Fe₄^ⅢNi₂^Ⅱ hexa-nuclear complex based on tricyanideferrate(Ⅲ)[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1564-1570. doi: 10.11862/CJIC.2023.119 shu

Synthesis, crystal structure, and magnetic properties of a cyanide-bridged Fe₄^ⅢNi₂^Ⅱ hexa-nuclear complex based on tricyanideferrate(Ⅲ)

1.
School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong 999077, China

Corresponding author: Guo-Ling LI, 6469@cumt.edu.cn Zhong-Hai NI, nizhonghai@cumt.edu.cn
Received Date: 23 February 2023
Revised Date: 8 May 2023

Figures(4)

A cyanide-bridged Fe₄^ⅢNi₂^Ⅱ hexa-nuclear complex [Fe₄Ni₂(Tp)₄(CN)₁₂(dpzpen)₂]·12H₂O·3CH₃OH (1) (Tp=hydrotris(pyrazolyl)borate, dpzpen=2, 9-di(pyrazo-1-yl)-1, 10-phenanthroline) was prepared by the reaction of tricyanideferrate(Ⅲ) (Bu₄N)[Fe^Ⅲ(Tp)(CN)₃] with ligand dpzpen and Ni^Ⅱ salt. Structural analysis indicates that two [Fe^Ⅲ(Tp)(CN)₃]^- units bridge two [Ni^Ⅱ(dpzpen)]²⁺ fragments forming an approximately rhombic Fe₂^ⅢNi₂^Ⅱ skeleton with another two [Fe^Ⅲ(Tp)(CN)₃]^- hanging outside the rhombus through cyanide bridges. Magnetic studies show that complex 1 exhibits ferromagnetic interaction between Fe^Ⅲ and Ni^Ⅱ through cyanide groups. More significantly, the magnetic-structural relationship of complex 1 was established by fitting the temperature dependence of magnetic susceptibility based on its structural model. The best-fitting parameters J_3d (15.73 cm^-1) > J_2d (3.53 cm^-1) ≈ J_1d (3.50 cm^-1) were in good agreement with the variation tendency of corresponding Ni—N bond lengths and Ni—N≡C angles (J_3d: 0.206 5 nm, 169.8°; J_2d: 0.206 2 nm, 163.1°; J_1d: 0.198 7 nm, 161.6°), indicating a shorter Ni—N bond length and a larger Ni—N≡C angle in favor of ferromagnetic interaction for cyanide-bridged Fe^Ⅲ-Ni^Ⅱ system.
- tricyanideferrate(Ⅲ),
- Fe^ⅢNi^Ⅱ complex,
- crystal structure,
- magnetic property,
- magnetic-structural relationship
1. [1]
  YANG R, ZHANG S Y, WANG R G, MENG Y S, LIU T, ZHU Y Y. Synthesis and magnetic properties of mononuclear cobalt(Ⅱ) spin crossover complexes from complementary terpyridine ligand pairing[J]. Chinese J. Inorg. Chem, 2022,38(8):1477-1486.
2. [2]
  LIU D, ZHAO L, SHAO Z, MENG Y S, LIU T. A 2D cyano-bridged W^Ⅴ-Co^Ⅱ coordination network exhibiting reversible thermal-induced charge transfer[J]. Chinese J. Inorg. Chem., 2023,39(2):367-374.
3. [3]
  Nihei M, Yanai Y, Hsu I J, Sekine Y, Oshio H. A hydrogen-bonded cyanide-bridged[Co₂Fe₂] square complex exhibiting a three-step spin transition[J]. Angew. Chem. Int. Ed., 2017,56(2):591-594. doi: 10.1002/anie.201610268
4. [4]
  Zhang Y, Malik U P, Quiggins B, Nguyen H, Beedle C C, Kovalev A E, Clérac R, Hill S, Bythell B J, Holmes S M. Structure-property relationships in tricyanoferrate(Ⅲ) building blocks and trinuclear cyanide-bridged complexes[J]. Eur. J. Inorg. Chem., 2016(15/16):2432-2442.
5. [5]
  Li G L, Chen W Q, Zhang Z L, Ni Z H, Yu M M, Kou H Z. Syntheses, crystal structures and magnetic properties of three cyanide-bridged iron(Ⅲ)-manganese(Ⅱ) binuclear complexes based on dicyanideferrite(Ⅲ) building blocks[J]. Transition Met. Chem., 2012,37:469-474. doi: 10.1007/s11243-012-9611-6
6. [6]
  Zhang Y Z, Gao S, Wang Z M, Su G, Sun H L, Pan F. Rational synthesis and magnetic properties of a family of low-dimensional heterometallic Cr-Mn complexes based on the versatile building block[Cr(2, 2'-bipyridine)(CN)₄]^-[J]. Inorg. Chem., 2005,44:4534-4545. doi: 10.1021/ic0484194
7. [7]
  Erkarslan U, Oylumluoglu G, Coban M B, Ö ztürk E, Kara H. Cyanide-bridged trinuclear Mn^Ⅲ-Fe^Ⅲ assembly: Crystal structure, magnetic and photoluminescence behavior[J]. Inorg. Chem. Acta, 2016,445:57-61. doi: 10.1016/j.ica.2016.02.010
8. [8]
  Zhao X H, Shao D, Chen J T, Liu M, Li T, Yang J, Zhang Y Z. Spin and valence isomerism in cyanide-bridged {Fe₂^ⅢM^Ⅱ} (M=Fe and Co) clusters[J]. Dalton Trans., 2021,50:9768-9774. doi: 10.1039/D1DT01298C
9. [9]
  Meng Y S, Sato O, Liu T. Manipulating metal-to-metal charge transfer for materials with switchable functionality[J]. Angew. Chem. Int. Ed., 2018,57(38):12216-12226. doi: 10.1002/anie.201804557
10. [10]
  Shaikh K, Santra A, Chattopadhyay S. Use of hexacyanometalates as efficient linkers to assemble manganese(Ⅲ)-salen moieties forming cyanide bridged polynuclear complexes: A review[J]. Polyhedron, 2022,224115977. doi: 10.1016/j.poly.2022.115977
11. [11]
  Mondal A, Li Y, Chamoreau L M, Seuleiman M, Rechignat L, Bousseksou A, Boillot M L, Lescouë zec R. Photo- and thermo- induced spin crossover in a cyanide-bridged {Mo₂^ⅤFe₂^Ⅱ} rhombus molecule[J]. Chem. Commun., 2014,50:2893-2895. doi: 10.1039/C3CC49164A
12. [12]
  Pinkowicz D, Southerland H, Wang X Y, Dunbar K R. Record antiferromagnetic coupling for a 3d/4d cyanide-bridged compound[J]. J. Am. Chem. Soc., 2014,136(28):9922-9924. doi: 10.1021/ja5044352
13. [13]
  Li G L, Zhang L F, Ni Z H, Kou H Z, Cui A L. Cyanide-Bridged Cr^ⅢMn^Ⅱ binuclear complexes based on [Mn(phen)₂]²⁺ and dicyanidechromate(Ⅲ) building blocks: Syntheses, crystal structures, and magnetic properties[J]. Bull. Korean Chem. Soc., 2012,33(5):1675-1680. doi: 10.5012/bkcs.2012.33.5.1675
14. [14]
  Kang S, Zheng H, Liu T, Hamachi K, Kanegawa S, Sugimoto K, Shiota Y, Hayami S, Mito M, Nakamura T, Nakano M, Baker M L, Nojiri H, Yoshizawa K, Duan C, Sato O. A ferromagnetically coupled Fe₄₂ cyanide-bridged nanocage[J]. Nat. Commun., 2015,65955. doi: 10.1038/ncomms6955
15. [15]
  Huang W, Wu S Q, Gu X W, Li Y, Okazawa A, Kojima N, Hayami S, Baker M L, Bencok P, Noguchi M, Miyazaki Y, Nakano M, Nakanishi T, Kanegawa S, Inagaki Y, Kawae T, Zhuang G L, Shiota Y, Yoshizawa K, Wu D Y, Sato O. Temperature dependence of spherical electron transfer in a nanosized[Fe₁₄] complex[J]. Nat. Commun., 2019,105510. doi: 10.1038/s41467-019-13279-y
16. [16]
  Meng L, Deng Y F, Zhang Y Z. Anion-dependent electron transfer in the cyanide-bridged[Fe₂Co₂]capsules[J]. Inorg. Chem., 2021,60(18):14330-14335. doi: 10.1021/acs.inorgchem.1c01952
17. [17]
  Ahmed S, Kumar A, Mukhopadhyay N, Lloret F, Mukherjee R. Heterobimetallic cyanide-bridged Fe^Ⅲ(μ-CN)M^Ⅱ complexes (M=Mn and Cu): Synthesis, structure and magnetism[J]. New J. Chem., 2022,46:7711-7720. doi: 10.1039/D2NJ00126H
18. [18]
  Cheng Y, Chen Z Y, Xie K P, Deng Y F, Jiang Y X, Liu Q, Zhang Y Z. Cyanide-bridged Fe-Co polynuclear clusters based on four-coordinate cobalt(Ⅱ)[J]. Inorg. Chem., 2020,59(12):8025-8033. doi: 10.1021/acs.inorgchem.0c00233
19. [19]
  Shiga T, Tetsuka T, Sakai K, Sekine Y, Nihei M, Newton G N, Oshio H. Cyanide-bridged decanuclear cobalt-iron cage[J]. Inorg. Chem., 2014,53(12):5899-5901. doi: 10.1021/ic500964m
20. [20]
  Li G L, Nie J, Ni Z H, Zhao Y, Zhang L F. Syntheses, crystal structures and magnetic properties of two Fe^Ⅲ-Mn^Ⅲ complexes based on manganese(Ⅲ)-porphyrin and tetracyanideferrite(Ⅲ) building blocks[J]. Inorg. Chem. Commun., 2012,19:66-69. doi: 10.1016/j.inoche.2012.02.012
21. [21]
  Zheng C Y, Xu J P, Wang F, Tao J, Li D F. Spin crossover and reversible single-crystal to single-crystal transformation behaviour in two cyanide-bridged mixed-valence {Fe₂^ⅢFe₂^Ⅱ} clusters[J]. Dalton Trans., 2016,45:17254-17263. doi: 10.1039/C6DT03436E
22. [22]
  Liu X R, Jiao C Q, Meng Y S, Zhu H L, Jiang W J, Wen W, Zhao L, Liu T. Single-molecule magnet behavior in two tetranuclear cyanide-bridged Fe₂^ⅢNi₂^Ⅱ compounds[J]. Z. Anorg. Allg. Chem., 2019,645(4):428-432. doi: 10.1002/zaac.201800401
23. [23]
  Ni Z H, Kou H Z, Zhang L F, Ge C, Cui A L, Wang R J, Li Y, Sato O. [Mn^Ⅲ(salen)]₆[Fe^Ⅲ(bpmb)(CN)₂]₆·7H₂O: A cyanide-bridged nanosized molecular wheel. Angew[J]. Chem. Ed. Int, 2005,44(47):7742-7745. doi: 10.1002/anie.200502699
24. [24]
  Zhang D P, Wang H L, Tian L J, Kou H Z, Jiang J Z, Ni Z H. Synthesis, crystal structures, and magnetic properties of cyanide-bridged Fe(Ⅲ)-Mn(Ⅲ) complexes based on manganese(Ⅲ)-porphyrin and pyridinecarboxamide dicyanideiron(Ⅲ) building blocks[J]. Cryst. Growth Des., 2009,9(9):3989-3996. doi: 10.1021/cg9001253
25. [25]
  Li G L, Wu S Q, Zhang L F, Wang Z X, Ouyang Z W, Ni Z H, Su S Q, Yao Z S, Li J Q, Sato O. Field-induced slow magnetic relaxation in an octacoordinated Fe(Ⅱ) complex with pseudo-D_2d symmetry: Magnetic, HF-EPR, and theoretical investigations[J]. Inorg. Chem., 2017,56(14):8018-8025. doi: 10.1021/acs.inorgchem.7b00765
26. [26]
  Lescouë zec R, Vaissermann J, Lloret F, Julve M, Verdaguer M. Ferromagnetic coupling between low- and high-spin iron(Ⅲ) ions in the tetranuclear complex. fac-{[Fe^Ⅲ{HB(pz)₃}(CN)₂(μ-CN)]₃Fe^Ⅲ(H₂O)₃}·6H₂O ([HB(pz)₃]^-=hydrotris(1-pyrazolyl)borate).[J]. Inorg. Chem, 2002,41(23):5943-5945. doi: 10.1021/ic020374o
27. [27]
  MIAO B X, LI G L, ZHAO Y, NI Z H. Synthesis, crystal structure and magnetic properties of a one-dimensional cyanide-bridged Fe^Ⅲ-Cu^Ⅱ complex {[Fe(1-CH₃im)(CN)₄(μ-CN)Cu(cyclam)]·H₂O}_n[J]. Chinese J. Inorg. Chem., 2013,29(11):2470-2474.
28. [28]
  Liu W, Wang C F, Li Y Z, Zuo J L, You X Z. Structural and magnetic studies on cyano-bridged rectangular Fe₂M₂ (M=Cu, Ni) clusters[J]. Inorg. Chem, 2006,45(25):10058-10065. doi: 10.1021/ic061347r
29. [29]
  Zhang Y Z, Mallik U P, Clérac R, Rath N P, Holmes S M. Irreversible solvent-driven conversion in cyanometalate {Fe₂Ni}_n (n=2, 3) single-molecule magnets[J]. Chem. Commun., 2011,47:7194-7196. doi: 10.1039/c1cc10679a
30. [30]
  Wu D Y, Zhang Y J, Huang W, Sato O. An. S=3 cyanide-bridged tetranuclear Fe₂^ⅢNi₂^Ⅱ square that exhibits slow relaxation of magnetization: synthesis, structure and magnetic properties[J]. Dalton Trans, 2010,39:5500-5503. doi: 10.1039/b925698a
31. [31]
  Zhuang P F, Zhang Y J, Zheng H, Jiao C Q, Zhao L, Wang J L, He C, Duan C Y, Liu T. Single-molecule magnet behavior in three cyano-bridged heterometallic Fe^Ⅲ-Ni^Ⅱ clusters[J]. Dalton Trans., 2015,44:3393-3398.
32. [32]
  Jiao C Q, Jiang W J, Wen W, Ren Y, Wang J L, Liu T, He C. Single-molecule magnet behavior in a tetranuclear cyano-bridged Fe₂^ⅢNi₂^Ⅱ cluster[J]. Inorg. Chem. Commun., 2016,74:12-15.
1. [1]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
4. [4]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
10. [10]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
11. [11]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
12. [12]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
13. [13]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
14. [14]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
15. [15]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
16. [16]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
19. [19]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(784)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, crystal structure, and magnetic properties of a cyanide-bridged Fe4ⅢNi2Ⅱ hexa-nuclear complex based on tricyanideferrate(Ⅲ)

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, crystal structure, and magnetic properties of a cyanide-bridged Fe₄^ⅢNi₂^Ⅱ hexa-nuclear complex based on tricyanideferrate(Ⅲ)