Citation: Long SUN, Xiao-Xia WANG, Feng SU. Synthesis, structure, and electrocatalytic oxygen reduction reaction properties ofmetal chalcogenide non-supertetrahedral In—Sn—S cluster materials[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1369-1378. doi: 10.11862/CJIC.2023.112 shu

Synthesis, structure, and electrocatalytic oxygen reduction reaction properties ofmetal chalcogenide non-supertetrahedral In—Sn—S cluster materials

Department of Chemistry, Changzhi University, Changzhi, Shanxi 046011, China

Corresponding author: Long SUN, sxsunlong@163.com
Received Date: 12 February 2023
Revised Date: 7 May 2023

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The development of metal chalcogenide non-supertetrahedral (non-Tn) cluster materials composed of metal In and Sn is very important for realizing the structural diversity of the materials and enriching their photoelectric applications. Herein, a series of new non-Tn cluster-based compounds C₇H₁₃N₂[InS₂] (1), (C₇H₁₃N₂)₄[In₂S₁₁Sn₃] (2), and (C₇H₁₃N₂)₃[In₃S₁₂Sn₃] (3) were prepared by the solvothermal method, where C₇H₁₃N₂=protonated 1, 5-diazabicyclo[4.3.0]non-5-ene. The three compounds are formed by the combination of {SnS₄}, {InS₄}, or {InS₅} coordination units in the way of edge-sharing or vertex-sharing. The electrocatalytic oxygen reduction reaction (ORR) study showed that the reduction peak potentials of compounds 1-3 were 0.6, 0.64, and 0.65 V, respectively, which indicates that compounds 2 and 3 containing Sn(Ⅳ) have better catalytic performance. More than that, the Koutecky-Levich plot analysis showed that the composition ratio of In and Sn in the compounds has a significant modulating effect on the ORR catalytic pathways.
- metal sulfides,
- cluster chemistry,
- crystal structure,
- oxygen reduction reaction
1. [1]
  Manos M J, Kanatzidis M G. Metal sulfide ion exchangers: Superior sorbents for the capture of toxic and nuclear waste-related metal ions[J]. Chem. Sci., 2016,7(8):4804-4824. doi: 10.1039/C6SC01039C
2. [2]
  Feng M L, Sarma D, Gao Y J, Qi X H, Li W A, Huang X Y, Kanatzidis M G. Efficient removal of[UO₂]²⁺, Cs⁺, and Sr²⁺ ions by radiation-resistant gallium thioantimonates[J]. J. Am. Chem. Soc., 2018,140(35):11133-11140. doi: 10.1021/jacs.8b07457
3. [3]
  Li W A, Peng Y C, Ma W, Huang X Y, Feng M L. Rapid and selective removal of Cs⁺ and Sr²⁺ ions by two zeolite-type sulfides via ion exchange method[J]. Chem. Eng. J., 2022,442(2)136377.
4. [4]
  Zhu J Y, Cheng L, Zhao Y M, Li M Y, Wang Z Z, Wang J, Wang C, Wang K Y. Structural investigation on the efficient capture of Cs⁺ and Sr²⁺ by a microporous Cd-Sn-Se ion exchanger constructed from mono-lacunary supertetrahedral clusters[J]. Inorg. Chem. Front., 2022,9:2880-2894. doi: 10.1039/D2QI00338D
5. [5]
  Nie L N, Jian X, Liu G F, Hao S J, Xu Z J, Xu R, Zhang Q C. Crystalline In-Sb-S framework for highly-performed lithium/sodium storage[J]. J. Mater. Chem. A, 2017,5(27):14198-14205. doi: 10.1039/C7TA03334F//www.cnki.com.cn/Article/CJFDTOTAL-HJKZ201507007.htm2017.01.017
6. [6]
  Tang J Q, Wang X, Zhang J X, Wang J, Yin W J, Li D S, Wu T. A chalcogenide-cluster-based semiconducting nanotube array with oriented photoconductive behavior[J]. Nat. Commun., 2021,12(1)4275. doi: 10.1038/s41467-021-24510-0
7. [7]
  Lin J, Dong Y Z, Zhang Q, Hu D D, Li N, Wang L, Liu Y, Wu T. Interrupted chalcogenide-based zeolite-analogue semiconductor: Atomically precise doping for tunable electro-/photoelectrochemical properties[J]. Angew. Chem. Int. Ed., 2015,54(17):5103-5107. doi: 10.1002/anie.201500659
8. [8]
  Liu D L, Fan X, Wang X, Hu D D, Xue C Z, Liu Y, Wang Y, Zhu X, Guo J, Lin H P, Li Y Y, Zhong J, Li D S, Bu X H, Feng P Y, Wu T. Cooperativity by multi-metals confined in supertetrahedral sulfide nanoclusters to enhance electrocatalytic hydrogen evolution[J]. Chem. Mater., 2018,31(2):553-559.
9. [9]
  Wang W, Wang X, Hu D D, Yang H J, Xue C Z, Lin Z E, Wu T. An unusual metal chalcogenide zeolitic framework built from the extended spiro-5 units with supertetrahedral clusters as nodes[J]. Inorg. Chem., 2018,57(3):921-925. doi: 10.1021/acs.inorgchem.7b03057
10. [10]
  Lin Q P, Bu X H, Mao C Y, Zhao X, Sasan K, Feng P Y. Mimicking high-silica zeolites: Highly stable germanium- and tin-rich zeolite-type chalcogenides[J]. J. Am. Chem. Soc., 2015,137(19):6184-6187. doi: 10.1021/jacs.5b03550
11. [11]
  Sasan K, Lin Q P, Mao C Y, Feng P Y. Open framework metal chalcogenides as efficient photocatalysts for reduction of CO₂ into renewable hydrocarbon fuel[J]. Nanoscale, 2016,8(21):10913-10916. doi: 10.1039/C6NR02525K
12. [12]
  Bu X H, Zheng N F, Feng P Y. Tetrahedral chalcogenide clusters and open frameworks[J]. Chem.-Eur. J., 2004,10(14):3356-3362. doi: 10.1002/chem.200306041
13. [13]
  Zhang J X, Bu X H, Feng P Y, Wu T. Metal chalcogenide supertetrahedral clusters: Synthetic control over assembly, dispersibility, and their functional applications[J]. Acc. Chem. Res., 2020,53(10):2261-2272. doi: 10.1021/acs.accounts.0c00381
14. [14]
  Silva-Gaspar B, Martinez-Franco R, Pirngruber G, Fécant A, Diaz U, Corma A. Open-framework chalcogenide materials—From isolated clusters to highly ordered structures and their photocatalytic applications[J]. Coord. Chem. Rev., 2022,453214243. doi: 10.1016/j.ccr.2021.214243
15. [15]
  Wu T, Bu X H, Zhao X, Khazhakyan R, Feng P Y. Phase selection and site-selective distribution by tin and sulfur in supertetrahedral zinc gallium selenides[J]. J. Am. Chem. Soc., 2011,133(24):9616-9625. doi: 10.1021/ja203143q
16. [16]
  Zhang J X, Feng P Y, Bu X H, Wu T. Atomically precise metal chalcogenide supertetrahedral clusters: Frameworks to molecules, and structure to function[J]. Nati. Sci. Rev., 2022,9nwab076. doi: 10.1093/nsr/nwab076
17. [17]
  Feng M L, Wang K Y, Huang X Y. Combination of metal coordination tetrahedra and asymmetric coordination geometries of Sb(Ⅲ) in the organically directed chalcogenidometalates: Structural diversity and ion-exchange properties[J]. Chem. Rec., 2016,16(2):582-600. doi: 10.1002/tcr.201500243
18. [18]
  Wang K Y, Feng M L, Huang X Y, Li J. Organically directed heterometallic chalcogenidometalates containing group 12(Ⅱ)/13(Ⅲ)/14(Ⅳ) metal ions and antimony(Ⅲ)[J]. Coord. Chem. Rev., 2016,322:41-68. doi: 10.1016/j.ccr.2016.04.021
19. [19]
  SHELE M G, DU C X, TIAN X Y, BAIYIN M H. Solvothermal synthesis and properties of quaternary chalcogenides containing transition metals cadmium or mercury[J]. Chinese J. Inorg. Chem., 2021,37(12):2149-2157.
20. [20]
  Wang K Y, Ding D, Zhang S, Wang Y L, Liu W, Wang S, Wang S H, Liu D, Wang C. Preparation of thermochromic selenidostannates in deep eutectic solvents[J]. Chem. Commun., 2018,54(38):4806-4809. doi: 10.1039/C8CC01614C
21. [21]
  Wang K Y, Sun M, Ding D, Liu H W, Cheng L, Wang C. Di-lacunary[In₆S₁₅]^12- cluster: The building block of a highly negatively charged framework for superior Sr²⁺ adsorption capacities[J]. Chem. Commun., 2020,56:3409-3412. doi: 10.1039/D0CC00441C
22. [22]
  Zhang K, Dong H F, Dai W H, Meng X D, Lu H T, Wu T T, Zhang X J. Fabricating Pt/Sn-In₂O₃ nanoflower with advanced oxygen reduction reaction performance for high-sensitivity microrna electrochemical detection[J]. Anal. Chem., 2017,89(1):648-655. doi: 10.1021/acs.analchem.6b02858
23. [23]
  Chen H L, Chen J X, Si J C, Hou Y, Zheng Q, Yang B, Li Z J, Gao L G, Lei L C, Wen Z H, Feng X L. Ultrathin tin monosulfide nanosheets with the exposed (001) plane for efficient electrocatalytic conversion of CO₂ into formate[J]. Chem. Sci., 2020,11(15):3952-3958. doi: 10.1039/C9SC06548B
24. [24]
  Zhao X L, Huang M, Deng B W, Li K L, Li F, Dong F. Interfacial engineering of In₂O₃/InN heterostructure with promoted charge transfer for highly efficient CO₂ reduction to formate[J]. Chem. Eng. J., 2022,437135114. doi: 10.1016/j.cej.2022.135114
25. [25]
  FENG M L, HUANG X Y. Recent progress in organic hybrid main group heterometallic chalcogenides based on antimony[J]. Chinese J. Inorg. Chem., 2013,29(8):1599-1608.
26. [26]
  Sheldrick G M. A short history of SHELX[J]. Acta Crystallogr. Sect. A, 2008,A64:112-122.
27. [27]
  Sheldrick G M. Crystal structure refinement with SHELXL[J]. Acta Crystallogr. Sect. C, 2015,C71:3-8.
28. [28]
  Brown I D. The chemical bond in inorganic chemistry: The bond valence model. Oxford: Oxford University Press, 2006: 27-29
29. [29]
  Zhang Y Y, Hu D D, Xue C Z, Yang H J, Wang X, Wu T. A 3D neutral chalcogenide framework built from a supertetrahedral T3 cluster and a metal complex for the electrocatalytic oxygen reduction reaction[J]. Dalton Trans., 2018,47:3227-3230. doi: 10.1039/C7DT04891B
30. [30]
  Wu Z, Wang X L, Hu D D, Wu S J, Liu C D, Wang X, Zhou R, Li D S, Wu T. A new cluster-based chalcogenide zeolite analogue with a large inter-cluster bridging angle[J]. Inorg. Chem. Front., 2019,6:3063-3069. doi: 10.1039/C9QI01051C
31. [31]
  Peng Y, Bai Y, Liu C L, Cao S, Kong Q Q, Pang H. Applications of metal-organic framework-derived N, P, S doped materials in electrochemical energy conversion and storage[J]. Coord. Chem. Rev., 2022,466214602. doi: 10.1016/j.ccr.2022.214602
32. [32]
  Du M, Li X R, Pang H, Xu Q. Alloy electrocatalysts[J]. EnergyChem, 2023,5(2)100083. doi: 10.1016/j.enchem.2022.100083
33. [33]
  Qiu Z W, Bai Y, Gao Y D, Liu C L, Ru Y, Pi Y C, Zhang Y Z, Luo Y S, Pang H. MXenes nanocomposites for energy storage and conversion[J]. Rare Met., 2022,41:1101-1128. doi: 10.1007/s12598-021-01876-0
34. [34]
  Wang W, Wang X, Zhang J X, Yang H J, Luo M, Xue C Z, Lin Z E, Wu T. Three-dimensional superlattices based on unusual chalcogenide supertetrahedral In-Sn-S nanoclusters[J]. Inorg. Chem., 2019,58(1):31-34. doi: 10.1021/acs.inorgchem.8b02574
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