Citation: Yun-Shang YANG, Fan-Fan QIN, Yi-Zhen YUAN, Ying-Peng ZHANG, Yu-Ning LIANG. Synthesis of a Zr-based organometallic gel with effective adsorption of Pb(Ⅱ) ion[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1303-1314. doi: 10.11862/CJIC.2023.104 shu

Synthesis of a Zr-based organometallic gel with effective adsorption of Pb(Ⅱ) ion

School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: Yun-Shang YANG, yangyunshang@tom.com Ying-Peng ZHANG, yingpengzhang@126.com
Received Date: 8 October 2022
Revised Date: 26 May 2023

Figures(11)

In this work, the overall formation of gel groups was studied by using the synthesized 4, 4, 4-tricarboxytri-phenylamine (H₃TCA) as the main ligand. A supramolecular amorphous zirconium - based organometallic gel (Zr-MOG) was synthesized by the solvothermal method. Amorphous Zr-MOG was synthesized by gelation of UIO -66 (i.e. Zr- MOF) by a simple method of constant time- controlled crystallization. The gelation of precursor ZrCl₄ was promoted by changing the ratio of metal ligands. The precursor ZrCl₄ forms oxide and hydroxide bridges at room temperature, which promotes the formation of [Zr₆O₄(OH)₄]¹²⁺ clusters and induces rapid and excessive nucleation rates. The results showed that the prepared Zr-MOG had the multi-layer structure of gel soft materials and amorphous polymer network, and had good adsorption capacity for Pb(Ⅱ). A series of studies on its adsorption properties were made to verify its recyclability and reusability. In addition, the transformation between crystalline MOF and highly dispersed amorphous MOG was successfully realized by using glacial acetic acid as a crystallization accelerator.
- organometallic gel,
- adsorption material,
- Zr-based metal-organic framework,
- Pb(Ⅱ)
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