Citation: Pei-Ying CHENG, Li-Hua ZHU, Chun-Xin LÜ, Jiang-Hua LIU, Wei ZHONG, Ya-Bing HE. Efficient aerobic oxidation of alcohols over Cu-Cu₂O nanoparticles supported on a porous polythiophene polymer[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1223-1234. doi: 10.11862/CJIC.2023.108 shu

Efficient aerobic oxidation of alcohols over Cu-Cu₂O nanoparticles supported on a porous polythiophene polymer

Pei-Ying CHENG ^{1, 2} ,
Li-Hua ZHU ^{1, 2} ,
Chun-Xin LÜ ² ,
Jiang-Hua LIU ³ ,
Wei ZHONG ^2,, ,
Ya-Bing HE ^1,,

1.
College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
3.
Yanshan County Fire and Rescue Brigade of Yunnan, Wenshan, Yunnan 663100, China

Corresponding author: Wei ZHONG, weizhong@mail.zjxu.edu.cn Ya-Bing HE, heyabing@zjnu.cn
Received Date: 9 March 2023
Revised Date: 19 May 2023

Figures(9)

Porous organic polymer PTPA containing N, S heteroatoms has been prepared via oxidative coupling of thiophene. Then composite material Cu-Cu₂O/PTPA was synthesized via solvothermal method and fully characterized by infrared spectroscopy (IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), N₂ adsorption desorption, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy (HRTEM). Under the mild conditions of 30 ℃ and open air, Cu-Cu₂O/PTPA showed good catalytic activity towards selective oxidation of benzyl, allyl, and heterocyclic alcohols employing 2, 2, 6, 6-tetramethylpiperidine 1-oxyl (TEMPO) as a co-catalyst and N-methylimidazole (NMI) as an auxiliary ligand. Due to the high content of N and S heteroatoms in the material, Cu-Cu₂O/PTPA showed excellent cycling stability for oxidation of benzyl alcohol, and the yield of product remained above 97% after 9 runs.
- Cu-based catalyst,
- porous organic polymers,
- selective oxidation of alcohols,
- cycling stability
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Efficient aerobic oxidation of alcohols over Cu-Cu2O nanoparticles supported on a porous polythiophene polymer

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Efficient aerobic oxidation of alcohols over Cu-Cu₂O nanoparticles supported on a porous polythiophene polymer