Citation: Hui-Yu WANG, Shu-Qin LIU, Ke-Xin FENG, Jian-Jun ZHANG. Afterglow stimulation response behaviors of a benzimidazole derivative based on crystalline-to-crystalline transition[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1571-1578. doi: 10.11862/CJIC.2023.118 shu

Afterglow stimulation response behaviors of a benzimidazole derivative based on crystalline-to-crystalline transition

School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Shu-Qin LIU, shuqinliu@163.com Jian-Jun ZHANG, zhangjj@dlut.edu.cn
Received Date: 7 March 2023
Revised Date: 6 May 2023

Figures(5)

A new organic compound 3-(5, 7-dioxoimidazo[4, 5-f]isoindol-6(1H, 5H, 7H)-yl) benzenesulfonic acid (DIBS) was synthesized by condensation of benzimidazo-5, 6-dicarboxylic acid and m-aminobenzene sulfonic acid. Then two solid phases, DIBS(10℃) and DIBS(60℃), were obtained by recrystallization at different temperatures. DIBS(10℃) had green room temperature phosphorescence with a lifetime of 721.6 ms, while the yellow-green afterglow of DIBS(60℃) consisted of delayed fluorescence and room temperature phosphorescence with lifetimes of 259.8 and 336.3 ms, respectively. The different luminescence behaviors of the two phases can be attributed to the different conformations and stacking structures of DIBS molecules in the two phases. Interestingly, DIBS(10℃) could be transformed into DIBS(60℃) under grinding or heating stimulation, showing rare afterglow stimulus - response behavior.
- room temperature phosphorescence,
- delayed fluorescence,
- mechanochromic luminescence,
- thermochromic luminescence,
- molecular packing
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